Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)
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Publication Date: | 2022 |
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Format: | Article |
Language: | eng |
Source: | Research, Society and Development |
Download full: | https://rsdjournal.org/index.php/rsd/article/view/32489 |
Summary: | Fuel cells are one of the most efficient and effective solutions to environmental problems and high energy demand. They are devices which change chemical energy into electrochemical energy, allowing much higher efficiency than conventional thermomechanical conversion methods. Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites have been widely studied for application as cathodes in solid oxide fuel cells (SOFC) due to their high electrical conductivity, high thermal and chemical stability, low difference in thermal expansion coefficient, and physico-chemical compatibility with the other cells components. The aim of this work was to synthesize perovskitas type La0.7Sr0.3Co0.5Fe0.5O3 by sol-gel method and evaluate the potential for application as a cathode for fuel cell. The results obtained by X-ray powder diffraction (XRD) indicate that the sol-gel method calcined at 900ºC obtained an amount of the perovskite phase above 95%. The Field Emission Gun-Scanning Electron Microscope (FEG-SEM) images of LSCF film produced with 4 layers showed a better quality. Thus, the results obtained by XRD and FEG-SEM, indicate that the sol-gel method calcined at 900ºC has a potential application as cathode in solid oxide fuel cells. |
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Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC)Perovskitas LSCF (Lanthanum, Strontium and Cobalt Ferrites) obtenidas por el método sol-gel para su potencial aplicación en celdas de combustible de óxido sólidoPerovskitas LSCF (Ferritas de Lantânio, Estrôncio e Cobalto) obtidas pelo método sol-gel para potencial aplicação em células à combustível de óxido sólido (SOFC)PerovskitaLSCFCélulas à combustívelCatodo.PerovskitaLSCFPila de combustibleCátodo.PerovskiteLSCFFuel cellCathode.Fuel cells are one of the most efficient and effective solutions to environmental problems and high energy demand. They are devices which change chemical energy into electrochemical energy, allowing much higher efficiency than conventional thermomechanical conversion methods. Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites have been widely studied for application as cathodes in solid oxide fuel cells (SOFC) due to their high electrical conductivity, high thermal and chemical stability, low difference in thermal expansion coefficient, and physico-chemical compatibility with the other cells components. The aim of this work was to synthesize perovskitas type La0.7Sr0.3Co0.5Fe0.5O3 by sol-gel method and evaluate the potential for application as a cathode for fuel cell. The results obtained by X-ray powder diffraction (XRD) indicate that the sol-gel method calcined at 900ºC obtained an amount of the perovskite phase above 95%. The Field Emission Gun-Scanning Electron Microscope (FEG-SEM) images of LSCF film produced with 4 layers showed a better quality. Thus, the results obtained by XRD and FEG-SEM, indicate that the sol-gel method calcined at 900ºC has a potential application as cathode in solid oxide fuel cells.Las pilas de combustible son una de las soluciones más eficientes y eficaces a los problemas medioambientales y de alta demanda energética. Son dispositivos que transforman la energía química en energía electroquímica, lo que permite una eficiencia mucho mayor que los métodos convencionales de conversión termomecánica. Las perovskitas de ferrita de lantano, estroncio y cobalto (LSCF) han sido ampliamente estudiadas para su aplicación como cátodos en celdas de combustible de óxido sólido (SOFC) debido a su alta conductividad eléctrica, alta estabilidad térmica y química, baja diferencia en el coeficiente de expansión térmica y compatibilidad fisicoquímica con los demás componentes de las células. El objetivo de este trabajo fue sintetizar perovskitas tipo La0.7Sr0.3Co0.5Fe0.5O3 por el método sol-gel, y evaluar el potencial de aplicación como cátodo para celdas de combustible. Los resultados obtenidos por DRX indican que el método sol-gel calcinado a 900ºC obtuvo una cantidad de fase perovskita superior al 95%. Las imágenes FEG-MEV de película LSCF producida con 4 capas mostraron una mejor calidad. Así, los resultados obtenidos por DRX y FEG-MEV, indican que el método sol-gel calcinado a 900ºC tiene una aplicación potencial como cátodo en pilas de combustible de óxido sólido.As células à combustível são uma das soluções mais eficientes e eficazes para problemas ambientais e atender a alta demanda de energia. São dispositivos que transformam energia química em energia eletroquímica, permitindo uma eficiência muito maior do que os métodos convencionais de conversão termomecânica. As perovskitas de Ferrita de Lantânio, Estrôncio e Cobalto (LSCF) têm sido amplamente estudadas para aplicação como cátodos em células a combustível de óxido sólido (SOFC) devido à sua alta condutividade elétrica, alta estabilidade térmica e química, baixa diferença no coeficiente de expansão térmica e compatibilidade físico-química com os demais componentes das células. O objetivo deste trabalho foi sintetizar perovskitas tipo La0,7Sr0,3Co0,5Fe0,5O3 pelo método sol-gel, e avaliar o potencial de aplicação como catodo para célula à combustível. Os resultados obtidos por difratometria de Raios X (DRX) indicam que o método sol-gel calcinado a 900ºC obteve uma quantidade da fase perovskita acima de 95 %. As imagens de microscopia eletrônica por emissão de campo (FEG-MEV) do filme LSCF produzidas com 4 camadas apresentaram melhor qualidade. Assim, os resultados obtidos por DRX e FEG-MEV, indicam que o método sol-gel calcinado a 900ºC tem potencial aplicação como catodo em células a combustível de óxido sólido.Research, Society and Development2022-10-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/3248910.33448/rsd-v11i14.32489Research, Society and Development; Vol. 11 No. 14; e43111432489Research, Society and Development; Vol. 11 Núm. 14; e43111432489Research, Society and Development; v. 11 n. 14; e431114324892525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIenghttps://rsdjournal.org/index.php/rsd/article/view/32489/30097Copyright (c) 2022 Lívia Cristina de Oliveira Felipe; Dulce Maria de Araújo Melo; Rodolfo Luiz Bezerra de Araújo Medeiros; Tomaz Rodrigues de Araújo; Artejose Revoredo da Silva; Luís Paulo da Silva Dias; Gilvan Pereira de Figueredohttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessFelipe, Lívia Cristina de Oliveira Melo, Dulce Maria de Araújo Medeiros, Rodolfo Luiz Bezerra de Araújo Araújo, Tomaz Rodrigues de Silva, Artejose Revoredo da Dias, Luís Paulo da Silva Figueredo, Gilvan Pereira de 2022-11-08T13:36:27Zoai:ojs.pkp.sfu.ca:article/32489Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:48:28.885654Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false |
dc.title.none.fl_str_mv |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) Perovskitas LSCF (Lanthanum, Strontium and Cobalt Ferrites) obtenidas por el método sol-gel para su potencial aplicación en celdas de combustible de óxido sólido Perovskitas LSCF (Ferritas de Lantânio, Estrôncio e Cobalto) obtidas pelo método sol-gel para potencial aplicação em células à combustível de óxido sólido (SOFC) |
title |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) |
spellingShingle |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) Felipe, Lívia Cristina de Oliveira Perovskita LSCF Células à combustível Catodo. Perovskita LSCF Pila de combustible Cátodo. Perovskite LSCF Fuel cell Cathode. |
title_short |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) |
title_full |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) |
title_fullStr |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) |
title_full_unstemmed |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) |
title_sort |
Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites by Sol-Gel Method for Potential Application in Solid Oxide Fuel Cells (SOFC) |
author |
Felipe, Lívia Cristina de Oliveira |
author_facet |
Felipe, Lívia Cristina de Oliveira Melo, Dulce Maria de Araújo Medeiros, Rodolfo Luiz Bezerra de Araújo Araújo, Tomaz Rodrigues de Silva, Artejose Revoredo da Dias, Luís Paulo da Silva Figueredo, Gilvan Pereira de |
author_role |
author |
author2 |
Melo, Dulce Maria de Araújo Medeiros, Rodolfo Luiz Bezerra de Araújo Araújo, Tomaz Rodrigues de Silva, Artejose Revoredo da Dias, Luís Paulo da Silva Figueredo, Gilvan Pereira de |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Felipe, Lívia Cristina de Oliveira Melo, Dulce Maria de Araújo Medeiros, Rodolfo Luiz Bezerra de Araújo Araújo, Tomaz Rodrigues de Silva, Artejose Revoredo da Dias, Luís Paulo da Silva Figueredo, Gilvan Pereira de |
dc.subject.por.fl_str_mv |
Perovskita LSCF Células à combustível Catodo. Perovskita LSCF Pila de combustible Cátodo. Perovskite LSCF Fuel cell Cathode. |
topic |
Perovskita LSCF Células à combustível Catodo. Perovskita LSCF Pila de combustible Cátodo. Perovskite LSCF Fuel cell Cathode. |
description |
Fuel cells are one of the most efficient and effective solutions to environmental problems and high energy demand. They are devices which change chemical energy into electrochemical energy, allowing much higher efficiency than conventional thermomechanical conversion methods. Lanthanum Strontium Cobalt Ferrite (LSCF) perovskites have been widely studied for application as cathodes in solid oxide fuel cells (SOFC) due to their high electrical conductivity, high thermal and chemical stability, low difference in thermal expansion coefficient, and physico-chemical compatibility with the other cells components. The aim of this work was to synthesize perovskitas type La0.7Sr0.3Co0.5Fe0.5O3 by sol-gel method and evaluate the potential for application as a cathode for fuel cell. The results obtained by X-ray powder diffraction (XRD) indicate that the sol-gel method calcined at 900ºC obtained an amount of the perovskite phase above 95%. The Field Emission Gun-Scanning Electron Microscope (FEG-SEM) images of LSCF film produced with 4 layers showed a better quality. Thus, the results obtained by XRD and FEG-SEM, indicate that the sol-gel method calcined at 900ºC has a potential application as cathode in solid oxide fuel cells. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-10-18 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/32489 10.33448/rsd-v11i14.32489 |
url |
https://rsdjournal.org/index.php/rsd/article/view/32489 |
identifier_str_mv |
10.33448/rsd-v11i14.32489 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/32489/30097 |
dc.rights.driver.fl_str_mv |
https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Research, Society and Development |
publisher.none.fl_str_mv |
Research, Society and Development |
dc.source.none.fl_str_mv |
Research, Society and Development; Vol. 11 No. 14; e43111432489 Research, Society and Development; Vol. 11 Núm. 14; e43111432489 Research, Society and Development; v. 11 n. 14; e43111432489 2525-3409 reponame:Research, Society and Development instname:Universidade Federal de Itajubá (UNIFEI) instacron:UNIFEI |
instname_str |
Universidade Federal de Itajubá (UNIFEI) |
instacron_str |
UNIFEI |
institution |
UNIFEI |
reponame_str |
Research, Society and Development |
collection |
Research, Society and Development |
repository.name.fl_str_mv |
Research, Society and Development - Universidade Federal de Itajubá (UNIFEI) |
repository.mail.fl_str_mv |
rsd.articles@gmail.com |
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1831934934704455680 |