Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride

Bibliographic Details
Main Author: Fernandes, José A.
Publication Date: 2010
Other Authors: Gomes, Ana C., Figueiredo, Sonia, Gago, Sandra, Ribeiro-Claro, Paulo J. A., Gonçalves, Isabel S., Almeida Paz, Filipe A.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10400.1/11474
Summary: In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octahedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.
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spelling Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chlorideOlefin epoxidationIn the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octahedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.Wiley-BlackwellSapientiaFernandes, José A.Gomes, Ana C.Figueiredo, SoniaGago, SandraRibeiro-Claro, Paulo J. A.Gonçalves, Isabel S.Almeida Paz, Filipe A.2018-12-07T14:53:21Z2010-072010-07-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.1/11474eng1600-536810.1107/S1600536810023950info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2025-02-18T17:32:35Zoai:sapientia.ualg.pt:10400.1/11474Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T20:25:56.219041Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
title Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
spellingShingle Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
Fernandes, José A.
Olefin epoxidation
title_short Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
title_full Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
title_fullStr Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
title_full_unstemmed Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
title_sort Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
author Fernandes, José A.
author_facet Fernandes, José A.
Gomes, Ana C.
Figueiredo, Sonia
Gago, Sandra
Ribeiro-Claro, Paulo J. A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_role author
author2 Gomes, Ana C.
Figueiredo, Sonia
Gago, Sandra
Ribeiro-Claro, Paulo J. A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Sapientia
dc.contributor.author.fl_str_mv Fernandes, José A.
Gomes, Ana C.
Figueiredo, Sonia
Gago, Sandra
Ribeiro-Claro, Paulo J. A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
dc.subject.por.fl_str_mv Olefin epoxidation
topic Olefin epoxidation
description In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octahedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.
publishDate 2010
dc.date.none.fl_str_mv 2010-07
2010-07-01T00:00:00Z
2018-12-07T14:53:21Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.1/11474
url http://hdl.handle.net/10400.1/11474
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1600-5368
10.1107/S1600536810023950
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley-Blackwell
publisher.none.fl_str_mv Wiley-Blackwell
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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