Detalhes bibliográficos
| Ano de defesa: |
2015 |
| Autor(a) principal: |
Dias, Guilherme Thomas Gerevini
 |
| Orientador(a): |
Einloft, Sandra Mara Oliveira
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| Banca de defesa: |
Não Informado pela instituição |
| Tipo de documento: |
Dissertação
|
| Tipo de acesso: |
Acesso aberto |
| Idioma: |
por |
| Instituição de defesa: |
Pontifícia Universidade Católica do Rio Grande do Sul
|
| Programa de Pós-Graduação: |
Programa de Pós-Graduação em Engenharia e Tecnologia de Materiais
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| Departamento: |
Faculdade de Engenharia
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| País: |
BR
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| Palavras-chave em Português: |
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| Área do conhecimento CNPq: |
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| Link de acesso: |
http://tede2.pucrs.br/tede2/handle/tede/3274
|
Resumo: |
The development of new materials with distinct properties is needed today; nanocomposites represent a new group of materials that stand out in this current market demand. Polyurethanes for having versatility as the processes of synthesis and composition are an object of study in various industrial segments. One method to improve the properties of the polyurethane is the addition of inorganic fillers. Thus, this work aims to study the interaction and incorporation of silico-metallic mineral synthetic particles with different hydrothermal treatments (7h and 24h), comparing the influence of the size, distribution and surface area on the properties of polyurethane nanocomposites. PU nanocomposite / SSMMP (7h and 24h) with defined amounts of 0.5%, 1%, 2%, 3% and 5% by weight relative to the pure polymer were synthesized. Technical Analysis of X-Ray Diffraction (XRD) Analysis of Specific Surface Area (BET) spectroscopy, Fourier Transform Infrared (FTIR), Differential Scanning Calorimetry (DSC), Thermogravimetric analysis (TGA), Gel Permeation Chromatography (GPC), Dynamic-Mechanical Analysis (DMTA) and Scanning Electron Microscopy (SEM) were used to characterize materials. The XRD analysis showed that the synthetic silico-metallic mineral fillers exfoliated/well dispersed in the polyurethane matrix. The high surface area of SSMMP influenced the crystallization, and also on the thermal and mechanical properties of nanocomposites. Both PU/ SSMMP (7h and 24h) showed an increase in mechanical properties, although the PU/ SSMMP 7h nanocomposites have a Young's modulus higher than PU / SSMMP 24h. The creep- recovery tests showed that the SSMMP (7h and 24h) restricted the movement of PU chains. The results showed the importance of controlled synthesis of SSMMP for obtaining new materials with desired properties |
