Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)

Bibliographic Details
Main Author: Nguyen,Tam Huu
Publication Date: 2019
Other Authors: Tran,Phuc Huynh, Thai,Linh Duy, Truong,Thuy Thu, Nguyen,Le-Thu T., Nguyen,Ha Tran
Format: Article
Language: eng
Source: Polímeros (São Carlos. Online)
Download full: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100409
Summary: Abstract The photoswitchable poly(methyl methacrylate-random-methacrylate spirooxazine) was synthesized via atom transfer radical polymerization with the feed mole ratio of MMA/MSp comonomer of about 5.5/1. Well-defined poly(methyl methacrylate- random-methacrylate spirooxazine) have been obtained with the average molecular weight (Mn) of 6500 g/mol and polydispersity of 1.21. The structure and properties of the resulting copolymers were characterized by proton nuclear magnetic resonance (1H NMR), gel permeation chromatography, Fourier Transform infrared, UV-visible spectroscopy, and differential scanning calorimetry. Moreover, the copolymer exhibited the erasable and rewritable photoimaging on the solid state film which could to be as potential candidate for optical data storage materials.
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spelling Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)spirooxazinecontrolled radical polymerizationphotoswitching polymersAbstract The photoswitchable poly(methyl methacrylate-random-methacrylate spirooxazine) was synthesized via atom transfer radical polymerization with the feed mole ratio of MMA/MSp comonomer of about 5.5/1. Well-defined poly(methyl methacrylate- random-methacrylate spirooxazine) have been obtained with the average molecular weight (Mn) of 6500 g/mol and polydispersity of 1.21. The structure and properties of the resulting copolymers were characterized by proton nuclear magnetic resonance (1H NMR), gel permeation chromatography, Fourier Transform infrared, UV-visible spectroscopy, and differential scanning calorimetry. Moreover, the copolymer exhibited the erasable and rewritable photoimaging on the solid state film which could to be as potential candidate for optical data storage materials.Associação Brasileira de Polímeros2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100409Polímeros v.29 n.1 2019reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/0104-1428.01118info:eu-repo/semantics/openAccessNguyen,Tam HuuTran,Phuc HuynhThai,Linh DuyTruong,Thuy ThuNguyen,Le-Thu T.Nguyen,Ha Traneng2019-03-13T00:00:00Zoai:scielo:S0104-14282019000100409Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2019-03-13T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false
dc.title.none.fl_str_mv Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
title Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
spellingShingle Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
Nguyen,Tam Huu
spirooxazine
controlled radical polymerization
photoswitching polymers
title_short Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
title_full Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
title_fullStr Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
title_full_unstemmed Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
title_sort Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
author Nguyen,Tam Huu
author_facet Nguyen,Tam Huu
Tran,Phuc Huynh
Thai,Linh Duy
Truong,Thuy Thu
Nguyen,Le-Thu T.
Nguyen,Ha Tran
author_role author
author2 Tran,Phuc Huynh
Thai,Linh Duy
Truong,Thuy Thu
Nguyen,Le-Thu T.
Nguyen,Ha Tran
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Nguyen,Tam Huu
Tran,Phuc Huynh
Thai,Linh Duy
Truong,Thuy Thu
Nguyen,Le-Thu T.
Nguyen,Ha Tran
dc.subject.por.fl_str_mv spirooxazine
controlled radical polymerization
photoswitching polymers
topic spirooxazine
controlled radical polymerization
photoswitching polymers
description Abstract The photoswitchable poly(methyl methacrylate-random-methacrylate spirooxazine) was synthesized via atom transfer radical polymerization with the feed mole ratio of MMA/MSp comonomer of about 5.5/1. Well-defined poly(methyl methacrylate- random-methacrylate spirooxazine) have been obtained with the average molecular weight (Mn) of 6500 g/mol and polydispersity of 1.21. The structure and properties of the resulting copolymers were characterized by proton nuclear magnetic resonance (1H NMR), gel permeation chromatography, Fourier Transform infrared, UV-visible spectroscopy, and differential scanning calorimetry. Moreover, the copolymer exhibited the erasable and rewritable photoimaging on the solid state film which could to be as potential candidate for optical data storage materials.
publishDate 2019
dc.date.none.fl_str_mv 2019-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100409
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100409
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-1428.01118
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Polímeros
publisher.none.fl_str_mv Associação Brasileira de Polímeros
dc.source.none.fl_str_mv Polímeros v.29 n.1 2019
reponame:Polímeros (São Carlos. Online)
instname:Associação Brasileira de Polímeros (ABPol)
instacron:ABPO
instname_str Associação Brasileira de Polímeros (ABPol)
instacron_str ABPO
institution ABPO
reponame_str Polímeros (São Carlos. Online)
collection Polímeros (São Carlos. Online)
repository.name.fl_str_mv Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)
repository.mail.fl_str_mv ||revista@abpol.org.br
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