Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents

Bibliographic Details
Main Author: Castro, Vânia I. B.
Publication Date: 2018
Other Authors: Mano, Francisca, Reis, Rui L., Paiva, Alexandre, Duarte, Ana Rita C.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: https://doi.org/10.1021/acs.jced.7b01037
Summary: The research leading to these results has received funding provided by Fundacio para a Ciencia e a Tecnologia through the project PTDC/BBB-EBB/1676/2014-DesZyme. Funding from the European Union, Horizon 2020 program has also been granted through project Des.solve (ERC consolidator) ERC-2016-COG 725034. This work was supported by the Associate Laboratory for Green Chemistry, LAQV, which is financed by national funds from FCT/MCTES (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265).
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spelling Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic SolventsEutecticsIonic liquidsSolvents DESsChemistry(all)Chemical Engineering(all)The research leading to these results has received funding provided by Fundacio para a Ciencia e a Tecnologia through the project PTDC/BBB-EBB/1676/2014-DesZyme. Funding from the European Union, Horizon 2020 program has also been granted through project Des.solve (ERC consolidator) ERC-2016-COG 725034. This work was supported by the Associate Laboratory for Green Chemistry, LAQV, which is financed by national funds from FCT/MCTES (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265).In this paper, four natural deep eutectic solvents (NADES) systems were prepared at specific molar ratios, La:Bet (2:1) (lactic acid/betaine), La:Hist (9:1) (lactic acid/histidine), Ma:Bet:H2O (1:2:3) (malic acid/betaine/water) and Ma:Bet:Pro:H2O (1:1:1:2) (malic acid/betaine/proline/water). Their physical and thermodynamic properties were studied, namely viscosity, electrical conductivity, and heat capacity. The viscosity and electrical conductivity were determined as a function of temperature and the correlation for the temperature dependence was obtained and discussed based on Arrhenius theory. The heat capacity for all eutectic systems was measured by differential scanning calorimetry (DSC) over a temperature range of 293.15-363.15 K. The ability of these NADES to reduce cellulose crystallinity was evaluated. Cellulose crystallinity after suspension in these NADES was studied by X-ray diffraction. Cellulose suspended in Ma/Bet/H2O (1:2:3) suffer the highest crystallinity reduction among the systems studied and was about of 20%.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCastro, Vânia I. B.Mano, FranciscaReis, Rui L.Paiva, AlexandreDuarte, Ana Rita C.2019-11-06T23:47:35Z2018-07-122018-07-12T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttps://doi.org/10.1021/acs.jced.7b01037eng0021-9568PURE: 6590183http://www.scopus.com/inward/record.url?scp=85049995821&partnerID=8YFLogxKhttps://doi.org/10.1021/acs.jced.7b01037info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:42:03Zoai:run.unl.pt:10362/86594Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:13:26.070606Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
title Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
spellingShingle Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
Castro, Vânia I. B.
Eutectics
Ionic liquids
Solvents DESs
Chemistry(all)
Chemical Engineering(all)
title_short Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
title_full Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
title_fullStr Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
title_full_unstemmed Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
title_sort Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents
author Castro, Vânia I. B.
author_facet Castro, Vânia I. B.
Mano, Francisca
Reis, Rui L.
Paiva, Alexandre
Duarte, Ana Rita C.
author_role author
author2 Mano, Francisca
Reis, Rui L.
Paiva, Alexandre
Duarte, Ana Rita C.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Castro, Vânia I. B.
Mano, Francisca
Reis, Rui L.
Paiva, Alexandre
Duarte, Ana Rita C.
dc.subject.por.fl_str_mv Eutectics
Ionic liquids
Solvents DESs
Chemistry(all)
Chemical Engineering(all)
topic Eutectics
Ionic liquids
Solvents DESs
Chemistry(all)
Chemical Engineering(all)
description The research leading to these results has received funding provided by Fundacio para a Ciencia e a Tecnologia through the project PTDC/BBB-EBB/1676/2014-DesZyme. Funding from the European Union, Horizon 2020 program has also been granted through project Des.solve (ERC consolidator) ERC-2016-COG 725034. This work was supported by the Associate Laboratory for Green Chemistry, LAQV, which is financed by national funds from FCT/MCTES (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265).
publishDate 2018
dc.date.none.fl_str_mv 2018-07-12
2018-07-12T00:00:00Z
2019-11-06T23:47:35Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://doi.org/10.1021/acs.jced.7b01037
url https://doi.org/10.1021/acs.jced.7b01037
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0021-9568
PURE: 6590183
http://www.scopus.com/inward/record.url?scp=85049995821&partnerID=8YFLogxK
https://doi.org/10.1021/acs.jced.7b01037
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 9
application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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