Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel

Bibliographic Details
Main Author: Mirante, Fatima
Publication Date: 2019
Other Authors: Gomes, Neide, Corvo, Marta C., Gago, Sandra, Balula, Salete S.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: https://doi.org/10.1016/j.poly.2019.06.019
Summary: This work was partly funded through the Associate Laboratory for Green Chemistry- LAQV which is financed by national funds from FCT/MCTES (POCI-01-0145-FEDER-007265, UID/QUI/50006/2019) and CENIMAT, I3N (POCI-01-0145-FEDER-007688, UID/CTM/50025/2013), also financed by national funds through the FCT/MCTES, and when appropriate co-financed by the Fundo Europeu de Desenvolvimento Regional (FEDER) under the PT2020 Partnership Agreement. This work is funded by national funds (OE), through FCT – Fundação para a Ciência e a Tecnologia. European Social Fund through the program POPH of QREN. The authors also acknowledge the Portuguese Nuclear Magnetic Resonance Network (PTNMR).
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spelling Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated dieselFuelsHeterogeneous catalysisMesoporous silica nanoparticlesOxidative desulfurizationPolyoxomolybdatePhysical and Theoretical ChemistryInorganic ChemistryMaterials ChemistryThis work was partly funded through the Associate Laboratory for Green Chemistry- LAQV which is financed by national funds from FCT/MCTES (POCI-01-0145-FEDER-007265, UID/QUI/50006/2019) and CENIMAT, I3N (POCI-01-0145-FEDER-007688, UID/CTM/50025/2013), also financed by national funds through the FCT/MCTES, and when appropriate co-financed by the Fundo Europeu de Desenvolvimento Regional (FEDER) under the PT2020 Partnership Agreement. This work is funded by national funds (OE), through FCT – Fundação para a Ciência e a Tecnologia. European Social Fund through the program POPH of QREN. The authors also acknowledge the Portuguese Nuclear Magnetic Resonance Network (PTNMR).This work compares the stability and the catalytic efficiency of different ionic liquid phosphomolybdates ([BPy]3[PMo12O40] and [BMIM]3[PMo12O40]) with a cationic (propylpyridinium) functionalized mesoporous silica nanoparticle composite (PMo12O40@PPy-MSN). These were used as solid catalysts for the oxidative desulfurization of a multicomponent model diesel using hydrogen peroxide as oxidant and a polar immiscible extraction solvent. Ionic liquid ([BMIM][PF6] was successfully used as solvent to extract sulfur compounds from model diesel. The ionic liquid phosphomolybdates showed partial solubility in the ionic liquid phase, occurring some decomposition of their Keggin structure in the soluble reaction media, probably caused by their interaction with oxidant. On the other hand, the phosphomolybdate composite PMo12O40@PPy-MSN presented high structural stability and only negligible leaching occurrence after various consecutive reaction cycles. The model diesel was near complete desulfurized after 3 h and consecutive desulfurization cycles were performed without loss of activity. Therefore, the immobilization of Keggin phosphomolybdate structure [PMo12O40]3− using cationic propylpyridinium silica nanoparticle is an assertive strategy to produce stable and active heterogeneous catalysts.LAQV@REQUIMTEDQ - Departamento de QuímicaDCM - Departamento de Ciência dos MateriaisCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)RUNMirante, FatimaGomes, NeideCorvo, Marta C.Gago, SandraBalula, Salete S.2023-09-16T00:31:33Z2019-09-152019-09-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttps://doi.org/10.1016/j.poly.2019.06.019eng0277-5387PURE: 14582169http://www.scopus.com/inward/record.url?scp=85068838044&partnerID=8YFLogxKhttps://doi.org/10.1016/j.poly.2019.06.019info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:41:13Zoai:run.unl.pt:10362/82338Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:12:28.242819Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
title Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
spellingShingle Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
Mirante, Fatima
Fuels
Heterogeneous catalysis
Mesoporous silica nanoparticles
Oxidative desulfurization
Polyoxomolybdate
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry
title_short Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
title_full Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
title_fullStr Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
title_full_unstemmed Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
title_sort Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel
author Mirante, Fatima
author_facet Mirante, Fatima
Gomes, Neide
Corvo, Marta C.
Gago, Sandra
Balula, Salete S.
author_role author
author2 Gomes, Neide
Corvo, Marta C.
Gago, Sandra
Balula, Salete S.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
DCM - Departamento de Ciência dos Materiais
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
RUN
dc.contributor.author.fl_str_mv Mirante, Fatima
Gomes, Neide
Corvo, Marta C.
Gago, Sandra
Balula, Salete S.
dc.subject.por.fl_str_mv Fuels
Heterogeneous catalysis
Mesoporous silica nanoparticles
Oxidative desulfurization
Polyoxomolybdate
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry
topic Fuels
Heterogeneous catalysis
Mesoporous silica nanoparticles
Oxidative desulfurization
Polyoxomolybdate
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry
description This work was partly funded through the Associate Laboratory for Green Chemistry- LAQV which is financed by national funds from FCT/MCTES (POCI-01-0145-FEDER-007265, UID/QUI/50006/2019) and CENIMAT, I3N (POCI-01-0145-FEDER-007688, UID/CTM/50025/2013), also financed by national funds through the FCT/MCTES, and when appropriate co-financed by the Fundo Europeu de Desenvolvimento Regional (FEDER) under the PT2020 Partnership Agreement. This work is funded by national funds (OE), through FCT – Fundação para a Ciência e a Tecnologia. European Social Fund through the program POPH of QREN. The authors also acknowledge the Portuguese Nuclear Magnetic Resonance Network (PTNMR).
publishDate 2019
dc.date.none.fl_str_mv 2019-09-15
2019-09-15T00:00:00Z
2023-09-16T00:31:33Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://doi.org/10.1016/j.poly.2019.06.019
url https://doi.org/10.1016/j.poly.2019.06.019
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0277-5387
PURE: 14582169
http://www.scopus.com/inward/record.url?scp=85068838044&partnerID=8YFLogxK
https://doi.org/10.1016/j.poly.2019.06.019
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 9
application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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