Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
Main Author: | |
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Publication Date: | 2023 |
Other Authors: | , , |
Format: | Other |
Language: | eng |
Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
Download full: | http://hdl.handle.net/10362/164172 |
Summary: | This research was funded by Fundação para a Ciência e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020) and fellowships PD/BD/05960/2020 (D.R.) and 2022.12365.BD (N.V.). Publisher Copyright: © 2023 by the authors. |
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Bimetallic (or Multimetallic) Synthesis of N-Heterocyclesbimetallic catalysisgreen chemistrymultimetallic catalysisN-heterocyclessequential catalysistransition metalsCatalysisEnvironmental Science(all)Physical and Theoretical ChemistryThis research was funded by Fundação para a Ciência e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020) and fellowships PD/BD/05960/2020 (D.R.) and 2022.12365.BD (N.V.). Publisher Copyright: © 2023 by the authors.Bimetallic (or multimetallic) catalysis has emerged as a powerful tool in modern chemical synthesis, offering improved reaction control and versatility. This review focuses on the recent developments in bimetallic sequential catalysis for the synthesis of nitrogen heterocycles, which are essential building blocks in pharmaceuticals and fine chemicals. The cooperative action of two (sometimes more) different metal catalysts enables intricate control over reaction pathways, enhancing the selectivity and efficiency of the synthesis of N-heterocyclic compounds. By activating less reactive substrates, this multimetal catalytic strategy opens new synthetic possibilities for challenging compounds. The use of catalytic materials in bimetallic systems reduces waste and improves atom efficiency, aligning with green chemistry principles. With a diverse range of metal combinations and reaction conditions, bimetallic catalysis provides access to a broad array of N-heterocyclic compounds with various functionalities. This paper highlights the significant progress made in the past decade in this topic, emphasizing the promising potential of bimetallic catalysis in drug discovery and the fine chemical industries.DQ - Departamento de QuímicaLAQV@REQUIMTEInstituto de Tecnologia Química e Biológica António Xavier (ITQB)RUNReis, Ana RitaViduedo, NunoRaydan, DanielMarques, Maria Manuel B.2024-02-26T23:55:28Z2023-09-022023-09-02T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/other27application/pdfhttp://hdl.handle.net/10362/164172eng2073-4344PURE: 83886233https://doi.org/10.3390/catal13091268info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:18:53Zoai:run.unl.pt:10362/164172Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:49:38.455817Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
dc.title.none.fl_str_mv |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
title |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
spellingShingle |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles Reis, Ana Rita bimetallic catalysis green chemistry multimetallic catalysis N-heterocycles sequential catalysis transition metals Catalysis Environmental Science(all) Physical and Theoretical Chemistry |
title_short |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
title_full |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
title_fullStr |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
title_full_unstemmed |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
title_sort |
Bimetallic (or Multimetallic) Synthesis of N-Heterocycles |
author |
Reis, Ana Rita |
author_facet |
Reis, Ana Rita Viduedo, Nuno Raydan, Daniel Marques, Maria Manuel B. |
author_role |
author |
author2 |
Viduedo, Nuno Raydan, Daniel Marques, Maria Manuel B. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
DQ - Departamento de Química LAQV@REQUIMTE Instituto de Tecnologia Química e Biológica António Xavier (ITQB) RUN |
dc.contributor.author.fl_str_mv |
Reis, Ana Rita Viduedo, Nuno Raydan, Daniel Marques, Maria Manuel B. |
dc.subject.por.fl_str_mv |
bimetallic catalysis green chemistry multimetallic catalysis N-heterocycles sequential catalysis transition metals Catalysis Environmental Science(all) Physical and Theoretical Chemistry |
topic |
bimetallic catalysis green chemistry multimetallic catalysis N-heterocycles sequential catalysis transition metals Catalysis Environmental Science(all) Physical and Theoretical Chemistry |
description |
This research was funded by Fundação para a Ciência e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020) and fellowships PD/BD/05960/2020 (D.R.) and 2022.12365.BD (N.V.). Publisher Copyright: © 2023 by the authors. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-09-02 2023-09-02T00:00:00Z 2024-02-26T23:55:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/other |
format |
other |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/164172 |
url |
http://hdl.handle.net/10362/164172 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2073-4344 PURE: 83886233 https://doi.org/10.3390/catal13091268 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
dc.format.none.fl_str_mv |
27 application/pdf |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia |
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