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Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid

Bibliographic Details
Main Author: Ribeiro, Ana P. C.
Publication Date: 2022
Other Authors: Matias, Inês A. S., Carabineiro, Sónia A. C., Martins, Luísa M. D. R. S.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/133133
Summary: UIDB/00100/2020 UIDP/00100/2020 LA/P/0056/2020 IST-ID/119/2018 SFRH/BD/146426/2019 CEEC-INST/00102/2018 UIDB/50006/2020 UIDP/50006/2020 Base-UIDB/50020/2020 Programmatic-UIDP/50020/2020
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spelling Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic AcidAcetic acidCarbonEthane oxidationGoldHeterogeneous catalysisCatalysisPhysical and Theoretical ChemistryUIDB/00100/2020 UIDP/00100/2020 LA/P/0056/2020 IST-ID/119/2018 SFRH/BD/146426/2019 CEEC-INST/00102/2018 UIDB/50006/2020 UIDP/50006/2020 Base-UIDB/50020/2020 Programmatic-UIDP/50020/2020The single-pot efficient oxidation of ethane to acetic acid catalysed by Au(I) or Au(III) compounds, chlorotriphenylphosphinegold(I) (1), chlorotrimethylphosphinegold(I) (2), 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) chloride (3), dichloro(2-pyridinecarboxylato)gold(III) (4), homogenous and supported on different carbon materials: activated carbon (AC), multi-walled carbon nanotubes (CNT) and carbon xerogel (CX), oxidised with nitric acid followed by treatment with NaOH (-ox-Na), is reported. The reactions were performed in water/acetonitrile. The materials were selective for the production of acetic acid, with no trace of by-products being detected. The best homogenous catalysts were complexes 2 and 3 which showed the highest ethane conversion and an acetic acid yield of ca. 21%, followed by 4 and 1. The heterogenised materials showed much better activity than the homogenous counterparts, with acetic acid yields up to 41.4% for 4@CNT-ox-Na, and remarkable selectivity (with acetic acid being the only product detected). The heterogenised catalysts with the best results were reused up to five cycles, with no significant loss of activity, and maintaining high selectivity for acetic acid. 4@CNT-ox-Na showed not only the best catalytic activity but also the best stability during the recycling runs.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNRibeiro, Ana P. C.Matias, Inês A. S.Carabineiro, Sónia A. C.Martins, Luísa M. D. R. S.2022-02-17T23:19:48Z2022-022022-02-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/133133eng2073-4344PURE: 36734554https://doi.org/10.3390/catal12020165info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:59:34Zoai:run.unl.pt:10362/133133Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:30:36.310615Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
title Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
spellingShingle Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
Ribeiro, Ana P. C.
Acetic acid
Carbon
Ethane oxidation
Gold
Heterogeneous catalysis
Catalysis
Physical and Theoretical Chemistry
title_short Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
title_full Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
title_fullStr Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
title_full_unstemmed Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
title_sort Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
author Ribeiro, Ana P. C.
author_facet Ribeiro, Ana P. C.
Matias, Inês A. S.
Carabineiro, Sónia A. C.
Martins, Luísa M. D. R. S.
author_role author
author2 Matias, Inês A. S.
Carabineiro, Sónia A. C.
Martins, Luísa M. D. R. S.
author2_role author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Ribeiro, Ana P. C.
Matias, Inês A. S.
Carabineiro, Sónia A. C.
Martins, Luísa M. D. R. S.
dc.subject.por.fl_str_mv Acetic acid
Carbon
Ethane oxidation
Gold
Heterogeneous catalysis
Catalysis
Physical and Theoretical Chemistry
topic Acetic acid
Carbon
Ethane oxidation
Gold
Heterogeneous catalysis
Catalysis
Physical and Theoretical Chemistry
description UIDB/00100/2020 UIDP/00100/2020 LA/P/0056/2020 IST-ID/119/2018 SFRH/BD/146426/2019 CEEC-INST/00102/2018 UIDB/50006/2020 UIDP/50006/2020 Base-UIDB/50020/2020 Programmatic-UIDP/50020/2020
publishDate 2022
dc.date.none.fl_str_mv 2022-02-17T23:19:48Z
2022-02
2022-02-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/133133
url http://hdl.handle.net/10362/133133
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4344
PURE: 36734554
https://doi.org/10.3390/catal12020165
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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