Applications and limitations of uranyl ion as a photophysical probe
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2001 |
| Outros Autores: | |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Texto Completo: | https://hdl.handle.net/10316/5226 https://doi.org/10.1016/S0001-8686(00)00075-0 |
Resumo: | Uranyl ion has a long-lived luminescent excited state, which can be used as a probe for the aggregation behaviour in a variety of surfactant and polymeric systems. The general spectroscopy and photophysics of this species are discussed, and the applications to specific micellar, microemulsion, vesicular and liquid crystalline systems presented. It is shown that both dynamic and structural information can be obtained from spectral and kinetic data. Examples of applications of uranyl probe studies to technologically important mesoscopic and mesoporous systems involving metal oxides, or their salts, and to humic acids and soils will also be reviewed. Emphasis will be given to both the advantages and restrictions on the use of this useful photophysical probe. |
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Applications and limitations of uranyl ion as a photophysical probeUranyl ionPhotophysical probesMicroheterogeneous systemsSurfactant aggregatesUranyl ion has a long-lived luminescent excited state, which can be used as a probe for the aggregation behaviour in a variety of surfactant and polymeric systems. The general spectroscopy and photophysics of this species are discussed, and the applications to specific micellar, microemulsion, vesicular and liquid crystalline systems presented. It is shown that both dynamic and structural information can be obtained from spectral and kinetic data. Examples of applications of uranyl probe studies to technologically important mesoscopic and mesoporous systems involving metal oxides, or their salts, and to humic acids and soils will also be reviewed. Emphasis will be given to both the advantages and restrictions on the use of this useful photophysical probe.http://www.sciencedirect.com/science/article/B6V5F-423HJVT-V/1/abc36a619aebc745170fe32b4e51b5fc2001info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttps://hdl.handle.net/10316/5226https://hdl.handle.net/10316/5226https://doi.org/10.1016/S0001-8686(00)00075-0engAdvances in Colloid and Interface Science. 89-90:(2001) 485-496Burrows, Hugh D.Miguel, Maria da Graçainfo:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2020-11-06T16:59:26Zoai:estudogeral.uc.pt:10316/5226Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T05:23:58.881529Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
Applications and limitations of uranyl ion as a photophysical probe |
| title |
Applications and limitations of uranyl ion as a photophysical probe |
| spellingShingle |
Applications and limitations of uranyl ion as a photophysical probe Burrows, Hugh D. Uranyl ion Photophysical probes Microheterogeneous systems Surfactant aggregates |
| title_short |
Applications and limitations of uranyl ion as a photophysical probe |
| title_full |
Applications and limitations of uranyl ion as a photophysical probe |
| title_fullStr |
Applications and limitations of uranyl ion as a photophysical probe |
| title_full_unstemmed |
Applications and limitations of uranyl ion as a photophysical probe |
| title_sort |
Applications and limitations of uranyl ion as a photophysical probe |
| author |
Burrows, Hugh D. |
| author_facet |
Burrows, Hugh D. Miguel, Maria da Graça |
| author_role |
author |
| author2 |
Miguel, Maria da Graça |
| author2_role |
author |
| dc.contributor.author.fl_str_mv |
Burrows, Hugh D. Miguel, Maria da Graça |
| dc.subject.por.fl_str_mv |
Uranyl ion Photophysical probes Microheterogeneous systems Surfactant aggregates |
| topic |
Uranyl ion Photophysical probes Microheterogeneous systems Surfactant aggregates |
| description |
Uranyl ion has a long-lived luminescent excited state, which can be used as a probe for the aggregation behaviour in a variety of surfactant and polymeric systems. The general spectroscopy and photophysics of this species are discussed, and the applications to specific micellar, microemulsion, vesicular and liquid crystalline systems presented. It is shown that both dynamic and structural information can be obtained from spectral and kinetic data. Examples of applications of uranyl probe studies to technologically important mesoscopic and mesoporous systems involving metal oxides, or their salts, and to humic acids and soils will also be reviewed. Emphasis will be given to both the advantages and restrictions on the use of this useful photophysical probe. |
| publishDate |
2001 |
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2001 |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
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https://hdl.handle.net/10316/5226 https://hdl.handle.net/10316/5226 https://doi.org/10.1016/S0001-8686(00)00075-0 |
| url |
https://hdl.handle.net/10316/5226 https://doi.org/10.1016/S0001-8686(00)00075-0 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
Advances in Colloid and Interface Science. 89-90:(2001) 485-496 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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aplication/PDF |
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Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
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