Detalhes bibliográficos
Ano de defesa: |
2010 |
Autor(a) principal: |
Pinto, Thaís Frazão
 |
Orientador(a): |
SANTANA, Sirlane Aparecida Abreu
 |
Banca de defesa: |
Tanaka, Auro Atsushi |
Tipo de documento: |
Dissertação
|
Tipo de acesso: |
Acesso aberto |
Idioma: |
por |
Instituição de defesa: |
Universidade Federal do Maranhão
|
Programa de Pós-Graduação: |
PROGRAMA DE PÓS-GRADUAÇÃO EM QUÍMICA/CCET
|
Departamento: |
QUIMICA
|
País: |
BR
|
Palavras-chave em Português: |
|
Palavras-chave em Inglês: |
|
Área do conhecimento CNPq: |
|
Link de acesso: |
http://tedebc.ufma.br:8080/jspui/handle/tede/910
|
Resumo: |
This work treated of modified wood sawdust with succinic anhydride and your application as adsorbent for remazol brilliant violet 5R (VR5) textile dye. The new material obtained was designated SMAS. The vibrations spectra indicated the presence of oxygenated groups, being the modification confirmed by Infrared, 13C NMR spectroscopy and titration of acid groups that indicated the introduction of carboxylic groups the material. It was found that the material can act as adsorbent to dye investigated and your active sites further enriched, due to considerably increased the adsorption capacity compared to natural material. Furthermore, the process of adsorption proved to be highly dependent of the pH and the largest amount adsorbed was obtained at pH 2.0. The adsorption of remazol brilliant violet 5R textile dye by wood sawdust modified with succinic anhydride followed the kinetic modeling of second order and was well described by the Freundlich model. In the conditions studied was reached a percentage of removal 51.66%. |