Solventes bio-renováveis para metátese de propenilbenzenos

• Ano de defesa: 2019
• Autor(a) principal: Pedro Leroy Evangelista Carvalhais
• Tipo de documento: Dissertação
• Tipo de acesso: Acesso aberto
• Idioma: por
• Instituição de defesa: Universidade Federal de Minas Gerais; UFMG
• Palavras-chave em Português: anisol; Metátese; metátese de fechamento de anel; catálise; pinano; solventes biodegradáveis; química verde; organometálicos; solventes verdes; olefinas; metátese cruzada; Olefinas; Solventes; Metátese (Química); Síntese orgânica; Catálise; Química ambiental; Quimica inorganica; Compostos organometalicos
• Link de acesso: http://hdl.handle.net/1843/SFSA-BDZQ3K

Metathesis reactions have emerged in the last few decades as important tools for a wide variety of organic synthesis, combining high yields and sustainability. In spite of intense studies in this area and developments optimizing metathesis conditions, in many cases solvent utilization is mandatory, especially in fine chemistry. The most widely employed classes of solvents are aromatics and chlorinated ones, suchas toluene and 1,2 -dichloroethane, that are rather toxic and harmful to the environment, which compromises the sustainable utilization of olefin metathesis. In this study, the substitution of those traditional and environmentally problematic solvents for biodegradable and less aggressive options was evaluated. The chosen test reactions were: ring closing metathesis of diethylallylmalonate and cross metathesis of anethole and methylacrylate. Anisole, e pinenes, pinane, limoneneand a mixture of pinane and p-cymene were employed for the first time for this reaction. High yields were achieved, specially with anisole and the mixture pcymene/pinane, showing that they can replace harmful traditional solvents.