Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds

Bibliographic Details
Main Author: Anis, Arfat
Publication Date: 2022
Other Authors: Alam, Manawwer, Alhamidi, Abdullah, Alam, Mohammad Asif, Gupta, Ravindra Kumar, Tariq, Mohammad, Shaikh, Hamid, Poulose, Anesh Manjaly, Al-Zahrani, Saeed M.
Format: Article
Language: eng
Source: Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
Download full: http://hdl.handle.net/10362/144487
Summary: Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042
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spelling Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic CompoundsFTIR spectroscopyionic conductivityNMR analysisp-toluene sulfonic acidprotic ionic liquidsChemical Engineering(all)Materials Science(all)Condensed Matter PhysicsInorganic ChemistryKingdom of Saudi Arabia, Award Number (2-17-01-001-0042In the present work, six protic ionic liquid (PIL) compounds based on p-toluene sulfonic acid [PTSA] anion along with different cations viz. tetraethylenepentammonium [TEPA], triethy-lammonium [TEA], pyridinium [Py], N-methylpiperidinium [Pip], 1-methylimidazolium [Im], and N-methylpyrrolidinium [Pyrr] were synthesized using the standard neutralization reaction method. The structural characterization of these compounds was achieved using FTIR,1H and13C NMR spectroscopies. Thermal behavior was studied using differential scanning calorimetry to determine the melting point (Tm) and crystallization (Tc ) temperatures. Thermogravimetric analysis was carried out to determine the thermal stability and degradation temperatures (Tdec) and to ascertain the hygroscopic or hydrophobic nature of the synthesized compounds. Structural effects on the outcome of various properties were witnessed and discussed in detail. Electrochemical impedance spectroscopy was utilized to study the electrical transport properties of the PILs at different temperatures. Cyclic voltammetry was performed to analyze the electrochemical stability of these PILs. Low values of activation energy indicating easy proton transportation along with good electrochemical stability make the PILs a potential candidate for use in the preparation of polymer electrolytes membranes for fuel cell applications.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNAnis, ArfatAlam, ManawwerAlhamidi, AbdullahAlam, Mohammad AsifGupta, Ravindra KumarTariq, MohammadShaikh, HamidPoulose, Anesh ManjalyAl-Zahrani, Saeed M.2022-10-05T22:16:03Z2022-04-062022-04-06T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article15application/pdfhttp://hdl.handle.net/10362/144487eng2073-4352PURE: 46294679https://doi.org/10.3390/cryst12040507info:eu-repo/semantics/openAccessreponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiainstacron:RCAAP2024-05-22T18:05:47Zoai:run.unl.pt:10362/144487Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireinfo@rcaap.ptopendoar:https://opendoar.ac.uk/repository/71602025-05-28T17:36:14.854813Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologiafalse
dc.title.none.fl_str_mv Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
title Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
spellingShingle Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
Anis, Arfat
FTIR spectroscopy
ionic conductivity
NMR analysis
p-toluene sulfonic acid
protic ionic liquids
Chemical Engineering(all)
Materials Science(all)
Condensed Matter Physics
Inorganic Chemistry
title_short Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
title_full Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
title_fullStr Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
title_full_unstemmed Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
title_sort Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
author Anis, Arfat
author_facet Anis, Arfat
Alam, Manawwer
Alhamidi, Abdullah
Alam, Mohammad Asif
Gupta, Ravindra Kumar
Tariq, Mohammad
Shaikh, Hamid
Poulose, Anesh Manjaly
Al-Zahrani, Saeed M.
author_role author
author2 Alam, Manawwer
Alhamidi, Abdullah
Alam, Mohammad Asif
Gupta, Ravindra Kumar
Tariq, Mohammad
Shaikh, Hamid
Poulose, Anesh Manjaly
Al-Zahrani, Saeed M.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Anis, Arfat
Alam, Manawwer
Alhamidi, Abdullah
Alam, Mohammad Asif
Gupta, Ravindra Kumar
Tariq, Mohammad
Shaikh, Hamid
Poulose, Anesh Manjaly
Al-Zahrani, Saeed M.
dc.subject.por.fl_str_mv FTIR spectroscopy
ionic conductivity
NMR analysis
p-toluene sulfonic acid
protic ionic liquids
Chemical Engineering(all)
Materials Science(all)
Condensed Matter Physics
Inorganic Chemistry
topic FTIR spectroscopy
ionic conductivity
NMR analysis
p-toluene sulfonic acid
protic ionic liquids
Chemical Engineering(all)
Materials Science(all)
Condensed Matter Physics
Inorganic Chemistry
description Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042
publishDate 2022
dc.date.none.fl_str_mv 2022-10-05T22:16:03Z
2022-04-06
2022-04-06T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/144487
url http://hdl.handle.net/10362/144487
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4352
PURE: 46294679
https://doi.org/10.3390/cryst12040507
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 15
application/pdf
dc.source.none.fl_str_mv reponame:Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
instname:FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron:RCAAP
instname_str FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
instacron_str RCAAP
institution RCAAP
reponame_str Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
collection Repositórios Científicos de Acesso Aberto de Portugal (RCAAP)
repository.name.fl_str_mv Repositórios Científicos de Acesso Aberto de Portugal (RCAAP) - FCCN, serviços digitais da FCT – Fundação para a Ciência e a Tecnologia
repository.mail.fl_str_mv info@rcaap.pt
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