Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications

Bibliographic Details
Main Author: Martins Junior, José Roberto Severino
Publication Date: 2024
Other Authors: Kuroda, Pedro Akira Bazaglia [UNESP], Grandini, Carlos Roberto [UNESP]
Format: Article
Language: eng
Source: Repositório Institucional da UNESP
Download full: http://dx.doi.org/10.3390/ma17010250
https://hdl.handle.net/11449/304765
Summary: β-type titanium alloys with a body-centered cubic structure are highly useful in orthopedics due to their low elastic modulus, lower than other commonly used alloys such as stainless steel and Co-Cr alloys. The formation of the β phase in titanium alloys is achieved through β-stabilizing elements such as Nb, Mo, and Ta. To produce new β alloys with a low modulus of elasticity, this work aimed to produce our alloy system for biomedical applications (Ti-50Nb-Mo). The alloys were produced by arc-melting and have the following compositions Ti-50Nb-xMo (x = 0, 3, 5, 7, and 12 wt% Mo). The alloys were characterized by density, X-ray diffraction, scanning electron microscopy, microhardness, and elastic modulus. It is worth highlighting that this new set of alloys of the Ti-50Nb-Mo system produced in this study is unprecedented; due to this, there needs to be a report in the literature on the production and structural characterization, hardness, and elastic modulus analyses. The microstructure of the alloys has an exclusively β phase (with bcc crystalline structure). The results show that adding molybdenum considerably increased the microhardness and decreased the elastic modulus, with values around 80 GPa, below the metallic materials used commercially for this type of application. From the produced alloys, Ti-50Nb-12Mo is highlighted due to its lower elastic modulus.
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spelling Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applicationselastic modulushardnessmaterials characterizationTi-50Nb-xMo alloysβ-type titanium alloys with a body-centered cubic structure are highly useful in orthopedics due to their low elastic modulus, lower than other commonly used alloys such as stainless steel and Co-Cr alloys. The formation of the β phase in titanium alloys is achieved through β-stabilizing elements such as Nb, Mo, and Ta. To produce new β alloys with a low modulus of elasticity, this work aimed to produce our alloy system for biomedical applications (Ti-50Nb-Mo). The alloys were produced by arc-melting and have the following compositions Ti-50Nb-xMo (x = 0, 3, 5, 7, and 12 wt% Mo). The alloys were characterized by density, X-ray diffraction, scanning electron microscopy, microhardness, and elastic modulus. It is worth highlighting that this new set of alloys of the Ti-50Nb-Mo system produced in this study is unprecedented; due to this, there needs to be a report in the literature on the production and structural characterization, hardness, and elastic modulus analyses. The microstructure of the alloys has an exclusively β phase (with bcc crystalline structure). The results show that adding molybdenum considerably increased the microhardness and decreased the elastic modulus, with values around 80 GPa, below the metallic materials used commercially for this type of application. From the produced alloys, Ti-50Nb-12Mo is highlighted due to its lower elastic modulus.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Instituto Federal de São Paulo, Campus Caraguatatuba, SPLaboratório de Anelasticidade e Biomateriais UNESP—Universidade Estadual Paulista, SPLaboratório de Anelasticidade e Biomateriais UNESP—Universidade Estadual Paulista, SPCAPES: 1534791CNPq: 314.810/2021Instituto Federal de São PauloUniversidade Estadual Paulista (UNESP)Martins Junior, José Roberto SeverinoKuroda, Pedro Akira Bazaglia [UNESP]Grandini, Carlos Roberto [UNESP]2025-04-29T20:00:46Z2024-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.3390/ma17010250Materials, v. 17, n. 1, 2024.1996-1944https://hdl.handle.net/11449/30476510.3390/ma170102502-s2.0-85181922646Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMaterialsinfo:eu-repo/semantics/openAccess2025-04-30T14:05:18Zoai:repositorio.unesp.br:11449/304765Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestrepositoriounesp@unesp.bropendoar:29462025-04-30T14:05:18Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
title Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
spellingShingle Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
Martins Junior, José Roberto Severino
elastic modulus
hardness
materials characterization
Ti-50Nb-xMo alloys
title_short Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
title_full Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
title_fullStr Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
title_full_unstemmed Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
title_sort Investigation of the Chemical Composition, Microstructure, Density, Microhardness, and Elastic Modulus of the New β Ti-50Nb-xMo Alloys for Biomedical Applications
author Martins Junior, José Roberto Severino
author_facet Martins Junior, José Roberto Severino
Kuroda, Pedro Akira Bazaglia [UNESP]
Grandini, Carlos Roberto [UNESP]
author_role author
author2 Kuroda, Pedro Akira Bazaglia [UNESP]
Grandini, Carlos Roberto [UNESP]
author2_role author
author
dc.contributor.none.fl_str_mv Instituto Federal de São Paulo
Universidade Estadual Paulista (UNESP)
dc.contributor.author.fl_str_mv Martins Junior, José Roberto Severino
Kuroda, Pedro Akira Bazaglia [UNESP]
Grandini, Carlos Roberto [UNESP]
dc.subject.por.fl_str_mv elastic modulus
hardness
materials characterization
Ti-50Nb-xMo alloys
topic elastic modulus
hardness
materials characterization
Ti-50Nb-xMo alloys
description β-type titanium alloys with a body-centered cubic structure are highly useful in orthopedics due to their low elastic modulus, lower than other commonly used alloys such as stainless steel and Co-Cr alloys. The formation of the β phase in titanium alloys is achieved through β-stabilizing elements such as Nb, Mo, and Ta. To produce new β alloys with a low modulus of elasticity, this work aimed to produce our alloy system for biomedical applications (Ti-50Nb-Mo). The alloys were produced by arc-melting and have the following compositions Ti-50Nb-xMo (x = 0, 3, 5, 7, and 12 wt% Mo). The alloys were characterized by density, X-ray diffraction, scanning electron microscopy, microhardness, and elastic modulus. It is worth highlighting that this new set of alloys of the Ti-50Nb-Mo system produced in this study is unprecedented; due to this, there needs to be a report in the literature on the production and structural characterization, hardness, and elastic modulus analyses. The microstructure of the alloys has an exclusively β phase (with bcc crystalline structure). The results show that adding molybdenum considerably increased the microhardness and decreased the elastic modulus, with values around 80 GPa, below the metallic materials used commercially for this type of application. From the produced alloys, Ti-50Nb-12Mo is highlighted due to its lower elastic modulus.
publishDate 2024
dc.date.none.fl_str_mv 2024-01-01
2025-04-29T20:00:46Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.3390/ma17010250
Materials, v. 17, n. 1, 2024.
1996-1944
https://hdl.handle.net/11449/304765
10.3390/ma17010250
2-s2.0-85181922646
url http://dx.doi.org/10.3390/ma17010250
https://hdl.handle.net/11449/304765
identifier_str_mv Materials, v. 17, n. 1, 2024.
1996-1944
10.3390/ma17010250
2-s2.0-85181922646
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Materials
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv repositoriounesp@unesp.br
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