Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties

Bibliographic Details
Main Author: Caparrós, Francisco J.
Publication Date: 2020
Other Authors: Outis, Mani, Jung, Yongsik, Choi, Hyeonho, Lima, João Carlos, Rodríguez, Laura
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/119331
Summary: CTQ2016-76120-P
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spelling Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical propertiesDibenzo[g,p]chryseneGoldHeavy atom effectLuminescence matrixesAnalytical ChemistryChemistry (miscellaneous)Molecular MedicinePharmaceutical ScienceDrug DiscoveryPhysical and Theoretical ChemistryOrganic ChemistryCTQ2016-76120-PA new 2,7,10,15-tetraethynyldibenzo[g,p]chrysene ligand (1) and two tetranuclear gold(I) derivatives containing PPh3 (3) and PMe3 (4) phosphines were synthesized and characterized by 1H and 31P NMR, IR spectroscopy, and high-resolution mass spectrometry. The compounds were studied in order to analyze the effect of the introduction of gold(I) on the supramolecular aggregation and photophysical properties. Absorption and emission spectra displayed broad bands due to the establishment of π π interactions as an indication of intermolecular contacts and the formation of aggregates. A decrease of the recorded quantum yield (QY) of the gold(I) derivatives was observed compared to the uncomplexed ligand. The introduction of the complexes into poly methyl methacrylate (PMMA) and Zeonex 480R matrixes was analyzed, and an increase of the measured QY of 4 in Zeonex was observed. No phosphorescent emission was detected.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCaparrós, Francisco J.Outis, ManiJung, YongsikChoi, HyeonhoLima, João CarlosRodríguez, Laura2021-06-15T22:21:38Z2020-02-202020-02-20T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/119331eng1420-3049PURE: 31972983https://doi.org/10.3390/molecules25040949info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:53:48Zoai:run.unl.pt:10362/119331Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:24:56.665651Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
title Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
spellingShingle Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
Caparrós, Francisco J.
Dibenzo[g,p]chrysene
Gold
Heavy atom effect
Luminescence matrixes
Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
title_short Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
title_full Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
title_fullStr Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
title_full_unstemmed Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
title_sort Luminescent tetranuclear gold(I) dibenzo[g,p]chrysene derivatives: Effect of the environment on photophysical properties
author Caparrós, Francisco J.
author_facet Caparrós, Francisco J.
Outis, Mani
Jung, Yongsik
Choi, Hyeonho
Lima, João Carlos
Rodríguez, Laura
author_role author
author2 Outis, Mani
Jung, Yongsik
Choi, Hyeonho
Lima, João Carlos
Rodríguez, Laura
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Caparrós, Francisco J.
Outis, Mani
Jung, Yongsik
Choi, Hyeonho
Lima, João Carlos
Rodríguez, Laura
dc.subject.por.fl_str_mv Dibenzo[g,p]chrysene
Gold
Heavy atom effect
Luminescence matrixes
Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
topic Dibenzo[g,p]chrysene
Gold
Heavy atom effect
Luminescence matrixes
Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
description CTQ2016-76120-P
publishDate 2020
dc.date.none.fl_str_mv 2020-02-20
2020-02-20T00:00:00Z
2021-06-15T22:21:38Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/119331
url http://hdl.handle.net/10362/119331
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1420-3049
PURE: 31972983
https://doi.org/10.3390/molecules25040949
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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