Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)

Bibliographic Details
Main Author: Kaabi, Kamel
Publication Date: 2010
Other Authors: El Glaoui, Meher, Pereira Silva, P. S., Silva, Manuela Ramos, Ben Nasr, Cherif
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: https://hdl.handle.net/10316/110152
https://doi.org/10.1107/S1600536810035051
Summary: In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd-N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd-O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl-pyrimidin-4(1H)-one ligands and two chloride ions [Cd-Cl = 2.4674 (6) and 2.4893 (7) Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter-molecular N-H⋯Cl and N-H⋯O hydrogen bonds.
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spelling Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)single-crystal X-ray studyT = 293 K; mean (C–C) = 0.004 A°R factor = 0.023wR factor = 0.108data-to-parameter ratio = 23.7In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd-N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd-O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl-pyrimidin-4(1H)-one ligands and two chloride ions [Cd-Cl = 2.4674 (6) and 2.4893 (7) Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter-molecular N-H⋯Cl and N-H⋯O hydrogen bonds.International Union of Crystallography2010-09-08info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://hdl.handle.net/10316/110152https://hdl.handle.net/10316/110152https://doi.org/10.1107/S1600536810035051eng1600-5368Kaabi, KamelEl Glaoui, MeherPereira Silva, P. S.Silva, Manuela RamosBen Nasr, Cherifinfo:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2023-11-15T11:17:53Zoai:estudogeral.uc.pt:10316/110152Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-29T06:01:49.193631Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
title Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
spellingShingle Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
Kaabi, Kamel
single-crystal X-ray study
T = 293 K; mean (C–C) = 0.004 A°
R factor = 0.023
wR factor = 0.108
data-to-parameter ratio = 23.7
title_short Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
title_full Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
title_fullStr Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
title_full_unstemmed Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
title_sort Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II)
author Kaabi, Kamel
author_facet Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Silva, Manuela Ramos
Ben Nasr, Cherif
author_role author
author2 El Glaoui, Meher
Pereira Silva, P. S.
Silva, Manuela Ramos
Ben Nasr, Cherif
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Silva, Manuela Ramos
Ben Nasr, Cherif
dc.subject.por.fl_str_mv single-crystal X-ray study
T = 293 K; mean (C–C) = 0.004 A°
R factor = 0.023
wR factor = 0.108
data-to-parameter ratio = 23.7
topic single-crystal X-ray study
T = 293 K; mean (C–C) = 0.004 A°
R factor = 0.023
wR factor = 0.108
data-to-parameter ratio = 23.7
description In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd-N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd-O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl-pyrimidin-4(1H)-one ligands and two chloride ions [Cd-Cl = 2.4674 (6) and 2.4893 (7) Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter-molecular N-H⋯Cl and N-H⋯O hydrogen bonds.
publishDate 2010
dc.date.none.fl_str_mv 2010-09-08
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://hdl.handle.net/10316/110152
https://hdl.handle.net/10316/110152
https://doi.org/10.1107/S1600536810035051
url https://hdl.handle.net/10316/110152
https://doi.org/10.1107/S1600536810035051
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1600-5368
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
_version_ 1833602553602899968

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