Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)
| Main Author: | |
|---|---|
| Publication Date: | 2010 |
| Other Authors: | , , , |
| Format: | Article |
| Language: | eng |
| Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Download full: | https://hdl.handle.net/10316/110150 https://doi.org/10.1107/S1600536810015874 |
Summary: | In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups. |
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Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II)single-crystal X-ray studyT = 293 K; mean (C–C) = 0.005 A°R factor = 0.035wR factor = 0.084data-to-parameter ratio = 16.5In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups.International Union of Crystallography2010-05-08info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://hdl.handle.net/10316/110150https://hdl.handle.net/10316/110150https://doi.org/10.1107/S1600536810015874eng1600-5368Kaabi, KamelEl Glaoui, MeherPereira Silva, P. S.Silva, M. RamosBen Nasr, Cherifinfo:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2023-11-15T11:04:27Zoai:estudogeral.uc.pt:10316/110150Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T06:01:49.080946Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| title |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| spellingShingle |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) Kaabi, Kamel single-crystal X-ray study T = 293 K; mean (C–C) = 0.005 A° R factor = 0.035 wR factor = 0.084 data-to-parameter ratio = 16.5 |
| title_short |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| title_full |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| title_fullStr |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| title_full_unstemmed |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| title_sort |
Bis(2-amino-6-methyl-pyrimidin-1-ium-4-olate-κN,O)bis-(nitrato-κO,O')cadmium(II) |
| author |
Kaabi, Kamel |
| author_facet |
Kaabi, Kamel El Glaoui, Meher Pereira Silva, P. S. Silva, M. Ramos Ben Nasr, Cherif |
| author_role |
author |
| author2 |
El Glaoui, Meher Pereira Silva, P. S. Silva, M. Ramos Ben Nasr, Cherif |
| author2_role |
author author author author |
| dc.contributor.author.fl_str_mv |
Kaabi, Kamel El Glaoui, Meher Pereira Silva, P. S. Silva, M. Ramos Ben Nasr, Cherif |
| dc.subject.por.fl_str_mv |
single-crystal X-ray study T = 293 K; mean (C–C) = 0.005 A° R factor = 0.035 wR factor = 0.084 data-to-parameter ratio = 16.5 |
| topic |
single-crystal X-ray study T = 293 K; mean (C–C) = 0.005 A° R factor = 0.035 wR factor = 0.084 data-to-parameter ratio = 16.5 |
| description |
In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl-pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups. |
| publishDate |
2010 |
| dc.date.none.fl_str_mv |
2010-05-08 |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/10316/110150 https://hdl.handle.net/10316/110150 https://doi.org/10.1107/S1600536810015874 |
| url |
https://hdl.handle.net/10316/110150 https://doi.org/10.1107/S1600536810015874 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
1600-5368 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
International Union of Crystallography |
| publisher.none.fl_str_mv |
International Union of Crystallography |
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reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia instacron:RCAAP |
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RCAAP |
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RCAAP |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia |
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info@rcaap.pt |
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1833602553599754240 |