Método de caracterização adaptativa aplicado à transferência de massa em misturas contínuas com o modelo de difusão de Maxwell-Stefan
Ano de defesa: | 2018 |
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Autor(a) principal: | |
Orientador(a): | |
Banca de defesa: | |
Tipo de documento: | Tese |
Tipo de acesso: | Acesso aberto |
Idioma: | por |
Instituição de defesa: |
Universidade Federal do Rio de Janeiro
Brasil Instituto Alberto Luiz Coimbra de Pós-Graduação e Pesquisa de Engenharia Programa de Pós-Graduação em Engenharia Química UFRJ |
Programa de Pós-Graduação: |
Não Informado pela instituição
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Departamento: |
Não Informado pela instituição
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País: |
Não Informado pela instituição
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Palavras-chave em Português: | |
Link de acesso: | http://hdl.handle.net/11422/12867 |
Resumo: | The adaptive pseudo-component characterization method for continuous mixtures was extended to mass transfer problems using the Maxwell-Stefan diffusion model. Being based on the direct quadrature method of moments (DQMoM), it uses a quadrature rule to discretize the molar fraction distribution of the continuous mixture. The solution method was applied to two one-dimensional mass transfer problems: the transient diffusion in a Loschmidt tube and the steady-state diffusion in a thin film. In the latter, it was showed that the DQMoM equations reduce to an equivalent problem with a fixed characterization and the solution methods for linearized theory problems can be employed. For these two problems, the proposed method was validated using continuous molar fraction distributions as initial or boundary conditions. Results showed that the adaptive method accurately predicts mixture properties with one order of magnitude reduction in the number of the pseudo-components when compared to the discrete component model. |