Benchmarking diamond surface preparation and fluorination via inductively coupled plasma-reactive ion etching

• Main Author: Gray, Tia
• Publication Date: 2024
• Other Authors: Zhang, Xiang, Biswas, Abhijit, Terlier, Tanguy, Oliveira, Eliezer F. [UNESP], Puthirath, Anand B., Li, Chenxi, Pieshkov, Tymofii S., Garratt, Elias J., Neupane, Mahesh R., Pate, Bradford B., Birdwell, A. Glen, Ivanov, Tony G., Vajtai, Robert, Ajayan, Pulickel M.
• Format: Article
• Language: eng
• Source: Repositório Institucional da UNESP
• Download full: http://dx.doi.org/10.1016/j.carbon.2024.119366; https://hdl.handle.net/11449/303257
• topic: Contact angle; Diamond; Fluorination; Reactive ion etching; Surface morphology

Diamond, renowned for its exceptional semiconducting properties, stands out as a promising material for high-performance power electronics, optics, quantum, and biosensing technologies. This study methodically investigates the optimization of polycrystalline diamond (PCD) substrate surfaces through Inductively Coupled Plasma Reactive Ion Etching (ICP-RIE). Various parameters, including gaseous species, flow rate, coil power, and bias power were tuned to understand their impact on surface morphology and chemistry. A thorough characterization, encompassing chemical, spectroscopic, and microscopic methods, shed light on the effects of different ICP-RIE conditions on surface properties. CF4/O2 plasma emerged as a viable treatment for achieving smooth PCD surfaces with minimal etch pit formation. Most notably, surface fluorination, a critical aspect of increasing chemical and thermal stability, was successfully accomplished using CF4, SF6, and other F-containing plasmas. The fluorine concentration and surface chemistry variations were studied, with high resolution X-ray Photoelectron Spectroscopy unveiling differences amongst the sp2 C phase, sp3 C phase, C–O, C[dbnd]O, and C–F bonds. Time-of-flight secondary Ion Mass Spectrometry (ToF-SIMS) and depth-profile analysis unveiled a consistent surface fluorination pattern with CF4/O2 treatment. Furthermore, contact angle measurements showcased heightened hydrophobicity. This study provides valuable insights into precise diamond surface engineering, important for the development of future diamond-based semiconductor technologies.