Carbon Dioxide Utilisation -The Formate Route
Main Author: | |
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Publication Date: | 2021 |
Other Authors: | , |
Language: | eng |
Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
Download full: | http://hdl.handle.net/10362/109755 |
Summary: | UIDB/50006/2020 CEEC-Individual 2017 Program Contract. |
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Carbon Dioxide Utilisation -The Formate RouteCarbon dioxide utilisationFormic acidFormate dehydrogenaseMolybdenumTungstenHydride transferBiocatalystGreen chemistryEnergyBiotechnologySDG 13 - Climate ActionSDG 14 - Life Below WaterUIDB/50006/2020 CEEC-Individual 2017 Program Contract.The relentless rise of atmospheric CO2 is causing large and unpredictable impacts on the Earth climate, due to the CO2 significant greenhouse effect, besides being responsible for the ocean acidification, with consequent huge impacts in our daily lives and in all forms of life. To stop spiral of destruction, we must actively reduce the CO2 emissions and develop new and more efficient “CO2 sinks”. We should be focused on the opportunities provided by exploiting this novel and huge carbon feedstock to produce de novo fuels and added-value compounds. The conversion of CO2 into formate offers key advantages for carbon recycling, and formate dehydrogenase (FDH) enzymes are at the centre of intense research, due to the “green” advantages the bioconversion can offer, namely substrate and product selectivity and specificity, in reactions run at ambient temperature and pressure and neutral pH. In this chapter, we describe the remarkable recent progress towards efficient and selective FDH-catalysed CO2 reduction to formate. We focus on the enzymes, discussing their structure and mechanism of action. Selected promising studies and successful proof of concepts of FDH-dependent CO2 reduction to formate and beyond are discussed, to highlight the power of FDHs and the challenges this CO2 bioconversion still faces.Springer International PublishingLAQV@REQUIMTERUNMaia, LuisaMoura, IsabelMoura, José J. G.2021-01-05T23:15:08Z20212021-01-01T00:00:00Zbook partinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10362/109755eng978-3-030-58314-9PURE: 26849217info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:49:41Zoai:run.unl.pt:10362/109755Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:20:59.956973Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
dc.title.none.fl_str_mv |
Carbon Dioxide Utilisation -The Formate Route |
title |
Carbon Dioxide Utilisation -The Formate Route |
spellingShingle |
Carbon Dioxide Utilisation -The Formate Route Maia, Luisa Carbon dioxide utilisation Formic acid Formate dehydrogenase Molybdenum Tungsten Hydride transfer Biocatalyst Green chemistry Energy Biotechnology SDG 13 - Climate Action SDG 14 - Life Below Water |
title_short |
Carbon Dioxide Utilisation -The Formate Route |
title_full |
Carbon Dioxide Utilisation -The Formate Route |
title_fullStr |
Carbon Dioxide Utilisation -The Formate Route |
title_full_unstemmed |
Carbon Dioxide Utilisation -The Formate Route |
title_sort |
Carbon Dioxide Utilisation -The Formate Route |
author |
Maia, Luisa |
author_facet |
Maia, Luisa Moura, Isabel Moura, José J. G. |
author_role |
author |
author2 |
Moura, Isabel Moura, José J. G. |
author2_role |
author author |
dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE RUN |
dc.contributor.author.fl_str_mv |
Maia, Luisa Moura, Isabel Moura, José J. G. |
dc.subject.por.fl_str_mv |
Carbon dioxide utilisation Formic acid Formate dehydrogenase Molybdenum Tungsten Hydride transfer Biocatalyst Green chemistry Energy Biotechnology SDG 13 - Climate Action SDG 14 - Life Below Water |
topic |
Carbon dioxide utilisation Formic acid Formate dehydrogenase Molybdenum Tungsten Hydride transfer Biocatalyst Green chemistry Energy Biotechnology SDG 13 - Climate Action SDG 14 - Life Below Water |
description |
UIDB/50006/2020 CEEC-Individual 2017 Program Contract. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-05T23:15:08Z 2021 2021-01-01T00:00:00Z |
dc.type.driver.fl_str_mv |
book part |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/109755 |
url |
http://hdl.handle.net/10362/109755 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
978-3-030-58314-9 PURE: 26849217 |
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info:eu-repo/semantics/openAccess |
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openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Springer International Publishing |
publisher.none.fl_str_mv |
Springer International Publishing |
dc.source.none.fl_str_mv |
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