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Bimetallic (or Multimetallic) Synthesis of N-Heterocycles

Bibliographic Details
Main Author: Reis, Ana Rita
Publication Date: 2023
Other Authors: Viduedo, Nuno, Raydan, Daniel, Marques, Maria Manuel B.
Format: Other
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/164172
Summary: This research was funded by Fundação para a Ciência e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020) and fellowships PD/BD/05960/2020 (D.R.) and 2022.12365.BD (N.V.). Publisher Copyright: © 2023 by the authors.
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spelling Bimetallic (or Multimetallic) Synthesis of N-Heterocyclesbimetallic catalysisgreen chemistrymultimetallic catalysisN-heterocyclessequential catalysistransition metalsCatalysisEnvironmental Science(all)Physical and Theoretical ChemistryThis research was funded by Fundação para a Ciência e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020) and fellowships PD/BD/05960/2020 (D.R.) and 2022.12365.BD (N.V.). Publisher Copyright: © 2023 by the authors.Bimetallic (or multimetallic) catalysis has emerged as a powerful tool in modern chemical synthesis, offering improved reaction control and versatility. This review focuses on the recent developments in bimetallic sequential catalysis for the synthesis of nitrogen heterocycles, which are essential building blocks in pharmaceuticals and fine chemicals. The cooperative action of two (sometimes more) different metal catalysts enables intricate control over reaction pathways, enhancing the selectivity and efficiency of the synthesis of N-heterocyclic compounds. By activating less reactive substrates, this multimetal catalytic strategy opens new synthetic possibilities for challenging compounds. The use of catalytic materials in bimetallic systems reduces waste and improves atom efficiency, aligning with green chemistry principles. With a diverse range of metal combinations and reaction conditions, bimetallic catalysis provides access to a broad array of N-heterocyclic compounds with various functionalities. This paper highlights the significant progress made in the past decade in this topic, emphasizing the promising potential of bimetallic catalysis in drug discovery and the fine chemical industries.DQ - Departamento de QuímicaLAQV@REQUIMTEInstituto de Tecnologia Química e Biológica António Xavier (ITQB)RUNReis, Ana RitaViduedo, NunoRaydan, DanielMarques, Maria Manuel B.2024-02-26T23:55:28Z2023-09-022023-09-02T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/other27application/pdfhttp://hdl.handle.net/10362/164172eng2073-4344PURE: 83886233https://doi.org/10.3390/catal13091268info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:18:53Zoai:run.unl.pt:10362/164172Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:49:38.455817Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
title Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
spellingShingle Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
Reis, Ana Rita
bimetallic catalysis
green chemistry
multimetallic catalysis
N-heterocycles
sequential catalysis
transition metals
Catalysis
Environmental Science(all)
Physical and Theoretical Chemistry
title_short Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
title_full Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
title_fullStr Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
title_full_unstemmed Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
title_sort Bimetallic (or Multimetallic) Synthesis of N-Heterocycles
author Reis, Ana Rita
author_facet Reis, Ana Rita
Viduedo, Nuno
Raydan, Daniel
Marques, Maria Manuel B.
author_role author
author2 Viduedo, Nuno
Raydan, Daniel
Marques, Maria Manuel B.
author2_role author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
LAQV@REQUIMTE
Instituto de Tecnologia Química e Biológica António Xavier (ITQB)
RUN
dc.contributor.author.fl_str_mv Reis, Ana Rita
Viduedo, Nuno
Raydan, Daniel
Marques, Maria Manuel B.
dc.subject.por.fl_str_mv bimetallic catalysis
green chemistry
multimetallic catalysis
N-heterocycles
sequential catalysis
transition metals
Catalysis
Environmental Science(all)
Physical and Theoretical Chemistry
topic bimetallic catalysis
green chemistry
multimetallic catalysis
N-heterocycles
sequential catalysis
transition metals
Catalysis
Environmental Science(all)
Physical and Theoretical Chemistry
description This research was funded by Fundação para a Ciência e Tecnologia (FCT, PTDC/QUI-QOR/0712/2020) and fellowships PD/BD/05960/2020 (D.R.) and 2022.12365.BD (N.V.). Publisher Copyright: © 2023 by the authors.
publishDate 2023
dc.date.none.fl_str_mv 2023-09-02
2023-09-02T00:00:00Z
2024-02-26T23:55:28Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/other
format other
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/164172
url http://hdl.handle.net/10362/164172
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4344
PURE: 83886233
https://doi.org/10.3390/catal13091268
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 27
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