Carbon Dioxide Utilisation -The Formate Route

Bibliographic Details
Main Author: Maia, Luisa
Publication Date: 2021
Other Authors: Moura, Isabel, Moura, José J. G.
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/109755
Summary: UIDB/50006/2020 CEEC-Individual 2017 Program Contract.
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network_name_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
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spelling Carbon Dioxide Utilisation -The Formate RouteCarbon dioxide utilisationFormic acidFormate dehydrogenaseMolybdenumTungstenHydride transferBiocatalystGreen chemistryEnergyBiotechnologySDG 13 - Climate ActionSDG 14 - Life Below WaterUIDB/50006/2020 CEEC-Individual 2017 Program Contract.The relentless rise of atmospheric CO2 is causing large and unpredictable impacts on the Earth climate, due to the CO2 significant greenhouse effect, besides being responsible for the ocean acidification, with consequent huge impacts in our daily lives and in all forms of life. To stop spiral of destruction, we must actively reduce the CO2 emissions and develop new and more efficient “CO2 sinks”. We should be focused on the opportunities provided by exploiting this novel and huge carbon feedstock to produce de novo fuels and added-value compounds. The conversion of CO2 into formate offers key advantages for carbon recycling, and formate dehydrogenase (FDH) enzymes are at the centre of intense research, due to the “green” advantages the bioconversion can offer, namely substrate and product selectivity and specificity, in reactions run at ambient temperature and pressure and neutral pH. In this chapter, we describe the remarkable recent progress towards efficient and selective FDH-catalysed CO2 reduction to formate. We focus on the enzymes, discussing their structure and mechanism of action. Selected promising studies and successful proof of concepts of FDH-dependent CO2 reduction to formate and beyond are discussed, to highlight the power of FDHs and the challenges this CO2 bioconversion still faces.Springer International PublishingLAQV@REQUIMTERUNMaia, LuisaMoura, IsabelMoura, José J. G.2021-01-05T23:15:08Z20212021-01-01T00:00:00Zbook partinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10362/109755eng978-3-030-58314-9PURE: 26849217info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:49:41Zoai:run.unl.pt:10362/109755Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:20:59.956973Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Carbon Dioxide Utilisation -The Formate Route
title Carbon Dioxide Utilisation -The Formate Route
spellingShingle Carbon Dioxide Utilisation -The Formate Route
Maia, Luisa
Carbon dioxide utilisation
Formic acid
Formate dehydrogenase
Molybdenum
Tungsten
Hydride transfer
Biocatalyst
Green chemistry
Energy
Biotechnology
SDG 13 - Climate Action
SDG 14 - Life Below Water
title_short Carbon Dioxide Utilisation -The Formate Route
title_full Carbon Dioxide Utilisation -The Formate Route
title_fullStr Carbon Dioxide Utilisation -The Formate Route
title_full_unstemmed Carbon Dioxide Utilisation -The Formate Route
title_sort Carbon Dioxide Utilisation -The Formate Route
author Maia, Luisa
author_facet Maia, Luisa
Moura, Isabel
Moura, José J. G.
author_role author
author2 Moura, Isabel
Moura, José J. G.
author2_role author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv Maia, Luisa
Moura, Isabel
Moura, José J. G.
dc.subject.por.fl_str_mv Carbon dioxide utilisation
Formic acid
Formate dehydrogenase
Molybdenum
Tungsten
Hydride transfer
Biocatalyst
Green chemistry
Energy
Biotechnology
SDG 13 - Climate Action
SDG 14 - Life Below Water
topic Carbon dioxide utilisation
Formic acid
Formate dehydrogenase
Molybdenum
Tungsten
Hydride transfer
Biocatalyst
Green chemistry
Energy
Biotechnology
SDG 13 - Climate Action
SDG 14 - Life Below Water
description UIDB/50006/2020 CEEC-Individual 2017 Program Contract.
publishDate 2021
dc.date.none.fl_str_mv 2021-01-05T23:15:08Z
2021
2021-01-01T00:00:00Z
dc.type.driver.fl_str_mv book part
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/109755
url http://hdl.handle.net/10362/109755
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 978-3-030-58314-9
PURE: 26849217
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.publisher.none.fl_str_mv Springer International Publishing
publisher.none.fl_str_mv Springer International Publishing
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instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
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repository.mail.fl_str_mv info@rcaap.pt
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