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Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state

Bibliographic Details
Main Author: Arce, Pedro F.
Publication Date: 2008
Other Authors: Aznar, Martin, Silva, Silvana Mattedi e
Format: Article
Language: eng
Source: Repositório Institucional da UFBA
Download full: http://repositorio.ufba.br/ri/handle/ri/14045
Summary: Texto completo: acesso restrito. p. 1157-1167
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spelling Arce, Pedro F.Aznar, MartinSilva, Silvana Mattedi eArce, Pedro F.Aznar, MartinSilva, Silvana Mattedi e2013-12-05T17:44:06Z20080032-3888http://repositorio.ufba.br/ri/handle/ri/14045v. 48 n. 6Texto completo: acesso restrito. p. 1157-1167Phase equilibrium data of CO2 + molten polymer systems are of great relevance for chemical engineers because these are necessary for the optimal design of polymer final-treatment processes. This kind of processes needs information about gas solubilities in polymers at several temperatures and pressures. In this work, CO2 solubilities in molten polymers were modeled by the perturbed chain-statistical associating fluid theory (PC-SAFT) equation of state (EoS). For comparison, the solubilities were also calculated by the lattice gas theory (LGT) EoS, and by the well-known Peng-Robinson (PR) cubic EoS. To adjust the interactions between segments of mixtures, there were used classical mixing rules, with one adjustable temperature-dependent binary parameter for the PC-SAFT and PR EoS, and two adjustable binary parameters for the LGT EoS. The results were compared with experimental data obtained from literature. The results in terms of solubility pressure deviations indicate that the vapor–liquid behavior for CO2 + polymer systems is better predicted by the PC-SAFT model than by LGT and PR models.Submitted by Suelen Reis (suziy.ellen@gmail.com) on 2013-12-03T17:28:22Z No. of bitstreams: 1 10.1002pen.21069.pdf: 349015 bytes, checksum: 990263c8e7425576068976dde44fbb35 (MD5)Approved for entry into archive by LIVIA FREITAS (livia.freitas@ufba.br) on 2013-12-05T17:44:06Z (GMT) No. of bitstreams: 1 10.1002pen.21069.pdf: 349015 bytes, checksum: 990263c8e7425576068976dde44fbb35 (MD5)Made available in DSpace on 2013-12-05T17:44:06Z (GMT). No. of bitstreams: 1 10.1002pen.21069.pdf: 349015 bytes, checksum: 990263c8e7425576068976dde44fbb35 (MD5) Previous issue date: 2008http://dx.doi.org/10.1002/pen.21069reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAThermodynamicPolymerChemical EngineeringFluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of statePolymer Engineering and Scienceinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01info:eu-repo/semantics/openAccessengORIGINAL10.1002pen.21069.pdf10.1002pen.21069.pdfapplication/pdf349015https://repositorio.ufba.br/bitstream/ri/14045/1/10.1002pen.21069.pdf990263c8e7425576068976dde44fbb35MD51LICENSElicense.txtlicense.txttext/plain1345https://repositorio.ufba.br/bitstream/ri/14045/2/license.txtff6eaa8b858ea317fded99f125f5fcd0MD52TEXT10.1002pen.21069.pdf.txt10.1002pen.21069.pdf.txtExtracted texttext/plain35332https://repositorio.ufba.br/bitstream/ri/14045/3/10.1002pen.21069.pdf.txt92837a5934384b8b2d8763a5a017c0efMD53ri/140452022-08-08 13:17:33.636oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestrepositorio@ufba.bropendoar:19322022-08-08T16:17:33Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
dc.title.alternative.pt_BR.fl_str_mv Polymer Engineering and Science
title Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
spellingShingle Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
Arce, Pedro F.
Thermodynamic
Polymer
Chemical Engineering
title_short Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
title_full Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
title_fullStr Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
title_full_unstemmed Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
title_sort Fluid phase behavior modeling of CO2 + molten polymer systems using cubic and theoretically based equations of state
author Arce, Pedro F.
author_facet Arce, Pedro F.
Aznar, Martin
Silva, Silvana Mattedi e
author_role author
author2 Aznar, Martin
Silva, Silvana Mattedi e
author2_role author
author
dc.contributor.author.fl_str_mv Arce, Pedro F.
Aznar, Martin
Silva, Silvana Mattedi e
Arce, Pedro F.
Aznar, Martin
Silva, Silvana Mattedi e
dc.subject.por.fl_str_mv Thermodynamic
Polymer
Chemical Engineering
topic Thermodynamic
Polymer
Chemical Engineering
description Texto completo: acesso restrito. p. 1157-1167
publishDate 2008
dc.date.issued.fl_str_mv 2008
dc.date.accessioned.fl_str_mv 2013-12-05T17:44:06Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://repositorio.ufba.br/ri/handle/ri/14045
dc.identifier.issn.none.fl_str_mv 0032-3888
dc.identifier.number.pt_BR.fl_str_mv v. 48 n. 6
identifier_str_mv 0032-3888
v. 48 n. 6
url http://repositorio.ufba.br/ri/handle/ri/14045
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.pt_BR.fl_str_mv http://dx.doi.org/10.1002/pen.21069
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
instname:Universidade Federal da Bahia (UFBA)
instacron:UFBA
instname_str Universidade Federal da Bahia (UFBA)
instacron_str UFBA
institution UFBA
reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
bitstream.url.fl_str_mv https://repositorio.ufba.br/bitstream/ri/14045/1/10.1002pen.21069.pdf
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