Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)

Bibliographic Details
Main Author: Kaabi, Kamel
Publication Date: 2010
Other Authors: El Glaoui, Meher, Pereira Silva, P. S., Silva, M. Ramos, Ben Nasr, Cherif
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: https://hdl.handle.net/10316/110150
https://doi.org/10.1107/S1600536810015874
Summary: In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups.
id RCAP_48c25febab23fae04cbd522aeceb6426
oai_identifier_str oai:estudogeral.uc.pt:10316/110150
network_acronym_str RCAP
network_name_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository_id_str https://opendoar.ac.uk/repository/7160
spelling Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)single-crystal X-ray studyT = 293 K; mean (C–C) = 0.005 A°R factor = 0.035wR factor = 0.084data-to-parameter ratio = 16.5In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups.International Union of Crystallography2010-05-08info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://hdl.handle.net/10316/110150https://hdl.handle.net/10316/110150https://doi.org/10.1107/S1600536810015874eng1600-5368Kaabi, KamelEl Glaoui, MeherPereira Silva, P. S.Silva, M. RamosBen Nasr, Cherifinfo:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2023-11-15T11:04:27Zoai:estudogeral.uc.pt:10316/110150Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T06:01:49.080946Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
title Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
spellingShingle Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
Kaabi, Kamel
single-crystal X-ray study
T = 293 K; mean (C–C) = 0.005 A°
R factor = 0.035
wR factor = 0.084
data-to-parameter ratio = 16.5
title_short Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
title_full Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
title_fullStr Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
title_full_unstemmed Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
title_sort Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
author Kaabi, Kamel
author_facet Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Silva, M. Ramos
Ben Nasr, Cherif
author_role author
author2 El Glaoui, Meher
Pereira Silva, P. S.
Silva, M. Ramos
Ben Nasr, Cherif
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Silva, M. Ramos
Ben Nasr, Cherif
dc.subject.por.fl_str_mv single-crystal X-ray study
T = 293 K; mean (C–C) = 0.005 A°
R factor = 0.035
wR factor = 0.084
data-to-parameter ratio = 16.5
topic single-crystal X-ray study
T = 293 K; mean (C–C) = 0.005 A°
R factor = 0.035
wR factor = 0.084
data-to-parameter ratio = 16.5
description In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups.
publishDate 2010
dc.date.none.fl_str_mv 2010-05-08
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://hdl.handle.net/10316/110150
https://hdl.handle.net/10316/110150
https://doi.org/10.1107/S1600536810015874
url https://hdl.handle.net/10316/110150
https://doi.org/10.1107/S1600536810015874
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1600-5368
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
_version_ 1833602553599754240

Similar Items