Thermo-acoustic catalytic effect on oxidizing woody torrefaction

সংরক্ষণ করুন:
গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: Silveira, Edgar Amaral
প্রকাশনার তারিখ: 2020
অন্যান্য লেখক: Galvão, Luiz Gustavo Oliveira, Macedo, Lucélia Alves de, Sá, Isabella A., Chaves, Bruno Sant'Anna, Morais, Marcus Vinícius Girão de, Rousset, Patrick, Caldeira-Pires, Armando de Azevedo
বিন্যাস: Article
ভাষা: eng
সম্পদ: Repositório Institucional da UnB
Download full: https://repositorio.unb.br/handle/10482/39887
https://doi.org/10.3390/pr8111361
https://orcid.org/0000-0003-4800-4513
https://orcid.org/0000-0003-4809-5291
সংক্ষিপ্ত: The torrefaction (mild pyrolysis) process modifies biomass chemical and physical properties and is applied as a thermochemical route to upgrade solid fuel. In this work, the catalytic effect of thermo-acoustic on oxidizing woody torrefaction is assessed. The combined effect of two acoustic frequencies (1411, 2696 Hz) and three temperatures (230, 250, and 290 °C) was evaluated through weight loss and its deviation curves, calculated torrefaction severity index (TSI), as well as proximate, calorific, and compression strength analysis of Eucalyptus grandis. A new index to account for the catalytic effects on torrefaction (TCEI) was introduced, providing the quantitative analysis of acoustic frequencies influence. A two-step consecutive reaction numerical model allowed the thermo-acoustic experiment evaluation. For instance, the thermogravimetric profiles revealed that the acoustic field has a catalytic effect on wood torrefaction and enhances the biomass oxidation process for severe treatments. The kinetic simulation of the acoustic coupling resulted in faster conversion rates for the solid pseudo-components showing the boosting effect of acoustic frequencies in anticipating hemicellulose decomposition and enhancing second step oxidizing reaction.