Estudo do método de obtenção de membranas assimétricas de polietersulfona contendo complexos de polieletrólitos

Detalhes bibliográficos
Ano de defesa: 2020
Autor(a) principal: Vale, Rayane da Silva
Orientador(a): Silva, Caio Marcio Paranhos da lattes
Banca de defesa: Não Informado pela instituição
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Federal de São Carlos
Câmpus São Carlos
Programa de Pós-Graduação: Programa de Pós-Graduação em Química - PPGQ
Departamento: Não Informado pela instituição
País: Não Informado pela instituição
Palavras-chave em Português:
Palavras-chave em Inglês:
Área do conhecimento CNPq:
Link de acesso: https://repositorio.ufscar.br/handle/20.500.14289/12977
Resumo: Compared with traditional separation methods, polymeric membranes have low operation cost, fast separation rate and versatility. One interesting way of changing membrane properties is mixing additives into the polymeric matrix. Polyelectrolytes complexes (PECs) (polyelectrolytes combined via electrostatic interaction) are a good material for that due theirs hydrophilicity, tunable surface charge, stable structures and insolubility in common solvents. Based in this context, inversion phase membranes containing PECs were obtained through three different methodologies: in situ, post crosslink and simultaneously crosslink. The chosen polyelectrolytes were 4-fluorophenyl sulfone terminated poly(diallylpiperidinium hexafluorphosphate) (PDApipPF6) and sulfonated poly(ethylene terephthalate) (SPET). The polymeric matrix used was polyether sulfone, known for its good mechanical strength and high temperature stability. Analysis by fourier transform infrared spectroscopy confirmed the presence of SPET in the PEC membranes, while the presence of PDApipPF6 was confirmed by positives values of zeta potential. Scanning electron microscopy images of the cross-section of the membranes were similar and showed asymmetric structure consisting of a dense skin and porous sub-layer. The increase of water vapor permeability and the decrease of water contact angle of the PEC membranes indicated that the presence of the complexes alters the membranes’ hydrophilic profile. Differences in the curves of the thermogravimetric analysis showed that depending on how the PECs are obtained, the interaction between the PELs changes, which produces membranes with different thermal behaviors. The results of filtration and adsorption of remazol red also varied with the methodology.