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Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery

Bibliographic Details
Main Author: Santos, M. S. S.
Publication Date: 2017
Other Authors: Peixoto, L., Ferreira, C. Dias, Mendes, Adélio, Alves, M. M.
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/1822/47247
Summary: ISMET 6 - General Meeting of the International Society for Microbial Electrochemistry and Technology
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spelling Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow batteryISMET 6 - General Meeting of the International Society for Microbial Electrochemistry and TechnologyRedox flow batteries (RFB) are electrochemical systems applied in the conversion and storage of chemical energy in electricity. Red ox chemical species (in soluble form) are the main responsible for the energy storage. Quinones are electroactive molecules applied in RFB because of their chemical and physical properties. The aim of this work is to develop an innovative technology to generate and storage the energy resultant from Bioelectrochemical system (BES). The strategy outlined was coupling a BES with a RFB that present potential to combine bioenergy production and storage in a microbially charged redox flow battery. Firstly, a BES system was studied with Geobacter su/furreducens as biocatalyst to convert a quinone (2,6-anthraquinone) in its respective reduced form, acetate being the carbon source used. The BES presented current intensities around 500 mA.m·2 and power densities around 2 wm· 2. The reduction was assessed visually by a typical colour change (from yellow to dark red) and by cyclic voltammetry. Simultaneously, as a control, the 2,6-anthraquinone was electrochemically reduced applying and controlling the cathode potential where the reduction was also observed by colour change and by cyclic voltammetry. In an RFB, the quinone bioreduced in tlie BES and electrochemically reduced in the electrochemical cell were studied using potassium hexacyanoferrate as the second redox chemical species for discharging/charging cycles in the RFB as the proof of concept of the microbially charged redox flow battery. The study was performed in a 25 cm2 single red ox flow cell (RF) with a constant current density of 0.2 mA.cm2 where coulombic efficiency, voltage efficiency and energy efficiency were observed for 10 cycles.info:eu-repo/semantics/publishedVersionUniversidade do MinhoSantos, M. S. S.Peixoto, L.Ferreira, C. DiasMendes, AdélioAlves, M. M.2017-10-032017-10-03T00:00:00Zconference objectinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttp://hdl.handle.net/1822/47247engMárcia S. S. Santos; Peixoto, L.; Dias-Ferreira, C.; Mendes, Adélio; Alves, M. Madalena, Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery. ISMET 6 - General Meeting of the International Society for Microbial Electrochemistry and Technology. Lisbon, Portugal, Oct 3-6, 95, 2017.http://www.itqb.unl.pt/ismet6info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-11T04:48:07Zoai:repositorium.sdum.uminho.pt:1822/47247Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T14:58:54.887947Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
title Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
spellingShingle Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
Santos, M. S. S.
title_short Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
title_full Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
title_fullStr Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
title_full_unstemmed Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
title_sort Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery
author Santos, M. S. S.
author_facet Santos, M. S. S.
Peixoto, L.
Ferreira, C. Dias
Mendes, Adélio
Alves, M. M.
author_role author
author2 Peixoto, L.
Ferreira, C. Dias
Mendes, Adélio
Alves, M. M.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Santos, M. S. S.
Peixoto, L.
Ferreira, C. Dias
Mendes, Adélio
Alves, M. M.
description ISMET 6 - General Meeting of the International Society for Microbial Electrochemistry and Technology
publishDate 2017
dc.date.none.fl_str_mv 2017-10-03
2017-10-03T00:00:00Z
dc.type.driver.fl_str_mv conference object
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/47247
url http://hdl.handle.net/1822/47247
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Márcia S. S. Santos; Peixoto, L.; Dias-Ferreira, C.; Mendes, Adélio; Alves, M. Madalena, Microbially charged redox flow battery: coupling a bioelectrochemical cell with a redox flow battery. ISMET 6 - General Meeting of the International Society for Microbial Electrochemistry and Technology. Lisbon, Portugal, Oct 3-6, 95, 2017.
http://www.itqb.unl.pt/ismet6
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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