Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators

Bibliographic Details
Main Author: Barbosa, J. C.
Publication Date: 2018
Other Authors: Dias, J. P., Lanceros-Méndez, S., Costa, C. M.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/1822/57369
Summary: The separator membrane is an essential component of lithium-ion batteries, separating the anode and cathode, and controlling the number and mobility of the lithium ions. Among the polymer matrices most commonly investigated for battery separators are poly(vinylidene fluoride) (PVDF) and its copolymers poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE), poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), and poly(vinylidene fluoride-cochlorotrifluoroethylene) (PVDF-CTFE), due to their excellent properties such as high polarity and the possibility of controlling the porosity of the materials through binary and ternary polymer/solvent systems, among others. This review presents the recent advances on battery separators based on PVDF and its copolymers for lithium-ion batteries. It is divided into the following sections: single polymer and co-polymers, surface modification, composites, and polymer blends. Further, a critical comparison between those membranes and other separator membranes is presented, as well as the future trends on this area.
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spelling Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separatorsBattery separatorCopolymersLithium-ion batteriesPVDFScience & TechnologyThe separator membrane is an essential component of lithium-ion batteries, separating the anode and cathode, and controlling the number and mobility of the lithium ions. Among the polymer matrices most commonly investigated for battery separators are poly(vinylidene fluoride) (PVDF) and its copolymers poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE), poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), and poly(vinylidene fluoride-cochlorotrifluoroethylene) (PVDF-CTFE), due to their excellent properties such as high polarity and the possibility of controlling the porosity of the materials through binary and ternary polymer/solvent systems, among others. This review presents the recent advances on battery separators based on PVDF and its copolymers for lithium-ion batteries. It is divided into the following sections: single polymer and co-polymers, surface modification, composites, and polymer blends. Further, a critical comparison between those membranes and other separator membranes is presented, as well as the future trends on this area.Portuguese Foundation for Science and Technology (FCT): UID/FIS/04650/2013, PTDC/CTM-ENE/5387/2014, UID/CTM/50025/2013, project NO. 28157/02/SAICT/2017 and grants SFRH/BPD/112547/2015 (C.M.C.), including FEDER funds through the COMPETE 2020 programme and National Funds through FCT. Financial support from the Basque Government Industry Department under the ELKARTEK and HAZITEK programs is also acknowledged.info:eu-repo/semantics/publishedVersionMDPI AGUniversidade do MinhoBarbosa, J. C.Dias, J. P.Lanceros-Méndez, S.Costa, C. M.20182018-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/57369engBarbosa, J.C.; Dias, J.P.; Lanceros-Méndez, S.; Costa, C.M. Recent Advances in Poly(vinylidene fluoride) and Its Copolymers for Lithium-Ion Battery Separators. Membranes 2018, 8, 45.2077-037510.3390/membranes8030045info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-11T07:30:28Zoai:repositorium.sdum.uminho.pt:1822/57369Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T16:29:49.058777Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
title Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
spellingShingle Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
Barbosa, J. C.
Battery separator
Copolymers
Lithium-ion batteries
PVDF
Science & Technology
title_short Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
title_full Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
title_fullStr Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
title_full_unstemmed Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
title_sort Recent advances in poly(Vinylidene fluoride) and its copolymers for lithium-ion battery separators
author Barbosa, J. C.
author_facet Barbosa, J. C.
Dias, J. P.
Lanceros-Méndez, S.
Costa, C. M.
author_role author
author2 Dias, J. P.
Lanceros-Méndez, S.
Costa, C. M.
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Barbosa, J. C.
Dias, J. P.
Lanceros-Méndez, S.
Costa, C. M.
dc.subject.por.fl_str_mv Battery separator
Copolymers
Lithium-ion batteries
PVDF
Science & Technology
topic Battery separator
Copolymers
Lithium-ion batteries
PVDF
Science & Technology
description The separator membrane is an essential component of lithium-ion batteries, separating the anode and cathode, and controlling the number and mobility of the lithium ions. Among the polymer matrices most commonly investigated for battery separators are poly(vinylidene fluoride) (PVDF) and its copolymers poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE), poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), and poly(vinylidene fluoride-cochlorotrifluoroethylene) (PVDF-CTFE), due to their excellent properties such as high polarity and the possibility of controlling the porosity of the materials through binary and ternary polymer/solvent systems, among others. This review presents the recent advances on battery separators based on PVDF and its copolymers for lithium-ion batteries. It is divided into the following sections: single polymer and co-polymers, surface modification, composites, and polymer blends. Further, a critical comparison between those membranes and other separator membranes is presented, as well as the future trends on this area.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/57369
url http://hdl.handle.net/1822/57369
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Barbosa, J.C.; Dias, J.P.; Lanceros-Méndez, S.; Costa, C.M. Recent Advances in Poly(vinylidene fluoride) and Its Copolymers for Lithium-Ion Battery Separators. Membranes 2018, 8, 45.
2077-0375
10.3390/membranes8030045
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
_version_ 1833595977216294912

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