Estudos Cinéticos da aquação do trans-[Co(en)2Cl2]Cl
Spremljeno u:
| Glavni autor: | |
|---|---|
| Datum izdanja: | 2006 |
| Daljnji autori: | , , , , |
| Format: | Article |
| Jezik: | por |
| Izvor: | Repositório Institucional da UnB |
| Download full: | http://repositorio.unb.br/handle/10482/26634 https://dx.doi.org/10.1590/S0100-40422006000200034 |
Sažetak: | The trans-dichlorobis(ethylenediamine)cobalt(III) chloride was synthesized in an undergraduate laboratory and its aquation reaction was carried out at different temperatures. This reaction follows pseudo-first-order kinetics and the rate constants, determined at 25, 35, 45, 55 and 70 º C, are 1.44 x 10-3; 5.14 x 10-3; 1.48 x 10-2; 4.21 x 10-2 and 2.21 x 10-1 s-1, respectively. The activation energy is 93.99 ± 2.88 kJ mol-1. |
Slični predmeti: Estudos Cinéticos da aquação do trans-[Co(en)2Cl2]Cl
- Intramolecular ene reactions catalyzed by NbCl5, TaCl5 and InCl3
- Heptacoordination in Organotin(IV) Complexes: Spectroscopic and Structural Studies of 2,6–Diacetylpyridine bis(thiosemicarbazone)di–n–butyltin(IV) Chloride Nitromethane Solvate, [nBu2Sn(H2daptsc)]Cl 2•MeNO2 and of 2,6–Diacetylpyridine bis(semicarbazone)dimethyltin(IV) trans–Tetrachlorodimethylstannate(IV), [Me2Sn(H2dapsc)][Me2 SnCl4]
- Cálculo das constantes espectroscópicas e energias rovibracionais da molécula de Cl2 em seus estados eletrônicos fundamental e excitados
- Cálculos das energias eletrônicas usando a equação de Hamilton-Jacobi para os sistemas : HeH2+, LiH3+ e BeH4+
- Avaliação do atraso eletromecânico por meio das ativações neural e muscular
- Reological and thermodynamical properties of mixtures containing [BMIM][Cl] and glycerol.