Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.

Bibliographic Details
Main Author: Zamian, JR
Publication Date: 1999
Other Authors: Mauro, A. E., Nogueira, V. M.
Format: Article
Language: por
Source: Repositório Institucional da UNESP
Download full: http://hdl.handle.net/11449/194542
Summary: cis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I, The series of compounds cis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I shows an octahedral geometry around the iron atom with the two HgX groups cis to each other, In this paper the assignment for the carbonyl stretching modes and the calculation of their force constants were performed on the basis of the Cotton-Krainhanzel model, Taking into account all the data from the IR,Hg-199 NMR and UV-vis spectra it is possible to verify the influence of X on the electronic densities at the metallic centers.
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spelling Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.iron carbonylsmercuryspectroscopic studiescis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I, The series of compounds cis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I shows an octahedral geometry around the iron atom with the two HgX groups cis to each other, In this paper the assignment for the carbonyl stretching modes and the calculation of their force constants were performed on the basis of the Cotton-Krainhanzel model, Taking into account all the data from the IR,Hg-199 NMR and UV-vis spectra it is possible to verify the influence of X on the electronic densities at the metallic centers.Fed Univ Para, Ctr Ciencias Exatas & Nat, Dept Quim, UFPA, BR-66075110 Belem, Para, BrazilUniv Estadual Paulista, UNESP, Inst Quim, BR-14800900 Araraquara, SP, BrazilUniv Estadual Paulista, UNESP, Inst Quim, BR-14800900 Araraquara, SP, BrazilSoc Brasileira QuimicaUniversidade Federal do Pará (UFPA)Universidade Estadual Paulista (Unesp)Zamian, JRMauro, A. E.Nogueira, V. M.2020-12-10T16:29:25Z2020-12-10T16:29:25Z1999-11-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article787-789Quimica Nova. Sao Paulo: Soc Brasileira Quimica, v. 22, n. 6, p. 787-789, 1999.0100-4042http://hdl.handle.net/11449/194542WOS:000084027000003Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuimica Novainfo:eu-repo/semantics/openAccess2025-05-28T05:03:12Zoai:repositorio.unesp.br:11449/194542Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestrepositoriounesp@unesp.bropendoar:29462025-05-28T05:03:12Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
title Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
spellingShingle Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
Zamian, JR
iron carbonyls
mercury
spectroscopic studies
title_short Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
title_full Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
title_fullStr Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
title_full_unstemmed Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
title_sort Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
author Zamian, JR
author_facet Zamian, JR
Mauro, A. E.
Nogueira, V. M.
author_role author
author2 Mauro, A. E.
Nogueira, V. M.
author2_role author
author
dc.contributor.none.fl_str_mv Universidade Federal do Pará (UFPA)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Zamian, JR
Mauro, A. E.
Nogueira, V. M.
dc.subject.por.fl_str_mv iron carbonyls
mercury
spectroscopic studies
topic iron carbonyls
mercury
spectroscopic studies
description cis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I, The series of compounds cis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I shows an octahedral geometry around the iron atom with the two HgX groups cis to each other, In this paper the assignment for the carbonyl stretching modes and the calculation of their force constants were performed on the basis of the Cotton-Krainhanzel model, Taking into account all the data from the IR,Hg-199 NMR and UV-vis spectra it is possible to verify the influence of X on the electronic densities at the metallic centers.
publishDate 1999
dc.date.none.fl_str_mv 1999-11-01
2020-12-10T16:29:25Z
2020-12-10T16:29:25Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv Quimica Nova. Sao Paulo: Soc Brasileira Quimica, v. 22, n. 6, p. 787-789, 1999.
0100-4042
http://hdl.handle.net/11449/194542
WOS:000084027000003
identifier_str_mv Quimica Nova. Sao Paulo: Soc Brasileira Quimica, v. 22, n. 6, p. 787-789, 1999.
0100-4042
WOS:000084027000003
url http://hdl.handle.net/11449/194542
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Quimica Nova
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 787-789
dc.publisher.none.fl_str_mv Soc Brasileira Quimica
publisher.none.fl_str_mv Soc Brasileira Quimica
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv repositoriounesp@unesp.br
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