Síntese e análise estrutural de compostos supramoleculares de Cd(II) com o ligante 4,6-dimetilpirimidina-2-tiona

• Ano de defesa: 2004
• Autor(a) principal: Casagrande, Gleison Antonio
• Tipo de documento: Dissertação
• Tipo de acesso: Acesso aberto
• Idioma: por
• Instituição de defesa: Universidade Federal de Santa Maria; Brasil; Química; UFSM; Programa de Pós-Graduação em Química; Centro de Ciências Naturais e Exatas
• Palavras-chave em Português: Química; Química inorgânica; CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
• Link de acesso: http://repositorio.ufsm.br/handle/1/26737

This dissertation describes the synthesis and analysis of the supramolecular compounds α- and β-[Cd(DMPYMT-S)2]n, DMPYMT-S = 4,6-dimethylpyrimidine-2- thione. The reaction product of cadmium acetate dihydrate with DMPYMT-S was dissolved in hot ethanol with a small quantity of DMSO or ammonium diethyldithiophosphate. Gradual evaporation of the solvent gave the crystallization products (1) or (2), respectively. Single crystal X-ray structural analysis for both products was carried out. Compound (1), solved and refined in the space group P21/c, shows a supramolecular structure formed by μ2-S–Cd secondary bonds parallel to the crystallographic a axis. Compound (2), solved and refined in the space group Pca21, possesses μ2-S–Cd and Npyrimidine–Cd secondary bonds to form a zig-zag supramolecular structure parallel to the crystallographic b axis. The Cd(II) atom in each structure is sp3 d2 hybridized with an octahedral geometry for (1) and a distorted octahedral geometry for (2). The structural control in the formation of the supramolecular compounds α- and β- [Cd(DYPYMT-S)2] is achieved by the use of complexing agents acting as coligands in the solubilization and crystallization processes. For the two compounds, the results of the C, H and N elemental analysis and infrared vibrational spectroscopy are included.