New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand

Bibliographic Details
Main Author: Moura, Nuno M. M.
Publication Date: 2022
Other Authors: Serra, Vanda Vaz, Bastos, Alexandre, Biazotto, Juliana C., Castro, Kelly A. D. F., Faustino, Maria Amparo F., Lodeiro, Carlos, da Silva, Roberto S., Neves, Maria da Graça P. M. S.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/151037
Summary: Funding Information: NMM Moura, VV Serra and A Bastos thank their research contracts (CDL-CTTRI-048-88-ARH/2018, and CDL-CTTRI-62-ARH/2018) which are funded by national funds (OE), through FCT–Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in numbers 4, 5 and 6 of the article 23, of the Law Decree 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was partially supported by the Scientific Society PROTEOMASS (General Funds) (Portugal), Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP-2019/19448-8) and Universidade de São Paulo. K.A.D.F. Castro thanks CAPES for the post-doctoral scholarship granted (PNPD/CAPES). Publisher Copyright: © 2022 by the authors.
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spelling New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary LigandElectrochemical and Photophysical Insightscoordination chemistrycyclometalated iridium(III)PETporphyrinsinglet oxygenCatalysisMolecular BiologySpectroscopyComputer Science ApplicationsPhysical and Theoretical ChemistryOrganic ChemistryInorganic ChemistryFunding Information: NMM Moura, VV Serra and A Bastos thank their research contracts (CDL-CTTRI-048-88-ARH/2018, and CDL-CTTRI-62-ARH/2018) which are funded by national funds (OE), through FCT–Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in numbers 4, 5 and 6 of the article 23, of the Law Decree 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was partially supported by the Scientific Society PROTEOMASS (General Funds) (Portugal), Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP-2019/19448-8) and Universidade de São Paulo. K.A.D.F. Castro thanks CAPES for the post-doctoral scholarship granted (PNPD/CAPES). Publisher Copyright: © 2022 by the authors.An efficient synthetic access to new cationic porphyrin-bipyridine iridium(III) bis-cyclometalated complexes was developed. These porphyrins bearing arylbipyridine moieties at β-pyrrolic positions coordinated with iridium(III), and the corresponding Zn(II) porphyrin complexes were spectroscopically, electrochemically, and electronically characterized. The features displayed by the new cyclometalated porphyrin-bipyridine iridium(III) complexes, namely photoinduced electron transfer process (PET), and a remarkable efficiency to generate 1O2, allowing us to envisage new challenges and opportunities for their applications in several fields, such as photo(catalysis) and photodynamic therapies.DQ - Departamento de QuímicaLAQV@REQUIMTERUNMoura, Nuno M. M.Serra, Vanda VazBastos, AlexandreBiazotto, Juliana C.Castro, Kelly A. D. F.Faustino, Maria Amparo F.Lodeiro, Carlosda Silva, Roberto S.Neves, Maria da Graça P. M. S.2023-03-21T22:29:16Z2022-07-092022-07-09T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article19application/pdfhttp://hdl.handle.net/10362/151037eng1661-6596PURE: 56530588https://doi.org/10.3390/ijms23147606info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:10:26Zoai:run.unl.pt:10362/151037Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:40:55.180045Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
Electrochemical and Photophysical Insights
title New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
spellingShingle New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
Moura, Nuno M. M.
coordination chemistry
cyclometalated iridium(III)
PET
porphyrin
singlet oxygen
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
title_short New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
title_full New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
title_fullStr New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
title_full_unstemmed New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
title_sort New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
author Moura, Nuno M. M.
author_facet Moura, Nuno M. M.
Serra, Vanda Vaz
Bastos, Alexandre
Biazotto, Juliana C.
Castro, Kelly A. D. F.
Faustino, Maria Amparo F.
Lodeiro, Carlos
da Silva, Roberto S.
Neves, Maria da Graça P. M. S.
author_role author
author2 Serra, Vanda Vaz
Bastos, Alexandre
Biazotto, Juliana C.
Castro, Kelly A. D. F.
Faustino, Maria Amparo F.
Lodeiro, Carlos
da Silva, Roberto S.
Neves, Maria da Graça P. M. S.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv Moura, Nuno M. M.
Serra, Vanda Vaz
Bastos, Alexandre
Biazotto, Juliana C.
Castro, Kelly A. D. F.
Faustino, Maria Amparo F.
Lodeiro, Carlos
da Silva, Roberto S.
Neves, Maria da Graça P. M. S.
dc.subject.por.fl_str_mv coordination chemistry
cyclometalated iridium(III)
PET
porphyrin
singlet oxygen
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
topic coordination chemistry
cyclometalated iridium(III)
PET
porphyrin
singlet oxygen
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
description Funding Information: NMM Moura, VV Serra and A Bastos thank their research contracts (CDL-CTTRI-048-88-ARH/2018, and CDL-CTTRI-62-ARH/2018) which are funded by national funds (OE), through FCT–Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in numbers 4, 5 and 6 of the article 23, of the Law Decree 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was partially supported by the Scientific Society PROTEOMASS (General Funds) (Portugal), Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP-2019/19448-8) and Universidade de São Paulo. K.A.D.F. Castro thanks CAPES for the post-doctoral scholarship granted (PNPD/CAPES). Publisher Copyright: © 2022 by the authors.
publishDate 2022
dc.date.none.fl_str_mv 2022-07-09
2022-07-09T00:00:00Z
2023-03-21T22:29:16Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/151037
url http://hdl.handle.net/10362/151037
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1661-6596
PURE: 56530588
https://doi.org/10.3390/ijms23147606
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
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