Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation
| Main Author: | |
|---|---|
| Publication Date: | 2005 |
| Other Authors: | , |
| Format: | Article |
| Language: | eng |
| Source: | Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| Download full: | http://hdl.handle.net/1822/10658 |
Summary: | 1-Aryl-2-thienyl-substituted pyrroles and/or 5-arylamino-2,2´-bithiophenes were synthesized by treatment of arylaminothieno-oxobutanamides with Lawesson’s reagent. These in turn were prepared by direct amidation of 4-oxo-(2-thienyl)butanoic acid through DCC–BtOH mediated reactions. |
| id |
RCAP_f91d2fd268b7cded06ff8248e515fdf7 |
|---|---|
| oai_identifier_str |
oai:repositorium.sdum.uminho.pt:1822/10658 |
| network_acronym_str |
RCAP |
| network_name_str |
Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| repository_id_str |
https://opendoar.ac.uk/repository/7160 |
| spelling |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formationSynthesisAmidesPyrrolesBithiophenesFriedel-Crafts reactionLawesson´s reagentAylamino-thieno-oxobutanamidesPi-conjugated systemsPrecursors of nonlinear optical (NLO) materialsPrecursors of organic conductive polymersheterocyclessubstituent effectsbicyclic compoundsScience & Technology1-Aryl-2-thienyl-substituted pyrroles and/or 5-arylamino-2,2´-bithiophenes were synthesized by treatment of arylaminothieno-oxobutanamides with Lawesson’s reagent. These in turn were prepared by direct amidation of 4-oxo-(2-thienyl)butanoic acid through DCC–BtOH mediated reactions.Fundação para a Ciência e Tecnologia (FCT)Georg Thieme VerlagUniversidade do MinhoRaposo, M. Manuela M.Sampaio, Ana M. B. A.Kirsch, G.20052005-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/10658eng"Synthesis : Journal of Synthetic Organic Chemistry". ISSN 0039-7881. 2 (Febr. 2005) 199-210.0039-788110.1055/s-2004-834952info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-11T07:19:33Zoai:repositorium.sdum.uminho.pt:1822/10658Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T16:23:17.319719Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse |
| dc.title.none.fl_str_mv |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| title |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| spellingShingle |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation Raposo, M. Manuela M. Synthesis Amides Pyrroles Bithiophenes Friedel-Crafts reaction Lawesson´s reagent Aylamino-thieno-oxobutanamides Pi-conjugated systems Precursors of nonlinear optical (NLO) materials Precursors of organic conductive polymers heterocycles substituent effects bicyclic compounds Science & Technology |
| title_short |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| title_full |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| title_fullStr |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| title_full_unstemmed |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| title_sort |
Arylamino-thieno-oxobutanamides under Lawesson’s conditions : competition between thienylpyrrole and bithiophene formation |
| author |
Raposo, M. Manuela M. |
| author_facet |
Raposo, M. Manuela M. Sampaio, Ana M. B. A. Kirsch, G. |
| author_role |
author |
| author2 |
Sampaio, Ana M. B. A. Kirsch, G. |
| author2_role |
author author |
| dc.contributor.none.fl_str_mv |
Universidade do Minho |
| dc.contributor.author.fl_str_mv |
Raposo, M. Manuela M. Sampaio, Ana M. B. A. Kirsch, G. |
| dc.subject.por.fl_str_mv |
Synthesis Amides Pyrroles Bithiophenes Friedel-Crafts reaction Lawesson´s reagent Aylamino-thieno-oxobutanamides Pi-conjugated systems Precursors of nonlinear optical (NLO) materials Precursors of organic conductive polymers heterocycles substituent effects bicyclic compounds Science & Technology |
| topic |
Synthesis Amides Pyrroles Bithiophenes Friedel-Crafts reaction Lawesson´s reagent Aylamino-thieno-oxobutanamides Pi-conjugated systems Precursors of nonlinear optical (NLO) materials Precursors of organic conductive polymers heterocycles substituent effects bicyclic compounds Science & Technology |
| description |
1-Aryl-2-thienyl-substituted pyrroles and/or 5-arylamino-2,2´-bithiophenes were synthesized by treatment of arylaminothieno-oxobutanamides with Lawesson’s reagent. These in turn were prepared by direct amidation of 4-oxo-(2-thienyl)butanoic acid through DCC–BtOH mediated reactions. |
| publishDate |
2005 |
| dc.date.none.fl_str_mv |
2005 2005-01-01T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/10658 |
| url |
http://hdl.handle.net/1822/10658 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
"Synthesis : Journal of Synthetic Organic Chemistry". ISSN 0039-7881. 2 (Febr. 2005) 199-210. 0039-7881 10.1055/s-2004-834952 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Georg Thieme Verlag |
| publisher.none.fl_str_mv |
Georg Thieme Verlag |
| dc.source.none.fl_str_mv |
reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia instacron:RCAAP |
| instname_str |
FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia |
| instacron_str |
RCAAP |
| institution |
RCAAP |
| reponame_str |
Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| collection |
Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) |
| repository.name.fl_str_mv |
Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia |
| repository.mail.fl_str_mv |
info@rcaap.pt |
| _version_ |
1833595913597091840 |