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Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids

Bibliographic Details
Main Author: Santiago, Sara
Publication Date: 2022
Other Authors: Cruz, Hugo, Jordão, Noemi, Giménez-Gómez, Pablo, Zalewska, Karolina, Muñoz-Berbel, Xavier, Santos, Andreia F. M., Hernando, Jordi, Branco, Luís C., Guirado, Gonzalo
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/146066
Summary: The authors are grateful for financial support from project PID2019-106171RB-I00 from the Ministerio de Ciencia e Innovación (MICINN) of Spain . ), Portuguese Foundation for Science and Technology/MCTES ( POCI-01-0145-FEDER-016387 and MIT-EXPL/CS/0055/2021 )). Finally, H.C. thanks financial suport in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of article 23 of the Decree-Law 57/2016 of 29 August, changed by Law 57/2017 of 19 July. Publisher Copyright: © 2022 The Authors
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spelling Spectroelectrochemical studies of electrochromic diarylethene ionic LiquidsFrom solution to ionogel based devicesDiarylethene ionic liquidsIonogelsPhotoelectrochemical devicesSpectroelectrochemistryAnalytical ChemistrySpectroscopyThe authors are grateful for financial support from project PID2019-106171RB-I00 from the Ministerio de Ciencia e Innovación (MICINN) of Spain . ), Portuguese Foundation for Science and Technology/MCTES ( POCI-01-0145-FEDER-016387 and MIT-EXPL/CS/0055/2021 )). Finally, H.C. thanks financial suport in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of article 23 of the Decree-Law 57/2016 of 29 August, changed by Law 57/2017 of 19 July. Publisher Copyright: © 2022 The AuthorsThis study establishes the photoelectrochromic properties of four diarylethene ionic liquids (DAE-ILs) composed of a diarylethene dicarboxylate (DAE) moiety, as counter-anion, and different organic cations ([C10mim]+, [C16Pyr] +, [N8,8,8,1]+, [P6,6,6,14]+). The synthetized ILs viscous fluids maintain the photochemical and electrochemical properties of this well-known family of photoswitches, as well as the typical features of ILs (e.g., low melting point, and high thermal and electrochemical stability). Our strategy of making multi-stimuli-responsive ionic liquids by ionic exchange opens the door to easily tune the physicochemical properties of smart DAE-ILs in function of the selected cation. Finally, those DAE-ILs are used to formulate smart ionogels (IGs), a type of materials that, by showing good conductive properties and retaining the stimuli-responsive behavior of the embedded DAE molecules, allow the fabrication of photoelectrochemical devices.LAQV@REQUIMTERUNSantiago, SaraCruz, HugoJordão, NoemiGiménez-Gómez, PabloZalewska, KarolinaMuñoz-Berbel, XavierSantos, Andreia F. M.Hernando, JordiBranco, Luís C.Guirado, Gonzalo2022-12-07T22:13:37Z2022-112022-11-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7application/pdfhttp://hdl.handle.net/10362/146066eng0026-265XPURE: 47201947https://doi.org/10.1016/j.microc.2022.107870info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:07:13Zoai:run.unl.pt:10362/146066Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:37:33.600787Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
From solution to ionogel based devices
title Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
spellingShingle Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
Santiago, Sara
Diarylethene ionic liquids
Ionogels
Photoelectrochemical devices
Spectroelectrochemistry
Analytical Chemistry
Spectroscopy
title_short Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_full Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_fullStr Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_full_unstemmed Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_sort Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
author Santiago, Sara
author_facet Santiago, Sara
Cruz, Hugo
Jordão, Noemi
Giménez-Gómez, Pablo
Zalewska, Karolina
Muñoz-Berbel, Xavier
Santos, Andreia F. M.
Hernando, Jordi
Branco, Luís C.
Guirado, Gonzalo
author_role author
author2 Cruz, Hugo
Jordão, Noemi
Giménez-Gómez, Pablo
Zalewska, Karolina
Muñoz-Berbel, Xavier
Santos, Andreia F. M.
Hernando, Jordi
Branco, Luís C.
Guirado, Gonzalo
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv Santiago, Sara
Cruz, Hugo
Jordão, Noemi
Giménez-Gómez, Pablo
Zalewska, Karolina
Muñoz-Berbel, Xavier
Santos, Andreia F. M.
Hernando, Jordi
Branco, Luís C.
Guirado, Gonzalo
dc.subject.por.fl_str_mv Diarylethene ionic liquids
Ionogels
Photoelectrochemical devices
Spectroelectrochemistry
Analytical Chemistry
Spectroscopy
topic Diarylethene ionic liquids
Ionogels
Photoelectrochemical devices
Spectroelectrochemistry
Analytical Chemistry
Spectroscopy
description The authors are grateful for financial support from project PID2019-106171RB-I00 from the Ministerio de Ciencia e Innovación (MICINN) of Spain . ), Portuguese Foundation for Science and Technology/MCTES ( POCI-01-0145-FEDER-016387 and MIT-EXPL/CS/0055/2021 )). Finally, H.C. thanks financial suport in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of article 23 of the Decree-Law 57/2016 of 29 August, changed by Law 57/2017 of 19 July. Publisher Copyright: © 2022 The Authors
publishDate 2022
dc.date.none.fl_str_mv 2022-12-07T22:13:37Z
2022-11
2022-11-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/146066
url http://hdl.handle.net/10362/146066
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0026-265X
PURE: 47201947
https://doi.org/10.1016/j.microc.2022.107870
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 7
application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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