2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl
| Main Author: | |
|---|---|
| Publication Date: | 2011 |
| Other Authors: | , , |
| Format: | Article |
| Language: | eng |
| Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Download full: | http://hdl.handle.net/10316/109984 https://doi.org/10.1107/S1600536811031722 |
Summary: | The title compound, C(25)H(24)O(4), a meth-oxy-methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter-mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol-ecules. |
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2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-ylsingle-crystal X-ray studyT = 293 K; mean (C–C) = 0.003 A°R factor = 0.031wR factor = 0.081data-to-parameter ratio = 7.7The title compound, C(25)H(24)O(4), a meth-oxy-methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter-mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol-ecules.International Union of Crystallography2011-09-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/109984http://hdl.handle.net/10316/109984https://doi.org/10.1107/S1600536811031722eng1600-5368Carrilho, Rui M. B.Abreu, Artur R.Pereira, Mariette M.Rodrigues, V. H.info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2023-11-10T09:28:37Zoai:estudogeral.uc.pt:10316/109984Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T06:01:39.165165Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| title |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| spellingShingle |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl Carrilho, Rui M. B. single-crystal X-ray study T = 293 K; mean (C–C) = 0.003 A° R factor = 0.031 wR factor = 0.081 data-to-parameter ratio = 7.7 |
| title_short |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| title_full |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| title_fullStr |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| title_full_unstemmed |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| title_sort |
2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl |
| author |
Carrilho, Rui M. B. |
| author_facet |
Carrilho, Rui M. B. Abreu, Artur R. Pereira, Mariette M. Rodrigues, V. H. |
| author_role |
author |
| author2 |
Abreu, Artur R. Pereira, Mariette M. Rodrigues, V. H. |
| author2_role |
author author author |
| dc.contributor.author.fl_str_mv |
Carrilho, Rui M. B. Abreu, Artur R. Pereira, Mariette M. Rodrigues, V. H. |
| dc.subject.por.fl_str_mv |
single-crystal X-ray study T = 293 K; mean (C–C) = 0.003 A° R factor = 0.031 wR factor = 0.081 data-to-parameter ratio = 7.7 |
| topic |
single-crystal X-ray study T = 293 K; mean (C–C) = 0.003 A° R factor = 0.031 wR factor = 0.081 data-to-parameter ratio = 7.7 |
| description |
The title compound, C(25)H(24)O(4), a meth-oxy-methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter-mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol-ecules. |
| publishDate |
2011 |
| dc.date.none.fl_str_mv |
2011-09-01 |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/109984 http://hdl.handle.net/10316/109984 https://doi.org/10.1107/S1600536811031722 |
| url |
http://hdl.handle.net/10316/109984 https://doi.org/10.1107/S1600536811031722 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
1600-5368 |
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info:eu-repo/semantics/openAccess |
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openAccess |
| dc.publisher.none.fl_str_mv |
International Union of Crystallography |
| publisher.none.fl_str_mv |
International Union of Crystallography |
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reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia instacron:RCAAP |
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