Environmentally friendly carrageenan-based ionic-liquid driven soft actuators

Bibliographic Details
Main Author: Serra, João P.
Publication Date: 2022
Other Authors: Fernandes, Liliana C., Correia, Daniela M., Tubio, Carmen R., Vilas-Vilela, José L., Tariq, Mohammad, Esperança, José M. S. S., Costa, Carlos M., Lanceros-Mendez, Senentxu
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/134191
Summary: UID/FIS/04650/2020 UID/QUI/0686/2020 LA/P/0008/2020 PID2019-106099RB-C43/AEI/10.13039/501100011033
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spelling Environmentally friendly carrageenan-based ionic-liquid driven soft actuatorsMaterials Science(all)Chemistry (miscellaneous)UID/FIS/04650/2020 UID/QUI/0686/2020 LA/P/0008/2020 PID2019-106099RB-C43/AEI/10.13039/501100011033A naturally derived polymer based on iota carrageenan and different ammonium and imidazolium based ionic liquids (ILs) are used for the development of environmentally friendly soft actuators. The influence of IL content and type and solvent evaporation temperature on the morphological and physico-chemical properties of the materials was evaluated, together with the effect on actuator functional response. Independently of the IL content and type, and the solvent evaporation temperature, a non-porous structure is obtained. The incorporation of the IL within the polymer matrix does not affect the thermal stability but leads to a decrease in the Young modulus for the different IL/carrageenan samples. The highest influence was observed by using the [Ch][DHP] IL at a filler content of 40% w/w with a decrease in the Young modulus from 748 MPa for the neat polymer to 145 MPa for the [Ch][DHP]/carrageenan sample. Furthermore, the ionic conductivity of the samples increases with increasing IL content, with the highest values being 2.9 × 10-6 S cm-1 and 1.2 × 10-6 S cm-1 for the samples with 40% w/w of [Bmim][FeCl4] and [Ch][DHP], respectively. Regarding the soft actuator performance, the maximum displacement was obtained for the [Ch][DHP]/carrageenan sample with an IL content of 40% w/w, showing a maximum displacement of 5.8 mm at a DC applied voltage of 9 V.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNSerra, João P.Fernandes, Liliana C.Correia, Daniela M.Tubio, Carmen R.Vilas-Vilela, José L.Tariq, MohammadEsperança, José M. S. S.Costa, Carlos M.Lanceros-Mendez, Senentxu2022-03-09T23:24:56Z2022-01-212022-01-21T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttp://hdl.handle.net/10362/134191eng2633-5409PURE: 41739690https://doi.org/10.1039/d1ma00887kinfo:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:00:02Zoai:run.unl.pt:10362/134191Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:30:56.554912Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
title Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
spellingShingle Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
Serra, João P.
Materials Science(all)
Chemistry (miscellaneous)
title_short Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
title_full Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
title_fullStr Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
title_full_unstemmed Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
title_sort Environmentally friendly carrageenan-based ionic-liquid driven soft actuators
author Serra, João P.
author_facet Serra, João P.
Fernandes, Liliana C.
Correia, Daniela M.
Tubio, Carmen R.
Vilas-Vilela, José L.
Tariq, Mohammad
Esperança, José M. S. S.
Costa, Carlos M.
Lanceros-Mendez, Senentxu
author_role author
author2 Fernandes, Liliana C.
Correia, Daniela M.
Tubio, Carmen R.
Vilas-Vilela, José L.
Tariq, Mohammad
Esperança, José M. S. S.
Costa, Carlos M.
Lanceros-Mendez, Senentxu
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Serra, João P.
Fernandes, Liliana C.
Correia, Daniela M.
Tubio, Carmen R.
Vilas-Vilela, José L.
Tariq, Mohammad
Esperança, José M. S. S.
Costa, Carlos M.
Lanceros-Mendez, Senentxu
dc.subject.por.fl_str_mv Materials Science(all)
Chemistry (miscellaneous)
topic Materials Science(all)
Chemistry (miscellaneous)
description UID/FIS/04650/2020 UID/QUI/0686/2020 LA/P/0008/2020 PID2019-106099RB-C43/AEI/10.13039/501100011033
publishDate 2022
dc.date.none.fl_str_mv 2022-03-09T23:24:56Z
2022-01-21
2022-01-21T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/134191
url http://hdl.handle.net/10362/134191
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2633-5409
PURE: 41739690
https://doi.org/10.1039/d1ma00887k
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eu_rights_str_mv openAccess
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