Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions
Autor(a) principal: | |
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Data de Publicação: | 2023 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
Texto Completo: | https://hdl.handle.net/10316/113152 https://doi.org/10.3390/pr11061701 |
Resumo: | The influence of oligosaccharides ( -cyclodextrin, -cyclodextrin and -cyclodextrin), and a polysaccharide, sodium hyaluronate (NaHy), on the diffusion of aqueous solutions of cobalt and chromium chlorides has been investigated. Cobalt and chromium are constituents of metal alloys for biomedical use, including dental prostheses. Thus, the release of these ions in the human body can lead to harmful biological effects. The interaction of metal ions with saccharides might have information on the role of mouthwashes in preventing these effects. This interaction has been assessed by measuring multicomponent intermolecular diffusion coefficients at 298.15 K. It has been found that -cyclodextrin has the highest interaction towards cobalt and chromium ions. This work will contribute to unveiling the mechanisms responsible for transport by diffusion in aqueous solutions, and, therefore, mitigating the potential toxicity inherent to those metal ions. |
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Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium IonscobaltchromiumCo-Cr alloyscyclodextrinshyaluronic aciddiffusion coefficientThe influence of oligosaccharides ( -cyclodextrin, -cyclodextrin and -cyclodextrin), and a polysaccharide, sodium hyaluronate (NaHy), on the diffusion of aqueous solutions of cobalt and chromium chlorides has been investigated. Cobalt and chromium are constituents of metal alloys for biomedical use, including dental prostheses. Thus, the release of these ions in the human body can lead to harmful biological effects. The interaction of metal ions with saccharides might have information on the role of mouthwashes in preventing these effects. This interaction has been assessed by measuring multicomponent intermolecular diffusion coefficients at 298.15 K. It has been found that -cyclodextrin has the highest interaction towards cobalt and chromium ions. This work will contribute to unveiling the mechanisms responsible for transport by diffusion in aqueous solutions, and, therefore, mitigating the potential toxicity inherent to those metal ions.COMPETE Programme (Operational Programme for Competitiveness) and CIROS, Centro de Investigação e Inovação em Ciências Dentárias da FMUC.MDPI2023info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://hdl.handle.net/10316/113152https://hdl.handle.net/10316/113152https://doi.org/10.3390/pr11061701eng2227-9717Trindade, Ana C. V.Fangaia, Sónia I. G.Nicolau, Pedro M. G.Messias, AnaRibeiro, Ana C. F.Silva, Daniela S. A.Valente, Artur J. M.Rodrigo, M. MeliaEsteso, Miguel Á.info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-12-17T10:57:45Zoai:estudogeral.uc.pt:10316/113152Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T06:05:43.356699Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
dc.title.none.fl_str_mv |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
title |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
spellingShingle |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions Trindade, Ana C. V. cobalt chromium Co-Cr alloys cyclodextrins hyaluronic acid diffusion coefficient |
title_short |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
title_full |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
title_fullStr |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
title_full_unstemmed |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
title_sort |
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions |
author |
Trindade, Ana C. V. |
author_facet |
Trindade, Ana C. V. Fangaia, Sónia I. G. Nicolau, Pedro M. G. Messias, Ana Ribeiro, Ana C. F. Silva, Daniela S. A. Valente, Artur J. M. Rodrigo, M. Melia Esteso, Miguel Á. |
author_role |
author |
author2 |
Fangaia, Sónia I. G. Nicolau, Pedro M. G. Messias, Ana Ribeiro, Ana C. F. Silva, Daniela S. A. Valente, Artur J. M. Rodrigo, M. Melia Esteso, Miguel Á. |
author2_role |
author author author author author author author author |
dc.contributor.author.fl_str_mv |
Trindade, Ana C. V. Fangaia, Sónia I. G. Nicolau, Pedro M. G. Messias, Ana Ribeiro, Ana C. F. Silva, Daniela S. A. Valente, Artur J. M. Rodrigo, M. Melia Esteso, Miguel Á. |
dc.subject.por.fl_str_mv |
cobalt chromium Co-Cr alloys cyclodextrins hyaluronic acid diffusion coefficient |
topic |
cobalt chromium Co-Cr alloys cyclodextrins hyaluronic acid diffusion coefficient |
description |
The influence of oligosaccharides ( -cyclodextrin, -cyclodextrin and -cyclodextrin), and a polysaccharide, sodium hyaluronate (NaHy), on the diffusion of aqueous solutions of cobalt and chromium chlorides has been investigated. Cobalt and chromium are constituents of metal alloys for biomedical use, including dental prostheses. Thus, the release of these ions in the human body can lead to harmful biological effects. The interaction of metal ions with saccharides might have information on the role of mouthwashes in preventing these effects. This interaction has been assessed by measuring multicomponent intermolecular diffusion coefficients at 298.15 K. It has been found that -cyclodextrin has the highest interaction towards cobalt and chromium ions. This work will contribute to unveiling the mechanisms responsible for transport by diffusion in aqueous solutions, and, therefore, mitigating the potential toxicity inherent to those metal ions. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/10316/113152 https://hdl.handle.net/10316/113152 https://doi.org/10.3390/pr11061701 |
url |
https://hdl.handle.net/10316/113152 https://doi.org/10.3390/pr11061701 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2227-9717 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
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RCAAP |
reponame_str |
Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
repository.name.fl_str_mv |
Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia |
repository.mail.fl_str_mv |
info@rcaap.pt |
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1833602574850195456 |