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Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane

Bibliographic Details
Main Author: Santos, A. Sofia
Publication Date: 2024
Other Authors: Losada-Garcia, Noelia, Garcia-Sanz, Carla, Silva, Artur M. S., Marques, M. Manuel B., Palomo, Jose M.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/172399
Summary: This work was supported by the Spanish Government, the Spanish National Research Council (CSIC). project PTDC/QUI‐QOR/0712/2020. We also thank Dr. Martinez from Novozymes. We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI) Publisher Copyright: © 2023 The Authors. ChemCatChem published by Wiley-VCH GmbH.
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spelling Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethanebis(3-indolyl)methanesC−C bond formationindolenanohybridpalladium nanoparticlesCatalysisPhysical and Theoretical ChemistryOrganic ChemistryInorganic ChemistryThis work was supported by the Spanish Government, the Spanish National Research Council (CSIC). project PTDC/QUI‐QOR/0712/2020. We also thank Dr. Martinez from Novozymes. We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI) Publisher Copyright: © 2023 The Authors. ChemCatChem published by Wiley-VCH GmbH.Palladium nanohybrids were synthesized and applied to the one-pot synthesis of bis(3-indolyl)methanes by selective C−C bond reaction from benzyl alcohol and indole. A T. lanuginosus lipase-palladium nanoparticles hybrid (Pd@TLL) was synthesized, yielding PdNPs with an average diameter size of 5 nm. This heterogeneous catalyst was first tested in the selective oxidation of benzyl alcohol to benzaldehyde in different solvents. Then, the direct formation of bis(3-indolyl)methane, by in situ oxidation and C−C coupling, was successfully evaluated under different conditions, obtaining >99 % conversion at 80 °C in toluene, with a TOF value of 9 min−1 and 89 % in pure water, demonstrating the versatility of these biohybrids.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNSantos, A. SofiaLosada-Garcia, NoeliaGarcia-Sanz, CarlaSilva, Artur M. S.Marques, M. Manuel B.Palomo, Jose M.2024-09-25T22:26:14Z2024-02-082024-02-08T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7application/pdfhttp://hdl.handle.net/10362/172399eng1867-3880PURE: 99739648https://doi.org/10.1002/cctc.202300748info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-09-30T01:43:01Zoai:run.unl.pt:10362/172399Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T18:54:22.127239Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
title Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
spellingShingle Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
Santos, A. Sofia
bis(3-indolyl)methanes
C−C bond formation
indole
nanohybrid
palladium nanoparticles
Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
title_short Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
title_full Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
title_fullStr Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
title_full_unstemmed Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
title_sort Exploring Thermomyces lanuginosus Lipase (TLL)-PdNPs Nanohybrid as Suitable Catalyst for One-pot Synthesis of Bis(3-indolyl)phenylmethane
author Santos, A. Sofia
author_facet Santos, A. Sofia
Losada-Garcia, Noelia
Garcia-Sanz, Carla
Silva, Artur M. S.
Marques, M. Manuel B.
Palomo, Jose M.
author_role author
author2 Losada-Garcia, Noelia
Garcia-Sanz, Carla
Silva, Artur M. S.
Marques, M. Manuel B.
Palomo, Jose M.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Santos, A. Sofia
Losada-Garcia, Noelia
Garcia-Sanz, Carla
Silva, Artur M. S.
Marques, M. Manuel B.
Palomo, Jose M.
dc.subject.por.fl_str_mv bis(3-indolyl)methanes
C−C bond formation
indole
nanohybrid
palladium nanoparticles
Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
topic bis(3-indolyl)methanes
C−C bond formation
indole
nanohybrid
palladium nanoparticles
Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
description This work was supported by the Spanish Government, the Spanish National Research Council (CSIC). project PTDC/QUI‐QOR/0712/2020. We also thank Dr. Martinez from Novozymes. We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI) Publisher Copyright: © 2023 The Authors. ChemCatChem published by Wiley-VCH GmbH.
publishDate 2024
dc.date.none.fl_str_mv 2024-09-25T22:26:14Z
2024-02-08
2024-02-08T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/172399
url http://hdl.handle.net/10362/172399
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1867-3880
PURE: 99739648
https://doi.org/10.1002/cctc.202300748
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 7
application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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