Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites

Bibliographic Details
Main Author: Criado-Gonzalez, Miryam
Publication Date: 2023
Other Authors: Alegret, Nuria, Fracaroli, Alejandro M., Mantione, Daniele, Guzmán-González, Gregorio, Del Olmo, Rafael, Tashiro, Kentaro, Tomé, Liliana C., Picchio, Matias L., Mecerreyes, David
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/154630
Summary: The financial support received from CONICET and ANPCyT (Argentina) is also gratefully acknowledged. M. C.‐G. thanks Emakiker Grant Program of POLYMAT. L. C. T. is grateful to Fundação para a Ciência e a Tecnologia (FCT/MCTES) in Portugal for her research contract under Scientific Employment Stimulus (2020.01555.CEECIND). D. M. thanks “Ayuda RYC2021‐031668‐I financiada por MCIN/AEI/10.13039/501100011033 y por la Unión Europea NextGenerationEU/PRTR”. The authors thank the technical and human support provided by SGIker (UPV/EHU/ERDF, EU). Publisher Copyright: © 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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spelling Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel CompositesBioimagingDeep Eutectic SolventsIonic LiquidsOrganic Mixed Ionic–Electronic ConductorsSupramolecular EutectogelsCatalysisChemistry(all)The financial support received from CONICET and ANPCyT (Argentina) is also gratefully acknowledged. M. C.‐G. thanks Emakiker Grant Program of POLYMAT. L. C. T. is grateful to Fundação para a Ciência e a Tecnologia (FCT/MCTES) in Portugal for her research contract under Scientific Employment Stimulus (2020.01555.CEECIND). D. M. thanks “Ayuda RYC2021‐031668‐I financiada por MCIN/AEI/10.13039/501100011033 y por la Unión Europea NextGenerationEU/PRTR”. The authors thank the technical and human support provided by SGIker (UPV/EHU/ERDF, EU). Publisher Copyright: © 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.Eutectogels are an emerging family of soft ionic materials alternative to ionic liquid gels and organogels, offering fresh perspectives for designing functional dynamic platforms in water-free environments. Herein, the first example of mixed ionic and electronic conducting supramolecular eutectogel composites is reported. A fluorescent glutamic acid-derived low-molecular-weight gelator (LMWG) was found to self-assemble into nanofibrillar networks in deep eutectic solvents (DES)/poly(3,4-ethylenedioxythiophene) (PEDOT): chondroitin sulfate dispersions. These dynamic materials displayed excellent injectability and self-healing properties, high ionic conductivity (up to 10−2 S cm−1), good biocompatibility, and fluorescence imaging ability. This set of features turns the mixed conducting supramolecular eutectogels into promising adaptive materials for bioimaging and electrostimulation applications.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCriado-Gonzalez, MiryamAlegret, NuriaFracaroli, Alejandro M.Mantione, DanieleGuzmán-González, GregorioDel Olmo, RafaelTashiro, KentaroTomé, Liliana C.Picchio, Matias L.Mecerreyes, David2023-06-29T22:18:03Z2023-06-262023-06-26T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7application/pdfhttp://hdl.handle.net/10362/154630eng1433-7851PURE: 64823620https://doi.org/10.1002/anie.202301489info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:12:31Zoai:run.unl.pt:10362/154630Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:42:48.456491Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
title Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
spellingShingle Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
Criado-Gonzalez, Miryam
Bioimaging
Deep Eutectic Solvents
Ionic Liquids
Organic Mixed Ionic–Electronic Conductors
Supramolecular Eutectogels
Catalysis
Chemistry(all)
title_short Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
title_full Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
title_fullStr Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
title_full_unstemmed Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
title_sort Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
author Criado-Gonzalez, Miryam
author_facet Criado-Gonzalez, Miryam
Alegret, Nuria
Fracaroli, Alejandro M.
Mantione, Daniele
Guzmán-González, Gregorio
Del Olmo, Rafael
Tashiro, Kentaro
Tomé, Liliana C.
Picchio, Matias L.
Mecerreyes, David
author_role author
author2 Alegret, Nuria
Fracaroli, Alejandro M.
Mantione, Daniele
Guzmán-González, Gregorio
Del Olmo, Rafael
Tashiro, Kentaro
Tomé, Liliana C.
Picchio, Matias L.
Mecerreyes, David
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Criado-Gonzalez, Miryam
Alegret, Nuria
Fracaroli, Alejandro M.
Mantione, Daniele
Guzmán-González, Gregorio
Del Olmo, Rafael
Tashiro, Kentaro
Tomé, Liliana C.
Picchio, Matias L.
Mecerreyes, David
dc.subject.por.fl_str_mv Bioimaging
Deep Eutectic Solvents
Ionic Liquids
Organic Mixed Ionic–Electronic Conductors
Supramolecular Eutectogels
Catalysis
Chemistry(all)
topic Bioimaging
Deep Eutectic Solvents
Ionic Liquids
Organic Mixed Ionic–Electronic Conductors
Supramolecular Eutectogels
Catalysis
Chemistry(all)
description The financial support received from CONICET and ANPCyT (Argentina) is also gratefully acknowledged. M. C.‐G. thanks Emakiker Grant Program of POLYMAT. L. C. T. is grateful to Fundação para a Ciência e a Tecnologia (FCT/MCTES) in Portugal for her research contract under Scientific Employment Stimulus (2020.01555.CEECIND). D. M. thanks “Ayuda RYC2021‐031668‐I financiada por MCIN/AEI/10.13039/501100011033 y por la Unión Europea NextGenerationEU/PRTR”. The authors thank the technical and human support provided by SGIker (UPV/EHU/ERDF, EU). Publisher Copyright: © 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
publishDate 2023
dc.date.none.fl_str_mv 2023-06-29T22:18:03Z
2023-06-26
2023-06-26T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/154630
url http://hdl.handle.net/10362/154630
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1433-7851
PURE: 64823620
https://doi.org/10.1002/anie.202301489
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 7
application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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