Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times
| Main Author: | |
|---|---|
| Publication Date: | 2019 |
| Other Authors: | , , , , , , |
| Format: | Article |
| Language: | eng |
| Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Download full: | https://hdl.handle.net/1822/66294 |
Summary: | Ti and its alloys exhibit combination of unique properties for biomedical applications, however their poor tribo-electrochemical behaviour is a major concern. Therefore, TiN coatings were deposited on cp-Ti (grade 4) by sputtering technique aiming the improvement of its tribocorrosion behaviour. The properties of the coated samples, using different TiN deposition times, were characterized by using grazing incidence X-ray diffraction, FIB-SEM, and nanoindentation. The corrosion behaviour was studied by electrochemical impedance spectroscopy and potentiodynamic polarization in 9 g/L NaCl solution at body temperature. Tribocorrosion tests were employed under open circuit potential by using a ball-on-plate tribometer with 1 N normal load, 3 mm total stroke length, 1 Hz frequency, and 1800 s sliding duration. The results suggested that the TiN coatings deposited during 80 min presented better corrosion and tribocorrosion behaviour as compared to the bare metal and TiN coatings deposited during 30 min. |
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Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition timesTiNCorrosionTribocorrosionScience & TechnologyTi and its alloys exhibit combination of unique properties for biomedical applications, however their poor tribo-electrochemical behaviour is a major concern. Therefore, TiN coatings were deposited on cp-Ti (grade 4) by sputtering technique aiming the improvement of its tribocorrosion behaviour. The properties of the coated samples, using different TiN deposition times, were characterized by using grazing incidence X-ray diffraction, FIB-SEM, and nanoindentation. The corrosion behaviour was studied by electrochemical impedance spectroscopy and potentiodynamic polarization in 9 g/L NaCl solution at body temperature. Tribocorrosion tests were employed under open circuit potential by using a ball-on-plate tribometer with 1 N normal load, 3 mm total stroke length, 1 Hz frequency, and 1800 s sliding duration. The results suggested that the TiN coatings deposited during 80 min presented better corrosion and tribocorrosion behaviour as compared to the bare metal and TiN coatings deposited during 30 min.This work is supported by FCT with the reference project UID/EEA/04436/2013, COMPETE 2020 with the code POCI-01-0145-FEDER-006941, and M-ERA-NET/0001/2015 (FAPESP proc. #2015/50.280-5) project. I. Caha grateful for financial support through PhD grant under NORTE-08-5369-FSE-000012 project. The authors would also like to acknowledge Dr. Paulo Ferreira and Dr. Enrique Carbo-Argibay (International Iberian Nanotechnology Laboratory) for the provision of FIB facilities, and Prof. Grata Minas (Universidade do Minho) for the provision of profilometry.Elsevier ScienceUniversidade do MinhoCaha, IhsanAlves, Alexandra Manuela Vieira Cruz PintoAffonco, L. J.Lisboa-Filho, P. N.da Silva, J. H. D.Rocha, L. A.Pinto, A. M. P.Toptan, Fatih20192019-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/66294eng0257-897210.1016/j.surfcoat.2019.06.073info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2025-04-12T04:57:11Zoai:repositorium.sdum.uminho.pt:1822/66294Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T15:49:05.274094Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| title |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| spellingShingle |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times Caha, Ihsan TiN Corrosion Tribocorrosion Science & Technology |
| title_short |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| title_full |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| title_fullStr |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| title_full_unstemmed |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| title_sort |
Corrosion and tribocorrosion behaviour of titanium nitride thin films grown on titanium under different deposition times |
| author |
Caha, Ihsan |
| author_facet |
Caha, Ihsan Alves, Alexandra Manuela Vieira Cruz Pinto Affonco, L. J. Lisboa-Filho, P. N. da Silva, J. H. D. Rocha, L. A. Pinto, A. M. P. Toptan, Fatih |
| author_role |
author |
| author2 |
Alves, Alexandra Manuela Vieira Cruz Pinto Affonco, L. J. Lisboa-Filho, P. N. da Silva, J. H. D. Rocha, L. A. Pinto, A. M. P. Toptan, Fatih |
| author2_role |
author author author author author author author |
| dc.contributor.none.fl_str_mv |
Universidade do Minho |
| dc.contributor.author.fl_str_mv |
Caha, Ihsan Alves, Alexandra Manuela Vieira Cruz Pinto Affonco, L. J. Lisboa-Filho, P. N. da Silva, J. H. D. Rocha, L. A. Pinto, A. M. P. Toptan, Fatih |
| dc.subject.por.fl_str_mv |
TiN Corrosion Tribocorrosion Science & Technology |
| topic |
TiN Corrosion Tribocorrosion Science & Technology |
| description |
Ti and its alloys exhibit combination of unique properties for biomedical applications, however their poor tribo-electrochemical behaviour is a major concern. Therefore, TiN coatings were deposited on cp-Ti (grade 4) by sputtering technique aiming the improvement of its tribocorrosion behaviour. The properties of the coated samples, using different TiN deposition times, were characterized by using grazing incidence X-ray diffraction, FIB-SEM, and nanoindentation. The corrosion behaviour was studied by electrochemical impedance spectroscopy and potentiodynamic polarization in 9 g/L NaCl solution at body temperature. Tribocorrosion tests were employed under open circuit potential by using a ball-on-plate tribometer with 1 N normal load, 3 mm total stroke length, 1 Hz frequency, and 1800 s sliding duration. The results suggested that the TiN coatings deposited during 80 min presented better corrosion and tribocorrosion behaviour as compared to the bare metal and TiN coatings deposited during 30 min. |
| publishDate |
2019 |
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2019 2019-01-01T00:00:00Z |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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publishedVersion |
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https://hdl.handle.net/1822/66294 |
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eng |
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eng |
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0257-8972 10.1016/j.surfcoat.2019.06.073 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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Elsevier Science |
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Elsevier Science |
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