High nonlinear optical anisotropy of urea nanofibers

Detalhes bibliográficos
Autor(a) principal: Isakov, D. V.
Data de Publicação: 2010
Outros Autores: Gomes, E. Matos, Belsley, M., Almeida, B. G., Martins, Albino, Neves, N. M., Reis, R. L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Texto Completo: http://hdl.handle.net/1822/14148
Resumo: Nanofibers consisting of the optically nonlinear organic molecule urea embedded in both poly(ethylene oxide) (PEO) and poly(vinyl alcohol) (PVA) polymers were produced by the electrospinning technique. The second-harmonic generation produced by aligned fiber mats of these materials displays a strong dependence on the polarization of the incident light. In PVA-urea nanofibers the effectiveness in generating of the second-harmonic light is as high as that of a pure urea powder with an average grain size of 110 μm. The results suggest that single crystalline urea nanofibers were achieved with a long-range crystalline order extending into the range of 2–4 μm with PVA as the host polymer.
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spelling High nonlinear optical anisotropy of urea nanofibersNanoscale materials and structures: fabrication and characterizationPolymers, organicsOptical frequency convertersScience & TechnologyNanofibers consisting of the optically nonlinear organic molecule urea embedded in both poly(ethylene oxide) (PEO) and poly(vinyl alcohol) (PVA) polymers were produced by the electrospinning technique. The second-harmonic generation produced by aligned fiber mats of these materials displays a strong dependence on the polarization of the incident light. In PVA-urea nanofibers the effectiveness in generating of the second-harmonic light is as high as that of a pure urea powder with an average grain size of 110 μm. The results suggest that single crystalline urea nanofibers were achieved with a long-range crystalline order extending into the range of 2–4 μm with PVA as the host polymer.This work was carried out in the frame of CIENCIA-2007 program (reference UMINHO-CF06) and financially supported by Fundacao para a Ciencia e Tecnologia, PTDC/CTM/105597/2008.EDP SciencesUniversidade do MinhoIsakov, D. V.Gomes, E. MatosBelsley, M.Almeida, B. G.Martins, AlbinoNeves, N. M.Reis, R. L.20102010-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/14148eng0295-5075 (print)10.1209/0295-5075/91/28007DOI: 10.1209/0295-5075/91/28007info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-11T06:18:10Zoai:repositorium.sdum.uminho.pt:1822/14148Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T15:48:30.373754Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv High nonlinear optical anisotropy of urea nanofibers
title High nonlinear optical anisotropy of urea nanofibers
spellingShingle High nonlinear optical anisotropy of urea nanofibers
Isakov, D. V.
Nanoscale materials and structures: fabrication and characterization
Polymers, organics
Optical frequency converters
Science & Technology
title_short High nonlinear optical anisotropy of urea nanofibers
title_full High nonlinear optical anisotropy of urea nanofibers
title_fullStr High nonlinear optical anisotropy of urea nanofibers
title_full_unstemmed High nonlinear optical anisotropy of urea nanofibers
title_sort High nonlinear optical anisotropy of urea nanofibers
author Isakov, D. V.
author_facet Isakov, D. V.
Gomes, E. Matos
Belsley, M.
Almeida, B. G.
Martins, Albino
Neves, N. M.
Reis, R. L.
author_role author
author2 Gomes, E. Matos
Belsley, M.
Almeida, B. G.
Martins, Albino
Neves, N. M.
Reis, R. L.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Isakov, D. V.
Gomes, E. Matos
Belsley, M.
Almeida, B. G.
Martins, Albino
Neves, N. M.
Reis, R. L.
dc.subject.por.fl_str_mv Nanoscale materials and structures: fabrication and characterization
Polymers, organics
Optical frequency converters
Science & Technology
topic Nanoscale materials and structures: fabrication and characterization
Polymers, organics
Optical frequency converters
Science & Technology
description Nanofibers consisting of the optically nonlinear organic molecule urea embedded in both poly(ethylene oxide) (PEO) and poly(vinyl alcohol) (PVA) polymers were produced by the electrospinning technique. The second-harmonic generation produced by aligned fiber mats of these materials displays a strong dependence on the polarization of the incident light. In PVA-urea nanofibers the effectiveness in generating of the second-harmonic light is as high as that of a pure urea powder with an average grain size of 110 μm. The results suggest that single crystalline urea nanofibers were achieved with a long-range crystalline order extending into the range of 2–4 μm with PVA as the host polymer.
publishDate 2010
dc.date.none.fl_str_mv 2010
2010-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/14148
url http://hdl.handle.net/1822/14148
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0295-5075 (print)
10.1209/0295-5075/91/28007
DOI: 10.1209/0295-5075/91/28007
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dc.publisher.none.fl_str_mv EDP Sciences
publisher.none.fl_str_mv EDP Sciences
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