The tetranuclear copper active site of nitrous oxide reductase: the CuZ center
| Main Author: | |
|---|---|
| Publication Date: | 2011 |
| Other Authors: | , , |
| Format: | Article |
| Language: | eng |
| Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Download full: | http://hdl.handle.net/10362/8620 |
Summary: | J Biol Inorg Chem (2011) 16:183–194 DOI 10.1007/s00775-011-0753-3 |
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The tetranuclear copper active site of nitrous oxide reductase: the CuZ centerCopper proteinsCuZ centerNitrous oxide reductaseDenitrificationJ Biol Inorg Chem (2011) 16:183–194 DOI 10.1007/s00775-011-0753-3This review focuses on the novel CuZ center of nitrous oxide reductase, an important enzyme owing to the environmental significance of the reaction it catalyzes, reduction of nitrous oxide, and the unusual nature of its catalytic center, named CuZ. The structure of the CuZ center, the unique tetranuclear copper center found in this enzyme, opened a novel area of research in metallobiochemistry. In the last decade, there has been progress in defining the structure of the CuZ center, characterizing the mechanism of nitrous oxide reduction, and identifying intermediates of this reaction. In addition, the determination of the structure of the CuZ center allowed a structural interpretation of the spectroscopic data, which was supported by theoretical calculations. The current knowledge of the structure, function, and spectroscopic characterization of the CuZ center is described here. We would like to stress that although many questions have been answered, the CuZ center remains a scientific challenge, with many hypotheses still being formed.SpringerRUNDell’Acqua, SimonePauleta, Sofia R.Moura, IsabelMoura, José J. G.2013-01-30T11:52:05Z20112011-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/8620eng1432-1327info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:12:18Zoai:run.unl.pt:10362/8620Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T16:43:13.360839Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| title |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| spellingShingle |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center Dell’Acqua, Simone Copper proteins CuZ center Nitrous oxide reductase Denitrification |
| title_short |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| title_full |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| title_fullStr |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| title_full_unstemmed |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| title_sort |
The tetranuclear copper active site of nitrous oxide reductase: the CuZ center |
| author |
Dell’Acqua, Simone |
| author_facet |
Dell’Acqua, Simone Pauleta, Sofia R. Moura, Isabel Moura, José J. G. |
| author_role |
author |
| author2 |
Pauleta, Sofia R. Moura, Isabel Moura, José J. G. |
| author2_role |
author author author |
| dc.contributor.none.fl_str_mv |
RUN |
| dc.contributor.author.fl_str_mv |
Dell’Acqua, Simone Pauleta, Sofia R. Moura, Isabel Moura, José J. G. |
| dc.subject.por.fl_str_mv |
Copper proteins CuZ center Nitrous oxide reductase Denitrification |
| topic |
Copper proteins CuZ center Nitrous oxide reductase Denitrification |
| description |
J Biol Inorg Chem (2011) 16:183–194 DOI 10.1007/s00775-011-0753-3 |
| publishDate |
2011 |
| dc.date.none.fl_str_mv |
2011 2011-01-01T00:00:00Z 2013-01-30T11:52:05Z |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
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http://hdl.handle.net/10362/8620 |
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http://hdl.handle.net/10362/8620 |
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eng |
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eng |
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1432-1327 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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Springer |
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Springer |
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