Enzymatic hydrolysis of PTT polymers and oligomers
Main Author: | |
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Publication Date: | 2008 |
Other Authors: | , , , , , |
Format: | Article |
Language: | eng |
Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
Download full: | https://hdl.handle.net/1822/13849 |
Summary: | Article in Press |
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Enzymatic hydrolysis of PTT polymers and oligomersPoly(trimethylene terephthalate)PolyesterPolyesteraseCutinaseScience & TechnologyArticle in PressOligomers and polymers (film, fabrics) of the linear aromatic polyester poly(trimethylene terephthalate) (PTT) were treated with polyesterases from Thermomyces lanuginosus, Penicillium citrinum, Thermobifida fusca and Fusarium solani pisi. The cutinase from T. fusca was found to release the highest amounts of hydrolysis products from PTT materials and was able to open and hydrolyse a cyclic PTT dimer according to RP-HPLC–UV detection. In contrast, the lipase from T. lanuginosus also showed activity on the PTT fibres and on bis(3-hydroxypropyl) terephthalate (BHPT) but was not able to hydrolyse the polymer film, mono(3-hydroxypropyl) terephthalate (MHPT) nor the cyclic dimer of PTT. As control enzymes inhibited with mercury chloride were used. Surface hydrophilicity changes were investigated with contact angle measurements and the degree of crystallinity changes were determined with DSC.ElsevierUniversidade do MinhoEberl, A.Heumann, SonjaKotek, R.Kaufmann, F.Mitscher, S.Paulo, Artur CavacoGübitz, Georg M.2008-052008-05-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/13849eng0168-165610.1016/j.jbiotec.2008.02.01518405994http://www.sciencedirect.com/science/article/pii/S0168165608000667info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2025-04-12T04:34:14Zoai:repositorium.sdum.uminho.pt:1822/13849Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T15:25:00.250434Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
dc.title.none.fl_str_mv |
Enzymatic hydrolysis of PTT polymers and oligomers |
title |
Enzymatic hydrolysis of PTT polymers and oligomers |
spellingShingle |
Enzymatic hydrolysis of PTT polymers and oligomers Eberl, A. Poly(trimethylene terephthalate) Polyester Polyesterase Cutinase Science & Technology |
title_short |
Enzymatic hydrolysis of PTT polymers and oligomers |
title_full |
Enzymatic hydrolysis of PTT polymers and oligomers |
title_fullStr |
Enzymatic hydrolysis of PTT polymers and oligomers |
title_full_unstemmed |
Enzymatic hydrolysis of PTT polymers and oligomers |
title_sort |
Enzymatic hydrolysis of PTT polymers and oligomers |
author |
Eberl, A. |
author_facet |
Eberl, A. Heumann, Sonja Kotek, R. Kaufmann, F. Mitscher, S. Paulo, Artur Cavaco Gübitz, Georg M. |
author_role |
author |
author2 |
Heumann, Sonja Kotek, R. Kaufmann, F. Mitscher, S. Paulo, Artur Cavaco Gübitz, Georg M. |
author2_role |
author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Eberl, A. Heumann, Sonja Kotek, R. Kaufmann, F. Mitscher, S. Paulo, Artur Cavaco Gübitz, Georg M. |
dc.subject.por.fl_str_mv |
Poly(trimethylene terephthalate) Polyester Polyesterase Cutinase Science & Technology |
topic |
Poly(trimethylene terephthalate) Polyester Polyesterase Cutinase Science & Technology |
description |
Article in Press |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-05 2008-05-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/13849 |
url |
https://hdl.handle.net/1822/13849 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0168-1656 10.1016/j.jbiotec.2008.02.015 18405994 http://www.sciencedirect.com/science/article/pii/S0168165608000667 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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Elsevier |
publisher.none.fl_str_mv |
Elsevier |
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