Síntese de análogo de brassinoesteróide a partir de vespertilina

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Main Author: Gárate, José L. M.
Publication Date: 1998
Other Authors: Magalhães, Gouvan C. de, Romeiro, Luiz Antonio Soares
Format: Article
Language: por
Source: Repositório Institucional da UnB
Download full: http://repositorio.unb.br/handle/10482/25451
https://dx.doi.org/10.1590/S0100-40421998000600011
Summary: In the last years, several research groups have been working on the synthesis of new steroidal plant hormones called brassinosteroids (BS), which promote plant growth and better crops. Many synthetic targets and applications of these compounds and their analogues have been described in the literature. From Solanum species of the Distrito Federal, we isolated the steroidal alkaloid solasodine, which was then converted into our starting material, vespertiline. By functionalization of rings A and B, we have synthesized a new analogue of BS, with a 2alpha,3alpha-dihydroxy-6-one structure, typical of the naturally occurring BS castasterone, the immediate biosynthetic precursor of brassinolide.
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author Gárate, José L. M.
author2 Magalhães, Gouvan C. de
Romeiro, Luiz Antonio Soares
author2_role author
author
author_browse Gárate, José L. M.
Magalhães, Gouvan C. de
Romeiro, Luiz Antonio Soares
author_facet Gárate, José L. M.
Magalhães, Gouvan C. de
Romeiro, Luiz Antonio Soares
author_role author
bitstream.checksum.fl_str_mv eeeb3a993978ce4870b8eb486bca0c49
bitstream.checksumAlgorithm.fl_str_mv MD5
bitstream.url.fl_str_mv http://repositorio.unb.br/bitstream/10482/25451/1/2905.pdf
collection Repositório Institucional da UnB
dc.contributor.author.fl_str_mv Gárate, José L. M.
Magalhães, Gouvan C. de
Romeiro, Luiz Antonio Soares
dc.date.accessioned.fl_str_mv 2017-12-07T04:28:29Z
dc.date.available.fl_str_mv 2017-12-07T04:28:29Z
dc.date.issued.fl_str_mv 1998
dc.identifier.citation.fl_str_mv Quím. Nova,v.21,n.6,p.726-730,1998
dc.identifier.doi.pt_BR.fl_str_mv https://dx.doi.org/10.1590/S0100-40421998000600011
dc.identifier.uri.fl_str_mv http://repositorio.unb.br/handle/10482/25451
dc.language.iso.fl_str_mv por
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
dc.source.none.fl_str_mv reponame:Repositório Institucional da UnB
instname:Universidade de Brasília (UnB)
instacron:UNB
dc.subject.keyword.pt_BR.fl_str_mv Vespertilina
Brassinosteroides
Esteróides promotores de crescimento de plantas
dc.title.pt_BR.fl_str_mv Síntese de análogo de brassinoesteróide a partir de vespertilina
Synthesis of a brassinosteroid analogue from vespertiline
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
description In the last years, several research groups have been working on the synthesis of new steroidal plant hormones called brassinosteroids (BS), which promote plant growth and better crops. Many synthetic targets and applications of these compounds and their analogues have been described in the literature. From Solanum species of the Distrito Federal, we isolated the steroidal alkaloid solasodine, which was then converted into our starting material, vespertiline. By functionalization of rings A and B, we have synthesized a new analogue of BS, with a 2alpha,3alpha-dihydroxy-6-one structure, typical of the naturally occurring BS castasterone, the immediate biosynthetic precursor of brassinolide.
eu_rights_str_mv openAccess
format article
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identifier_str_mv Quím. Nova,v.21,n.6,p.726-730,1998
instacron_str UNB
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instname_str Universidade de Brasília (UnB)
language por
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network_name_str Repositório Institucional da UnB
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publishDate 1998
publishDateSort 1998
publisher.none.fl_str_mv Sociedade Brasileira de Química
reponame_str Repositório Institucional da UnB
repository.mail.fl_str_mv repositorio@unb.br
repository.name.fl_str_mv Repositório Institucional da UnB - Universidade de Brasília (UnB)
repository_id_str
spelling Gárate, José L. M.Magalhães, Gouvan C. deRomeiro, Luiz Antonio Soares2017-12-07T04:28:29Z2017-12-07T04:28:29Z1998Quím. Nova,v.21,n.6,p.726-730,1998http://repositorio.unb.br/handle/10482/25451https://dx.doi.org/10.1590/S0100-40421998000600011In the last years, several research groups have been working on the synthesis of new steroidal plant hormones called brassinosteroids (BS), which promote plant growth and better crops. Many synthetic targets and applications of these compounds and their analogues have been described in the literature. From Solanum species of the Distrito Federal, we isolated the steroidal alkaloid solasodine, which was then converted into our starting material, vespertiline. By functionalization of rings A and B, we have synthesized a new analogue of BS, with a 2alpha,3alpha-dihydroxy-6-one structure, typical of the naturally occurring BS castasterone, the immediate biosynthetic precursor of brassinolide.Em processamentoporSociedade Brasileira de QuímicaSíntese de análogo de brassinoesteróide a partir de vespertilinaSynthesis of a brassinosteroid analogue from vespertilineinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleVespertilinaBrassinosteroidesEsteróides promotores de crescimento de plantasinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UnBinstname:Universidade de Brasília (UnB)instacron:UNBORIGINAL2905.pdfapplication/pdf57398http://repositorio.unb.br/bitstream/10482/25451/1/2905.pdfeeeb3a993978ce4870b8eb486bca0c49MD51open access10482/254512024-08-28 16:04:10.654open accessoai:repositorio.unb.br:10482/25451Repositório InstitucionalPUBhttps://repositorio.unb.br/oai/requestrepositorio@unb.bropendoar:2024-08-28T19:04:10Repositório Institucional da UnB - Universidade de Brasília (UnB)
spellingShingle Síntese de análogo de brassinoesteróide a partir de vespertilina
Gárate, José L. M.
Vespertilina
Brassinosteroides
Esteróides promotores de crescimento de plantas
status_str publishedVersion
title Síntese de análogo de brassinoesteróide a partir de vespertilina
title_full Síntese de análogo de brassinoesteróide a partir de vespertilina
title_fullStr Síntese de análogo de brassinoesteróide a partir de vespertilina
title_full_unstemmed Síntese de análogo de brassinoesteróide a partir de vespertilina
title_short Síntese de análogo de brassinoesteróide a partir de vespertilina
title_sort Síntese de análogo de brassinoesteróide a partir de vespertilina
topic Vespertilina
Brassinosteroides
Esteróides promotores de crescimento de plantas
url http://repositorio.unb.br/handle/10482/25451
https://dx.doi.org/10.1590/S0100-40421998000600011