K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices

Bibliographic Details
Main Author: Fernandes, M.
Publication Date: 2011
Other Authors: Rodrigues, L. C., Ferreira, R. A. Sá, Gonçalves, A., Fortunato, E., Silva, Maria Manuela, Smith, Michael John, Zea Bermudez, V. de, Carlos, L. D.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: https://hdl.handle.net/1822/14491
Summary: In Press; available online 10 November 2011
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spelling K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devicesSolid polymer electrolyteConductivityThermal analysisElectrochromic devicePoly(epsilon-caprolactone)/siloxane biohybrid elctrolytesPotassium inflateIonic conductivityPotassium triflateScience & TechnologyIn Press; available online 10 November 2011Sol-gel derived KCF3SO3-doped di-urethane cross-linked poly(ε-caprolactone) (PCL(530))/siloxane ormolytes with ∞ > n ≥ 0.5 (n indicates the number of (C(=O)(CH2)5O) repeat units per K+ ion) have been studied. Xerogel samples with n ≥ 1 are thermally stable up to 235 ºC. A minor proportion of PCL crystallites occur in some dilute-to-concentrated samples. At n ≤ 4 a crystalline PCL(530)/siloxane-KCF3SO3 complex with unknown stoichiometry emerges. At n ≤ 2 this complex coexists with pure salt. At temperatures higher than 40 ºC the composition which exhibits the highest ionic conductivity is n = 21. “Free” anions, weakly coordinated CF3SO3- ions, contact ion pairs and several higher ionic aggregates emerge in all the samples. The K+ ions bond to the oxygen atoms of the carbonyl groups of the urethane and ester groups, of the PCL (530) ether chain and of the triflate ions at all salt concentrations. The ormolytes were successfully used in the production of prototype electrochromic devices (ECDs) that exhibit low switching time and good open circuit memory.. The ECD incorporating the ormolyte with n = 21 displays an average transmittance in the visible region of ca. 55 % in the colored state and 76 % in the bleached state.Fundação para a Ciência e Tecnologia (FCT)ElsevierUniversidade do MinhoFernandes, M.Rodrigues, L. C.Ferreira, R. A. SáGonçalves, A.Fortunato, E.Silva, Maria ManuelaSmith, Michael JohnZea Bermudez, V. deCarlos, L. D.2011-112011-11-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/14491eng0167-273810.1016/j.ssi.2011.10.012The original publication is available at www.elsevier.cominfo:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2025-04-12T04:25:00Zoai:repositorium.sdum.uminho.pt:1822/14491Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T15:08:41.557852Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
title K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
spellingShingle K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
Fernandes, M.
Solid polymer electrolyte
Conductivity
Thermal analysis
Electrochromic device
Poly(epsilon-caprolactone)/siloxane biohybrid elctrolytes
Potassium inflate
Ionic conductivity
Potassium triflate
Science & Technology
title_short K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
title_full K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
title_fullStr K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
title_full_unstemmed K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
title_sort K+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes for electrochromic devices
author Fernandes, M.
author_facet Fernandes, M.
Rodrigues, L. C.
Ferreira, R. A. Sá
Gonçalves, A.
Fortunato, E.
Silva, Maria Manuela
Smith, Michael John
Zea Bermudez, V. de
Carlos, L. D.
author_role author
author2 Rodrigues, L. C.
Ferreira, R. A. Sá
Gonçalves, A.
Fortunato, E.
Silva, Maria Manuela
Smith, Michael John
Zea Bermudez, V. de
Carlos, L. D.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Fernandes, M.
Rodrigues, L. C.
Ferreira, R. A. Sá
Gonçalves, A.
Fortunato, E.
Silva, Maria Manuela
Smith, Michael John
Zea Bermudez, V. de
Carlos, L. D.
dc.subject.por.fl_str_mv Solid polymer electrolyte
Conductivity
Thermal analysis
Electrochromic device
Poly(epsilon-caprolactone)/siloxane biohybrid elctrolytes
Potassium inflate
Ionic conductivity
Potassium triflate
Science & Technology
topic Solid polymer electrolyte
Conductivity
Thermal analysis
Electrochromic device
Poly(epsilon-caprolactone)/siloxane biohybrid elctrolytes
Potassium inflate
Ionic conductivity
Potassium triflate
Science & Technology
description In Press; available online 10 November 2011
publishDate 2011
dc.date.none.fl_str_mv 2011-11
2011-11-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://hdl.handle.net/1822/14491
url https://hdl.handle.net/1822/14491
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0167-2738
10.1016/j.ssi.2011.10.012
The original publication is available at www.elsevier.com
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
_version_ 1833595126462545920

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