Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)

Bibliographic Details
Main Author: Felipe, Lívia Cristina de Oliveira
Publication Date: 2022
Other Authors: Melo, Dulce Maria de Araújo, Medeiros, Rodolfo Luiz Bezerra de Araújo, Araújo, Tomaz Rodrigues de, Silva, Artejose Revoredo da, Dias, Luís Paulo da Silva, Figueredo, Gilvan Pereira de
Format: Article
Language: eng
Source: Research, Society and Development
Download full: https://rsdjournal.org/index.php/rsd/article/view/32489
Summary: Fuel cells are one of the most efficient and effective solutions to environmental problems and high energy demand. They are devices which change chemical energy into electrochemical energy, allowing much higher efficiency than conventional thermomechanical conversion methods. Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites have been widely studied for application as cathodes in solid oxide fuel cells (SOFC) due to their high electrical conductivity, high thermal and chemical stability, low difference in thermal expansion coefficient, and physico-chemical compatibility with the other cells components. The aim of this work was to synthesize perovskitas type La0.7Sr0.3Co0.5Fe0.5O3 by sol-gel method and evaluate the potential for application as a cathode for fuel cell. The results obtained by X-ray powder diffraction (XRD) indicate that the sol-gel method calcined at 900ºC obtained an amount of the perovskite phase above 95%. The Field Emission Gun-Scanning Electron Microscope (FEG-SEM) images of LSCF film produced with 4 layers showed a better quality. Thus, the results obtained by XRD and FEG-SEM, indicate that the sol-gel method calcined at 900ºC has a potential application as cathode in solid oxide fuel cells.
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spelling Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)Perovskitas LSCF (Lanthanum, Strontium and Cobalt Ferrites) obtenidas por el método sol-gel para su potencial aplicación en celdas de combustible de óxido sólidoPerovskitas LSCF (Ferritas de Lantânio, Estrôncio e Cobalto) obtidas pelo método sol-gel para potencial aplicação em células à combustível de óxido sólido (SOFC)PerovskitaLSCFCélulas à combustívelCatodo.PerovskitaLSCFPila de combustibleCátodo.PerovskiteLSCFFuel cellCathode.Fuel cells are one of the most efficient and effective solutions to environmental problems and high energy demand. They are devices which change chemical energy into electrochemical energy, allowing much higher efficiency than conventional thermomechanical conversion methods. Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites have been widely studied for application as cathodes in solid oxide fuel cells (SOFC) due to their high electrical conductivity, high thermal and chemical stability, low difference in thermal expansion coefficient, and physico-chemical compatibility with the other cells components. The aim of this work was to synthesize perovskitas type La0.7Sr0.3Co0.5Fe0.5O3 by sol-gel method and evaluate the potential for application as a cathode for fuel cell. The results obtained by X-ray powder diffraction (XRD) indicate that the sol-gel method calcined at 900ºC obtained an amount of the perovskite phase above 95%. The Field Emission Gun-Scanning Electron Microscope (FEG-SEM) images of LSCF film produced with 4 layers showed a better quality. Thus, the results obtained by XRD and FEG-SEM, indicate that the sol-gel method calcined at 900ºC has a potential application as cathode in solid oxide fuel cells.Las pilas de combustible son una de las soluciones más eficientes y eficaces a los problemas medioambientales y de alta demanda energética. Son dispositivos que transforman la energía química en energía electroquímica, lo que permite una eficiencia mucho mayor que los métodos convencionales de conversión termomecánica. Las perovskitas de ferrita de lantano, estroncio y cobalto (LSCF) han sido ampliamente estudiadas para su aplicación como cátodos en celdas de combustible de óxido sólido (SOFC) debido a su alta conductividad eléctrica, alta estabilidad térmica y química, baja diferencia en el coeficiente de expansión térmica y compatibilidad fisicoquímica con los demás componentes de las células. El objetivo de este trabajo fue sintetizar perovskitas tipo La0.7Sr0.3Co0.5Fe0.5O3 por el método sol-gel, y evaluar el potencial de aplicación como cátodo para celdas de combustible. Los resultados obtenidos por DRX indican que el método sol-gel calcinado a 900ºC obtuvo una cantidad de fase perovskita superior al 95%. Las imágenes FEG-MEV de película LSCF producida con 4 capas mostraron una mejor calidad. Así, los resultados obtenidos por DRX y FEG-MEV, indican que el método sol-gel calcinado a 900ºC tiene una aplicación potencial como cátodo en pilas de combustible de óxido sólido.As células à combustível são uma das soluções mais eficientes e eficazes para problemas ambientais e atender a alta demanda de energia. São dispositivos que transformam energia química em energia eletroquímica, permitindo uma eficiência muito maior do que os métodos convencionais de conversão termomecânica. As perovskitas de Ferrita de Lantânio, Estrôncio e Cobalto (LSCF) têm sido amplamente estudadas para aplicação como cátodos em células a combustível de óxido sólido (SOFC) devido à sua alta condutividade elétrica, alta estabilidade térmica e química, baixa diferença no coeficiente de expansão térmica e compatibilidade físico-química com os demais componentes das células. O objetivo deste trabalho foi sintetizar perovskitas tipo La0,7Sr0,3Co0,5Fe0,5O3 pelo método sol-gel, e avaliar o potencial de aplicação como catodo para célula à combustível. Os resultados obtidos por difratometria de Raios X (DRX) indicam que o método sol-gel calcinado a 900ºC obteve uma quantidade da fase perovskita acima de 95 %. As imagens de microscopia eletrônica por emissão de campo (FEG-MEV) do filme LSCF produzidas com 4 camadas apresentaram melhor qualidade. Assim, os resultados obtidos por DRX e FEG-MEV, indicam que o método sol-gel calcinado a 900ºC tem potencial aplicação como catodo em células a combustível de óxido sólido.Research, Society and Development2022-10-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/3248910.33448/rsd-v11i14.32489Research, Society and Development; Vol. 11 No. 14; e43111432489Research, Society and Development; Vol. 11 Núm. 14; e43111432489Research, Society and Development; v. 11 n. 14; e431114324892525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIenghttps://rsdjournal.org/index.php/rsd/article/view/32489/30097Copyright (c) 2022 Lívia Cristina de Oliveira Felipe; Dulce Maria de Araújo Melo; Rodolfo Luiz Bezerra de Araújo Medeiros; Tomaz Rodrigues de Araújo; Artejose Revoredo da Silva; Luís Paulo da Silva Dias; Gilvan Pereira de Figueredohttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessFelipe, Lívia Cristina de Oliveira Melo, Dulce Maria de Araújo Medeiros, Rodolfo Luiz Bezerra de Araújo Araújo, Tomaz Rodrigues de Silva, Artejose Revoredo da Dias, Luís Paulo da Silva Figueredo, Gilvan Pereira de 2022-11-08T13:36:27Zoai:ojs.pkp.sfu.ca:article/32489Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:48:28.885654Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false
dc.title.none.fl_str_mv Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
Perovskitas LSCF (Lanthanum, Strontium and Cobalt Ferrites) obtenidas por el método sol-gel para su potencial aplicación en celdas de combustible de óxido sólido
Perovskitas LSCF (Ferritas de Lantânio, Estrôncio e Cobalto) obtidas pelo método sol-gel para potencial aplicação em células à combustível de óxido sólido (SOFC)
title Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
spellingShingle Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
Felipe, Lívia Cristina de Oliveira
Perovskita
LSCF
Células à combustível
Catodo.
Perovskita
LSCF
Pila de combustible
Cátodo.
Perovskite
LSCF
Fuel cell
Cathode.
title_short Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
title_full Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
title_fullStr Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
title_full_unstemmed Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
title_sort Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
author Felipe, Lívia Cristina de Oliveira
author_facet Felipe, Lívia Cristina de Oliveira
Melo, Dulce Maria de Araújo
Medeiros, Rodolfo Luiz Bezerra de Araújo
Araújo, Tomaz Rodrigues de
Silva, Artejose Revoredo da
Dias, Luís Paulo da Silva
Figueredo, Gilvan Pereira de
author_role author
author2 Melo, Dulce Maria de Araújo
Medeiros, Rodolfo Luiz Bezerra de Araújo
Araújo, Tomaz Rodrigues de
Silva, Artejose Revoredo da
Dias, Luís Paulo da Silva
Figueredo, Gilvan Pereira de
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Felipe, Lívia Cristina de Oliveira
Melo, Dulce Maria de Araújo
Medeiros, Rodolfo Luiz Bezerra de Araújo
Araújo, Tomaz Rodrigues de
Silva, Artejose Revoredo da
Dias, Luís Paulo da Silva
Figueredo, Gilvan Pereira de
dc.subject.por.fl_str_mv Perovskita
LSCF
Células à combustível
Catodo.
Perovskita
LSCF
Pila de combustible
Cátodo.
Perovskite
LSCF
Fuel cell
Cathode.
topic Perovskita
LSCF
Células à combustível
Catodo.
Perovskita
LSCF
Pila de combustible
Cátodo.
Perovskite
LSCF
Fuel cell
Cathode.
description Fuel cells are one of the most efficient and effective solutions to environmental problems and high energy demand. They are devices which change chemical energy into electrochemical energy, allowing much higher efficiency than conventional thermomechanical conversion methods. Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites have been widely studied for application as cathodes in solid oxide fuel cells (SOFC) due to their high electrical conductivity, high thermal and chemical stability, low difference in thermal expansion coefficient, and physico-chemical compatibility with the other cells components. The aim of this work was to synthesize perovskitas type La0.7Sr0.3Co0.5Fe0.5O3 by sol-gel method and evaluate the potential for application as a cathode for fuel cell. The results obtained by X-ray powder diffraction (XRD) indicate that the sol-gel method calcined at 900ºC obtained an amount of the perovskite phase above 95%. The Field Emission Gun-Scanning Electron Microscope (FEG-SEM) images of LSCF film produced with 4 layers showed a better quality. Thus, the results obtained by XRD and FEG-SEM, indicate that the sol-gel method calcined at 900ºC has a potential application as cathode in solid oxide fuel cells.
publishDate 2022
dc.date.none.fl_str_mv 2022-10-18
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/32489
10.33448/rsd-v11i14.32489
url https://rsdjournal.org/index.php/rsd/article/view/32489
identifier_str_mv 10.33448/rsd-v11i14.32489
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/32489/30097
dc.rights.driver.fl_str_mv https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Research, Society and Development
publisher.none.fl_str_mv Research, Society and Development
dc.source.none.fl_str_mv Research, Society and Development; Vol. 11 No. 14; e43111432489
Research, Society and Development; Vol. 11 Núm. 14; e43111432489
Research, Society and Development; v. 11 n. 14; e43111432489
2525-3409
reponame:Research, Society and Development
instname:Universidade Federal de Itajubá (UNIFEI)
instacron:UNIFEI
instname_str Universidade Federal de Itajubá (UNIFEI)
instacron_str UNIFEI
institution UNIFEI
reponame_str Research, Society and Development
collection Research, Society and Development
repository.name.fl_str_mv Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)
repository.mail.fl_str_mv rsd.articles@gmail.com
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