Novel biocompatible ionic liquids based on gluconate anion
Main Author: | |
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Publication Date: | 2015 |
Other Authors: | , , , , |
Format: | Article |
Language: | eng |
Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
Download full: | https://doi.org/10.1080/17518253.2014.951695 |
Summary: | A sustainable organic synthetic methodology for the preparation of novel biocompatible ionic liquids (ILs) based on gluconate anion has been developed. Four functionalized methylimidazolium cations were efficiently combined with gluconic acid by acid-base neutralization reactions. All salts were obtained as RTILs in high yields (92–98%) and in high purity levels. Proton Nuclear Magnetic Resonance (1H NMR) studies had proved the correct cation/ anion proportion (1:1) and their chemical stability. These novel gluconate ILs can be applied for chemistry, material science, and medicine areas. |
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Novel biocompatible ionic liquids based on gluconate anionBiocompatibleGluconateIonic liquidsChemistry(all)Environmental ChemistryA sustainable organic synthetic methodology for the preparation of novel biocompatible ionic liquids (ILs) based on gluconate anion has been developed. Four functionalized methylimidazolium cations were efficiently combined with gluconic acid by acid-base neutralization reactions. All salts were obtained as RTILs in high yields (92–98%) and in high purity levels. Proton Nuclear Magnetic Resonance (1H NMR) studies had proved the correct cation/ anion proportion (1:1) and their chemical stability. These novel gluconate ILs can be applied for chemistry, material science, and medicine areas.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCosta, AlexandraForte, AndreiaZalewska, KarolinaTiago, GonçaloPetrovski, ZeljkoBranco, Luís C.2017-09-04T22:02:46Z2015-01-012015-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article5application/pdfhttps://doi.org/10.1080/17518253.2014.951695eng1751-8253PURE: 2903674http://www.scopus.com/inward/record.url?scp=84926136426&partnerID=8YFLogxKhttps://doi.org/10.1080/17518253.2014.951695info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T17:27:30Zoai:run.unl.pt:10362/23063Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T16:58:52.943168Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
dc.title.none.fl_str_mv |
Novel biocompatible ionic liquids based on gluconate anion |
title |
Novel biocompatible ionic liquids based on gluconate anion |
spellingShingle |
Novel biocompatible ionic liquids based on gluconate anion Costa, Alexandra Biocompatible Gluconate Ionic liquids Chemistry(all) Environmental Chemistry |
title_short |
Novel biocompatible ionic liquids based on gluconate anion |
title_full |
Novel biocompatible ionic liquids based on gluconate anion |
title_fullStr |
Novel biocompatible ionic liquids based on gluconate anion |
title_full_unstemmed |
Novel biocompatible ionic liquids based on gluconate anion |
title_sort |
Novel biocompatible ionic liquids based on gluconate anion |
author |
Costa, Alexandra |
author_facet |
Costa, Alexandra Forte, Andreia Zalewska, Karolina Tiago, Gonçalo Petrovski, Zeljko Branco, Luís C. |
author_role |
author |
author2 |
Forte, Andreia Zalewska, Karolina Tiago, Gonçalo Petrovski, Zeljko Branco, Luís C. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
dc.contributor.author.fl_str_mv |
Costa, Alexandra Forte, Andreia Zalewska, Karolina Tiago, Gonçalo Petrovski, Zeljko Branco, Luís C. |
dc.subject.por.fl_str_mv |
Biocompatible Gluconate Ionic liquids Chemistry(all) Environmental Chemistry |
topic |
Biocompatible Gluconate Ionic liquids Chemistry(all) Environmental Chemistry |
description |
A sustainable organic synthetic methodology for the preparation of novel biocompatible ionic liquids (ILs) based on gluconate anion has been developed. Four functionalized methylimidazolium cations were efficiently combined with gluconic acid by acid-base neutralization reactions. All salts were obtained as RTILs in high yields (92–98%) and in high purity levels. Proton Nuclear Magnetic Resonance (1H NMR) studies had proved the correct cation/ anion proportion (1:1) and their chemical stability. These novel gluconate ILs can be applied for chemistry, material science, and medicine areas. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-01-01 2015-01-01T00:00:00Z 2017-09-04T22:02:46Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://doi.org/10.1080/17518253.2014.951695 |
url |
https://doi.org/10.1080/17518253.2014.951695 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1751-8253 PURE: 2903674 http://www.scopus.com/inward/record.url?scp=84926136426&partnerID=8YFLogxK https://doi.org/10.1080/17518253.2014.951695 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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5 application/pdf |
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