Enthalpy of solvation of butanediols in different solvents

Bibliographic Details
Main Author: Jesus, A. J. Lopes
Publication Date: 2000
Other Authors: Eusébio, M. Ermelinda, Redinha, J. S., Leitão, M. L. P.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: https://hdl.handle.net/10316/5251
https://doi.org/10.1016/s0040-6031(99)00318-4
Summary: The enthalpies of solution for 1,2-, 1,3-, 1,4- and 2,3-butanediol in water, formamide and dimethylsulphoxide were determined by calorimetry. From the results and data available in the literature for the enthalpy of vaporisation, the enthalpy of solvation was determined. The enthalpy of solvation was decomposed into two terms, cavity formation in the solvent to hold the solute and solute-solvent interaction.
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spelling Enthalpy of solvation of butanediols in different solventsSolvation enthalpyAlkanediolsNon-electrolyte solutionsSolute-solute interactionsHydrophobic hydrationThe enthalpies of solution for 1,2-, 1,3-, 1,4- and 2,3-butanediol in water, formamide and dimethylsulphoxide were determined by calorimetry. From the results and data available in the literature for the enthalpy of vaporisation, the enthalpy of solvation was determined. The enthalpy of solvation was decomposed into two terms, cavity formation in the solvent to hold the solute and solute-solvent interaction.http://www.sciencedirect.com/science/article/B6THV-3Y9X8C1-2/1/b096193734aae40b777de9e3a0cf0f5c2000info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttps://hdl.handle.net/10316/5251https://hdl.handle.net/10316/5251https://doi.org/10.1016/s0040-6031(99)00318-4engThermochimica Acta. 344:1-2 (2000) 3-8Jesus, A. J. LopesEusébio, M. ErmelindaRedinha, J. S.Leitão, M. L. P.info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2021-09-17T08:23:04Zoai:estudogeral.uc.pt:10316/5251Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T05:23:27.701335Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Enthalpy of solvation of butanediols in different solvents
title Enthalpy of solvation of butanediols in different solvents
spellingShingle Enthalpy of solvation of butanediols in different solvents
Jesus, A. J. Lopes
Solvation enthalpy
Alkanediols
Non-electrolyte solutions
Solute-solute interactions
Hydrophobic hydration
title_short Enthalpy of solvation of butanediols in different solvents
title_full Enthalpy of solvation of butanediols in different solvents
title_fullStr Enthalpy of solvation of butanediols in different solvents
title_full_unstemmed Enthalpy of solvation of butanediols in different solvents
title_sort Enthalpy of solvation of butanediols in different solvents
author Jesus, A. J. Lopes
author_facet Jesus, A. J. Lopes
Eusébio, M. Ermelinda
Redinha, J. S.
Leitão, M. L. P.
author_role author
author2 Eusébio, M. Ermelinda
Redinha, J. S.
Leitão, M. L. P.
author2_role author
author
author
dc.contributor.author.fl_str_mv Jesus, A. J. Lopes
Eusébio, M. Ermelinda
Redinha, J. S.
Leitão, M. L. P.
dc.subject.por.fl_str_mv Solvation enthalpy
Alkanediols
Non-electrolyte solutions
Solute-solute interactions
Hydrophobic hydration
topic Solvation enthalpy
Alkanediols
Non-electrolyte solutions
Solute-solute interactions
Hydrophobic hydration
description The enthalpies of solution for 1,2-, 1,3-, 1,4- and 2,3-butanediol in water, formamide and dimethylsulphoxide were determined by calorimetry. From the results and data available in the literature for the enthalpy of vaporisation, the enthalpy of solvation was determined. The enthalpy of solvation was decomposed into two terms, cavity formation in the solvent to hold the solute and solute-solvent interaction.
publishDate 2000
dc.date.none.fl_str_mv 2000
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://hdl.handle.net/10316/5251
https://hdl.handle.net/10316/5251
https://doi.org/10.1016/s0040-6031(99)00318-4
url https://hdl.handle.net/10316/5251
https://doi.org/10.1016/s0040-6031(99)00318-4
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Thermochimica Acta. 344:1-2 (2000) 3-8
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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