Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC

Bibliographic Details
Main Author: DÃbora Scharamm Bezerra
Publication Date: 2014
Format: Master thesis
Language: por
Source: Biblioteca Digital de Teses e Dissertações da UFC
Download full: http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=12578
Summary: Despite Institutions Teaching and Research possess a fundamental role in the formation of its professionals, the lack of oversight and vision, along with the improper disposal of chemical waste, have led many laboratories and, consequently, many universities, polluting the environment, promote material waste and mismanagement perform its chemical waste liabilities and assets. Within this context, this work aims to propose a system for managing chemical waste generated at the Laboratory of Environmental Sanitation, Department of Hydraulic and Environmental Engineering, Federal University of CearÃ, with a focus on preventive actions to minimize waste, followed by their treatment. For this, the methodology consisted initially of completing the inventory of chemical waste liabilities followed by characterization of unidentified reagents, which are amenable to reuse. Based on a questionnaire, it was possible to know the main active chemical analyzes generating waste and the situation of how these waste materials were processed in the laboratory. These residues were analyzed for the presence of heavy metals and submitted the metal copper in waste from the analysis of NTK and silver, mercury and hexavalent chromium in the waste analysis of COD. Thus, treatments have been proposed for each metal, which were quantitated using the techniques of X-ray fluorescence and atomic absorption spectroscopy, flame. It was possible to characterize 85.71% of unidentified reagents and thus reuse of 58,125% of the Labosan passive chemical waste. Through the technique of atomic absorption spectroscopy, flame (FAAS), the residue of NKT analysis showed 100% removal of this cover, while the COD analysis of the residue showed removal of 99.984% 99.975% silver and chrome . Thus, it was observed that the final supernatants of chrome and copper treatments showed results within the limits established by CONAMA Resolution No. 430/2011. Through the technique of fluorescence (XRF) X-rays, it was found that solid precipitates of heavy metals showed high purities, such as silver which had purity of 99.223% and the mercury that had purity of 93.540%. Thus, the study supports the need to investigate further all waste generated in Labosan, as also with the implementation of a program of Chemical Waste Management in the UFC.
id UFC_8782d8c2a34b9d92d2f0bb48dfde158c
oai_identifier_str oai:www.teses.ufc.br:8582
network_acronym_str UFC
network_name_str Biblioteca Digital de Teses e Dissertações da UFC
spelling info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisImplementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFCImplantaÃÃo de um sistema de gerenciamento de resÃduos quÃmicos no laboratÃrio de saneamento ambiental da UFC2014-08-22Ana BÃrbara de AraÃjo Nunes57660972200http://lattes.cnpq.br/1624361530002492Simone da Silveira Sà Borges16999517304http://lattes.cnpq.br/3147703167452385Andrà Bezerra dos Santos50211480363http://lattes.cnpq.br/3626519258208111Rivelino Martins Cavalcante57565147249http://lattes.cnpq.br/225312752701252203270690312http://lattes.cnpq.br/0834728791985502DÃbora Scharamm BezerraUniversidade Federal do CearÃPrograma de PÃs-GraduaÃÃo em Engenharia CivilUFCBRGerenciamento de resÃduosGestÃo AmbientalWaste management, chemical wastesENGENHARIA CIVILDespite Institutions Teaching and Research possess a fundamental role in the formation of its professionals, the lack of oversight and vision, along with the improper disposal of chemical waste, have led many laboratories and, consequently, many universities, polluting the environment, promote material waste and mismanagement perform its chemical waste liabilities and assets. Within this context, this work aims to propose a system for managing chemical waste generated at the Laboratory of Environmental Sanitation, Department of Hydraulic and Environmental Engineering, Federal University of CearÃ, with a focus on preventive actions to minimize waste, followed by their treatment. For this, the methodology consisted initially of completing the inventory of chemical waste liabilities followed by characterization of unidentified reagents, which are amenable to reuse. Based on a questionnaire, it was possible to know the main active chemical analyzes generating waste and the situation of how these waste materials were processed in the laboratory. These residues were analyzed for the presence of heavy metals and submitted the metal copper in waste from the analysis of NTK and silver, mercury and hexavalent chromium in the waste analysis of COD. Thus, treatments have been proposed for each metal, which were quantitated using the techniques of X-ray fluorescence and atomic absorption spectroscopy, flame. It was possible to characterize 85.71% of unidentified reagents and thus reuse of 58,125% of the Labosan passive chemical waste. Through the technique of atomic absorption spectroscopy, flame (FAAS), the residue of NKT analysis showed 100% removal of this cover, while the COD analysis of the residue showed removal of 99.984% 99.975% silver and chrome . Thus, it was observed that the final supernatants of chrome and copper treatments showed results within the limits established by CONAMA Resolution No. 430/2011. Through the technique of fluorescence (XRF) X-rays, it was found that solid precipitates of heavy metals showed high purities, such as silver which had purity of 99.223% and the mercury that had purity of 93.540%. Thus, the study supports the need to investigate further all waste generated in Labosan, as also with the implementation of a program of Chemical Waste Management in the UFC.Apesar das InstituiÃÃes de Ensino e Pesquisa possuÃrem um papel fundamental na formaÃÃo de seus profissionais, a falta de fiscalizaÃÃo e de visÃo, juntamente com o descarte inadequado dos resÃduos quÃmicos, levaram muitos laboratÃrios e, consequentemente, muitas universidades, a poluir o meio ambiente, promover o desperdÃcio de material e realizar o mau gerenciamento dos seus resÃduos quÃmicos passivos e ativos. Dentro desse contexto, este trabalho objetiva propor um sistema de gerenciamento dos resÃduos quÃmicos gerados no LaboratÃrio de Saneamento Ambiental do Departamento de Engenharia HidrÃulica e Ambiental da Universidade Federal do CearÃ, com enfoque nas aÃÃes preventivas de minimizaÃÃo dos resÃduos, seguido do seu tratamento. Para isso, a metodologia constituiu-se inicialmente da realizaÃÃo do inventÃrio dos resÃduos quÃmicos passivos seguido da caracterizaÃÃo dos reagentes nÃo identificados, os quais sÃo passÃveis de reaproveitamento. Com base na aplicaÃÃo de um questionÃrio, foi possÃvel conhecer as principais anÃlises geradoras de resÃduos quÃmicos ativos e a situaÃÃo de como esses materiais residuais eram tratados no laboratÃrio. Esses resÃduos foram analisados quanto à presenÃa de metais pesados, tendo apresentado o metal cobre nos resÃduos provenientes da anÃlise de NTK e prata, mercÃrio e cromo hexavalente nos resÃduos da anÃlise de DQO. Assim, foram propostos tratamentos para cada metal, os quais foram quantificados utilizando as tÃcnicas de fluorescÃncia de raios-X e espectroscopia de absorÃÃo atÃmica de chama. Conseguiu-se a caracterizaÃÃo de 85,71% dos reagentes nÃo identificados e com isso a reutilizaÃÃo de 58,125% dos resÃduos quÃmicos passivos do Labosan. AtravÃs da tÃcnica de espectroscopia de absorÃÃo atÃmica de chama (FAAS), o resÃduo da anÃlise de NTK apresentou remoÃÃo de 100% do cobre presente, enquanto que o resÃduo da anÃlise de DQO apresentou remoÃÃo de 99,984% da prata e de 99,975% do cromo. Assim, foi observado que os sobrenadantes finais dos tratamentos do cromo e do cobre apresentaram resultados dentro dos limites estabelecidos pela ResoluÃÃo CONAMA n 430/2011. AtravÃs da tÃcnica de fluorescÃncia de raios-X (FRX), verificou-se que os sÃlidos precipitados dos metais pesados apresentaram elevadas purezas, como à o caso da prata que apresentou pureza de 99,223% e do mercÃrio que apresentou pureza de 93,540%. Assim, o estudo corrobora com a necessidade de investigar mais profundamente todos os resÃduos gerados no Labosan, como tambÃm com a implantaÃÃo de um Programa de Gerenciamento de ResÃduos QuÃmicos na UFC.CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superiorhttp://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=12578application/pdfinfo:eu-repo/semantics/openAccessporreponame:Biblioteca Digital de Teses e Dissertações da UFCinstname:Universidade Federal do Cearáinstacron:UFC2019-01-21T11:25:45Zmail@mail.com -
dc.title.en.fl_str_mv Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
dc.title.alternative.pt.fl_str_mv ImplantaÃÃo de um sistema de gerenciamento de resÃduos quÃmicos no laboratÃrio de saneamento ambiental da UFC
title Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
spellingShingle Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
DÃbora Scharamm Bezerra
Gerenciamento de resÃduos
GestÃo Ambiental
Waste management, chemical wastes
ENGENHARIA CIVIL
title_short Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
title_full Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
title_fullStr Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
title_full_unstemmed Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
title_sort Implementation of a system for managing chemical waste in the laboratory of environmental sanitation of the UFC
author DÃbora Scharamm Bezerra
author_facet DÃbora Scharamm Bezerra
author_role author
dc.contributor.advisor1.fl_str_mv Ana BÃrbara de AraÃjo Nunes
dc.contributor.advisor1ID.fl_str_mv 57660972200
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/1624361530002492
dc.contributor.advisor-co1.fl_str_mv Simone da Silveira SÃ Borges
dc.contributor.advisor-co1ID.fl_str_mv 16999517304
dc.contributor.advisor-co1Lattes.fl_str_mv http://lattes.cnpq.br/3147703167452385
dc.contributor.referee1.fl_str_mv Andrà Bezerra dos Santos
dc.contributor.referee1ID.fl_str_mv 50211480363
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/3626519258208111
dc.contributor.referee2.fl_str_mv Rivelino Martins Cavalcante
dc.contributor.referee2ID.fl_str_mv 57565147249
dc.contributor.referee2Lattes.fl_str_mv http://lattes.cnpq.br/2253127527012522
dc.contributor.authorID.fl_str_mv 03270690312
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/0834728791985502
dc.contributor.author.fl_str_mv DÃbora Scharamm Bezerra
contributor_str_mv Ana BÃrbara de AraÃjo Nunes
Simone da Silveira SÃ Borges
Andrà Bezerra dos Santos
Rivelino Martins Cavalcante
dc.subject.por.fl_str_mv Gerenciamento de resÃduos
GestÃo Ambiental
topic Gerenciamento de resÃduos
GestÃo Ambiental
Waste management, chemical wastes
ENGENHARIA CIVIL
dc.subject.eng.fl_str_mv Waste management, chemical wastes
dc.subject.cnpq.fl_str_mv ENGENHARIA CIVIL
dc.description.sponsorship.fl_txt_mv CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior
dc.description.abstract.por.fl_txt_mv Despite Institutions Teaching and Research possess a fundamental role in the formation of its professionals, the lack of oversight and vision, along with the improper disposal of chemical waste, have led many laboratories and, consequently, many universities, polluting the environment, promote material waste and mismanagement perform its chemical waste liabilities and assets. Within this context, this work aims to propose a system for managing chemical waste generated at the Laboratory of Environmental Sanitation, Department of Hydraulic and Environmental Engineering, Federal University of CearÃ, with a focus on preventive actions to minimize waste, followed by their treatment. For this, the methodology consisted initially of completing the inventory of chemical waste liabilities followed by characterization of unidentified reagents, which are amenable to reuse. Based on a questionnaire, it was possible to know the main active chemical analyzes generating waste and the situation of how these waste materials were processed in the laboratory. These residues were analyzed for the presence of heavy metals and submitted the metal copper in waste from the analysis of NTK and silver, mercury and hexavalent chromium in the waste analysis of COD. Thus, treatments have been proposed for each metal, which were quantitated using the techniques of X-ray fluorescence and atomic absorption spectroscopy, flame. It was possible to characterize 85.71% of unidentified reagents and thus reuse of 58,125% of the Labosan passive chemical waste. Through the technique of atomic absorption spectroscopy, flame (FAAS), the residue of NKT analysis showed 100% removal of this cover, while the COD analysis of the residue showed removal of 99.984% 99.975% silver and chrome . Thus, it was observed that the final supernatants of chrome and copper treatments showed results within the limits established by CONAMA Resolution No. 430/2011. Through the technique of fluorescence (XRF) X-rays, it was found that solid precipitates of heavy metals showed high purities, such as silver which had purity of 99.223% and the mercury that had purity of 93.540%. Thus, the study supports the need to investigate further all waste generated in Labosan, as also with the implementation of a program of Chemical Waste Management in the UFC.
Apesar das InstituiÃÃes de Ensino e Pesquisa possuÃrem um papel fundamental na formaÃÃo de seus profissionais, a falta de fiscalizaÃÃo e de visÃo, juntamente com o descarte inadequado dos resÃduos quÃmicos, levaram muitos laboratÃrios e, consequentemente, muitas universidades, a poluir o meio ambiente, promover o desperdÃcio de material e realizar o mau gerenciamento dos seus resÃduos quÃmicos passivos e ativos. Dentro desse contexto, este trabalho objetiva propor um sistema de gerenciamento dos resÃduos quÃmicos gerados no LaboratÃrio de Saneamento Ambiental do Departamento de Engenharia HidrÃulica e Ambiental da Universidade Federal do CearÃ, com enfoque nas aÃÃes preventivas de minimizaÃÃo dos resÃduos, seguido do seu tratamento. Para isso, a metodologia constituiu-se inicialmente da realizaÃÃo do inventÃrio dos resÃduos quÃmicos passivos seguido da caracterizaÃÃo dos reagentes nÃo identificados, os quais sÃo passÃveis de reaproveitamento. Com base na aplicaÃÃo de um questionÃrio, foi possÃvel conhecer as principais anÃlises geradoras de resÃduos quÃmicos ativos e a situaÃÃo de como esses materiais residuais eram tratados no laboratÃrio. Esses resÃduos foram analisados quanto à presenÃa de metais pesados, tendo apresentado o metal cobre nos resÃduos provenientes da anÃlise de NTK e prata, mercÃrio e cromo hexavalente nos resÃduos da anÃlise de DQO. Assim, foram propostos tratamentos para cada metal, os quais foram quantificados utilizando as tÃcnicas de fluorescÃncia de raios-X e espectroscopia de absorÃÃo atÃmica de chama. Conseguiu-se a caracterizaÃÃo de 85,71% dos reagentes nÃo identificados e com isso a reutilizaÃÃo de 58,125% dos resÃduos quÃmicos passivos do Labosan. AtravÃs da tÃcnica de espectroscopia de absorÃÃo atÃmica de chama (FAAS), o resÃduo da anÃlise de NTK apresentou remoÃÃo de 100% do cobre presente, enquanto que o resÃduo da anÃlise de DQO apresentou remoÃÃo de 99,984% da prata e de 99,975% do cromo. Assim, foi observado que os sobrenadantes finais dos tratamentos do cromo e do cobre apresentaram resultados dentro dos limites estabelecidos pela ResoluÃÃo CONAMA n 430/2011. AtravÃs da tÃcnica de fluorescÃncia de raios-X (FRX), verificou-se que os sÃlidos precipitados dos metais pesados apresentaram elevadas purezas, como à o caso da prata que apresentou pureza de 99,223% e do mercÃrio que apresentou pureza de 93,540%. Assim, o estudo corrobora com a necessidade de investigar mais profundamente todos os resÃduos gerados no Labosan, como tambÃm com a implantaÃÃo de um Programa de Gerenciamento de ResÃduos QuÃmicos na UFC.
description Despite Institutions Teaching and Research possess a fundamental role in the formation of its professionals, the lack of oversight and vision, along with the improper disposal of chemical waste, have led many laboratories and, consequently, many universities, polluting the environment, promote material waste and mismanagement perform its chemical waste liabilities and assets. Within this context, this work aims to propose a system for managing chemical waste generated at the Laboratory of Environmental Sanitation, Department of Hydraulic and Environmental Engineering, Federal University of CearÃ, with a focus on preventive actions to minimize waste, followed by their treatment. For this, the methodology consisted initially of completing the inventory of chemical waste liabilities followed by characterization of unidentified reagents, which are amenable to reuse. Based on a questionnaire, it was possible to know the main active chemical analyzes generating waste and the situation of how these waste materials were processed in the laboratory. These residues were analyzed for the presence of heavy metals and submitted the metal copper in waste from the analysis of NTK and silver, mercury and hexavalent chromium in the waste analysis of COD. Thus, treatments have been proposed for each metal, which were quantitated using the techniques of X-ray fluorescence and atomic absorption spectroscopy, flame. It was possible to characterize 85.71% of unidentified reagents and thus reuse of 58,125% of the Labosan passive chemical waste. Through the technique of atomic absorption spectroscopy, flame (FAAS), the residue of NKT analysis showed 100% removal of this cover, while the COD analysis of the residue showed removal of 99.984% 99.975% silver and chrome . Thus, it was observed that the final supernatants of chrome and copper treatments showed results within the limits established by CONAMA Resolution No. 430/2011. Through the technique of fluorescence (XRF) X-rays, it was found that solid precipitates of heavy metals showed high purities, such as silver which had purity of 99.223% and the mercury that had purity of 93.540%. Thus, the study supports the need to investigate further all waste generated in Labosan, as also with the implementation of a program of Chemical Waste Management in the UFC.
publishDate 2014
dc.date.issued.fl_str_mv 2014-08-22
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
status_str publishedVersion
format masterThesis
dc.identifier.uri.fl_str_mv http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=12578
url http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=12578
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal do CearÃ
dc.publisher.program.fl_str_mv Programa de PÃs-GraduaÃÃo em Engenharia Civil
dc.publisher.initials.fl_str_mv UFC
dc.publisher.country.fl_str_mv BR
publisher.none.fl_str_mv Universidade Federal do CearÃ
dc.source.none.fl_str_mv reponame:Biblioteca Digital de Teses e Dissertações da UFC
instname:Universidade Federal do Ceará
instacron:UFC
reponame_str Biblioteca Digital de Teses e Dissertações da UFC
collection Biblioteca Digital de Teses e Dissertações da UFC
instname_str Universidade Federal do Ceará
instacron_str UFC
institution UFC
repository.name.fl_str_mv -
repository.mail.fl_str_mv mail@mail.com
_version_ 1643295193059819520