Physically-Deposited Hole Transporters in Perovskite PV

Detalhes bibliográficos
Autor(a) principal: Akalin, Salih Alper
Data de Publicação: 2024
Outros Autores: Erol, Mustafa, Uzunbayir, Begum, Oguzlar, Sibel, Yildirim, Serdar, Gokdemir Choi, Fatma Pinar, Gunes, Serap, Yilmazer Menda, Ugur Deneb, Mendes, Manuel J.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Texto Completo: http://hdl.handle.net/10362/172614
Resumo: This study was financially supported by the Dokuz Eylul University, the Scientific Research Projects Coordinatorship with the project code 2019.KB.MLT.004. The authors are indebted to the infrastructural support from Dokuz Eylül University, the Center for Production and Applications of Electronic Materials (EMUM), Department of Metallurgical and Materials Engineering, Yıldız Technical University Department of Physics, and Universidade Nova de Lisboa, Centro de Investigação em Materiais (CENIMAT) where research was carried out. S.A.A. acknowledges funding for a post‐doc scholarship from TUBİTAK (The Scientific and Technological Research Council of Türkiye, 2219) through grant 1059B192200308. The study was also partially supported by FCT (Fundação para a Ciência e Tecnologia, project M‐ECO2 (Industrial cluster for advanced biofuel production, ref. C644930471‐00000041) co‐financed by PRR − Recovery and Resilience Plan of the European Union (Next Generation EU). Publisher Copyright: © 2024 The Authors. Advanced Materials Technologies published by Wiley-VCH GmbH.
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spelling Physically-Deposited Hole Transporters in Perovskite PVNiOx Improved with Li/Mg Dopinghole transport materiallithium/magnesium dopingperovskite solar cellsphotovoltaicssputtered nickel oxideMaterials Science(all)Mechanics of MaterialsIndustrial and Manufacturing EngineeringThis study was financially supported by the Dokuz Eylul University, the Scientific Research Projects Coordinatorship with the project code 2019.KB.MLT.004. The authors are indebted to the infrastructural support from Dokuz Eylül University, the Center for Production and Applications of Electronic Materials (EMUM), Department of Metallurgical and Materials Engineering, Yıldız Technical University Department of Physics, and Universidade Nova de Lisboa, Centro de Investigação em Materiais (CENIMAT) where research was carried out. S.A.A. acknowledges funding for a post‐doc scholarship from TUBİTAK (The Scientific and Technological Research Council of Türkiye, 2219) through grant 1059B192200308. The study was also partially supported by FCT (Fundação para a Ciência e Tecnologia, project M‐ECO2 (Industrial cluster for advanced biofuel production, ref. C644930471‐00000041) co‐financed by PRR − Recovery and Resilience Plan of the European Union (Next Generation EU). Publisher Copyright: © 2024 The Authors. Advanced Materials Technologies published by Wiley-VCH GmbH.Nickel oxide (NiOx) has received a lot of attention as an inorganic hole transport material (HTM) in perovskite solar cells (PSCs) during the last decade, owing to its high hole mobility, chemical stability, good optical transparency, and suitable energy levels that align with the valance band of the perovskite absorber methylammonium lead iodide (MAPbI3). This study explores Li and Mg co-doped NiOx thin films physically-deposited from developed sputtering targets obtained through cold isostatic pressing and sintering. After sputtering, the structural, elemental, morphological, optical, and electrical properties of the layers are investigated by XRD, XPS, SEM, AFM, UV–vis spectrophotometer, and Hall-effect; revealing that crystalline, homogeneous, and smooth films are obtained. In particular, improvements in mobility and conductivity values are observed with Li and Mg doping, which contribute to enhanced PSC performance when used as an HTM layer in the glass-indium tin oxide (ITO)/NiOx-based HTM/MAPbI3/phenyl butryic acid methyl ester (PCBM)/bathocuproine (BCP)/Ag architecture. The champion solar cell achieves PCE of 15.52%. In addition, the average values of all samples are boosted, JSC (from 13.21 to 15.60 mA cm−2) and FF (from 59.32% to 67.7%), relative to pristine HTM, resulting in a pronounced PCE increment of up to 30% with the HTM film sputtered by a single target of co-doped material.CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)DCM - Departamento de Ciência dos MateriaisUNINOVA-Instituto de Desenvolvimento de Novas TecnologiasRUNAkalin, Salih AlperErol, MustafaUzunbayir, BegumOguzlar, SibelYildirim, SerdarGokdemir Choi, Fatma PinarGunes, SerapYilmazer Menda, Ugur DenebMendes, Manuel J.2024-09-28T22:21:08Z2024-04-042024-04-04T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article11application/pdfhttp://hdl.handle.net/10362/172614eng2365-709XPURE: 99759527https://doi.org/10.1002/admt.202301760info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-10-28T01:38:44Zoai:run.unl.pt:10362/172614Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T18:54:31.863318Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Physically-Deposited Hole Transporters in Perovskite PV
NiOx Improved with Li/Mg Doping
title Physically-Deposited Hole Transporters in Perovskite PV
spellingShingle Physically-Deposited Hole Transporters in Perovskite PV
Akalin, Salih Alper
hole transport material
lithium/magnesium doping
perovskite solar cells
photovoltaics
sputtered nickel oxide
Materials Science(all)
Mechanics of Materials
Industrial and Manufacturing Engineering
title_short Physically-Deposited Hole Transporters in Perovskite PV
title_full Physically-Deposited Hole Transporters in Perovskite PV
title_fullStr Physically-Deposited Hole Transporters in Perovskite PV
title_full_unstemmed Physically-Deposited Hole Transporters in Perovskite PV
title_sort Physically-Deposited Hole Transporters in Perovskite PV
author Akalin, Salih Alper
author_facet Akalin, Salih Alper
Erol, Mustafa
Uzunbayir, Begum
Oguzlar, Sibel
Yildirim, Serdar
Gokdemir Choi, Fatma Pinar
Gunes, Serap
Yilmazer Menda, Ugur Deneb
Mendes, Manuel J.
author_role author
author2 Erol, Mustafa
Uzunbayir, Begum
Oguzlar, Sibel
Yildirim, Serdar
Gokdemir Choi, Fatma Pinar
Gunes, Serap
Yilmazer Menda, Ugur Deneb
Mendes, Manuel J.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
DCM - Departamento de Ciência dos Materiais
UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
RUN
dc.contributor.author.fl_str_mv Akalin, Salih Alper
Erol, Mustafa
Uzunbayir, Begum
Oguzlar, Sibel
Yildirim, Serdar
Gokdemir Choi, Fatma Pinar
Gunes, Serap
Yilmazer Menda, Ugur Deneb
Mendes, Manuel J.
dc.subject.por.fl_str_mv hole transport material
lithium/magnesium doping
perovskite solar cells
photovoltaics
sputtered nickel oxide
Materials Science(all)
Mechanics of Materials
Industrial and Manufacturing Engineering
topic hole transport material
lithium/magnesium doping
perovskite solar cells
photovoltaics
sputtered nickel oxide
Materials Science(all)
Mechanics of Materials
Industrial and Manufacturing Engineering
description This study was financially supported by the Dokuz Eylul University, the Scientific Research Projects Coordinatorship with the project code 2019.KB.MLT.004. The authors are indebted to the infrastructural support from Dokuz Eylül University, the Center for Production and Applications of Electronic Materials (EMUM), Department of Metallurgical and Materials Engineering, Yıldız Technical University Department of Physics, and Universidade Nova de Lisboa, Centro de Investigação em Materiais (CENIMAT) where research was carried out. S.A.A. acknowledges funding for a post‐doc scholarship from TUBİTAK (The Scientific and Technological Research Council of Türkiye, 2219) through grant 1059B192200308. The study was also partially supported by FCT (Fundação para a Ciência e Tecnologia, project M‐ECO2 (Industrial cluster for advanced biofuel production, ref. C644930471‐00000041) co‐financed by PRR − Recovery and Resilience Plan of the European Union (Next Generation EU). Publisher Copyright: © 2024 The Authors. Advanced Materials Technologies published by Wiley-VCH GmbH.
publishDate 2024
dc.date.none.fl_str_mv 2024-09-28T22:21:08Z
2024-04-04
2024-04-04T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/172614
url http://hdl.handle.net/10362/172614
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2365-709X
PURE: 99759527
https://doi.org/10.1002/admt.202301760
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 11
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dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
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instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
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reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
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