New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2016 |
| Outros Autores: | , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Texto Completo: | https://doi.org/10.1063/1.4943617 |
Resumo: | SPTDC/EAT-EAT/112662/2009 SFRH/BPD/94234/2013 |
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New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometryPhysics and Astronomy(all)SPTDC/EAT-EAT/112662/2009 SFRH/BPD/94234/2013The richly decorated foral charter attributed by D. Manuel I of Portugal, in 1515, to the village of Setubal, was studied using Energy Dispersive X-ray Fluorescence spectrometry and Raman micro-spectroscopy. An in situ characterization of the pigments used in the production of this masterpiece showed a very different pigment palette choice when compared to other similar Manueline charters. The red and green pigments are particularly puzzling, as the widely used mercury- and copper-based pigments, vermillion and malachite, respectively, were not found in the illuminated frontispiece. Instead, the cheaper lead-based pigment minium was used in the King's flag, while a mixture of copper sulfates was found for the green color, identified by means of micro-Raman spectroscopy. This result led to a new look at the conception that only one Royal workshop existed for the elaboration of Manueline foral charters.LIBPhys-UNLDF – Departamento de FísicaDCR - Departamento de Conservação e RestauroRUNGuerra, MauroCarvalho, Maria LuisaLe Gac, AgnèsManso, MartaMortari, CamilaLongelin, StephanePessanha, Sofia2019-04-09T22:20:31Z2016-03-142016-03-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://doi.org/10.1063/1.4943617eng0021-8979PURE: 11799373http://www.scopus.com/inward/record.url?scp=84962487221&partnerID=8YFLogxKhttps://doi.org/10.1063/1.4943617info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:38:40Zoai:run.unl.pt:10362/66146Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:09:47.742050Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| title |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| spellingShingle |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry Guerra, Mauro Physics and Astronomy(all) |
| title_short |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| title_full |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| title_fullStr |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| title_full_unstemmed |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| title_sort |
New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry |
| author |
Guerra, Mauro |
| author_facet |
Guerra, Mauro Carvalho, Maria Luisa Le Gac, Agnès Manso, Marta Mortari, Camila Longelin, Stephane Pessanha, Sofia |
| author_role |
author |
| author2 |
Carvalho, Maria Luisa Le Gac, Agnès Manso, Marta Mortari, Camila Longelin, Stephane Pessanha, Sofia |
| author2_role |
author author author author author author |
| dc.contributor.none.fl_str_mv |
LIBPhys-UNL DF – Departamento de Física DCR - Departamento de Conservação e Restauro RUN |
| dc.contributor.author.fl_str_mv |
Guerra, Mauro Carvalho, Maria Luisa Le Gac, Agnès Manso, Marta Mortari, Camila Longelin, Stephane Pessanha, Sofia |
| dc.subject.por.fl_str_mv |
Physics and Astronomy(all) |
| topic |
Physics and Astronomy(all) |
| description |
SPTDC/EAT-EAT/112662/2009 SFRH/BPD/94234/2013 |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016-03-14 2016-03-14T00:00:00Z 2019-04-09T22:20:31Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
| format |
article |
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publishedVersion |
| dc.identifier.uri.fl_str_mv |
https://doi.org/10.1063/1.4943617 |
| url |
https://doi.org/10.1063/1.4943617 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
0021-8979 PURE: 11799373 http://www.scopus.com/inward/record.url?scp=84962487221&partnerID=8YFLogxK https://doi.org/10.1063/1.4943617 |
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openAccess |
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